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Establishment of control methods of regioselectivity by non-covalent interactions in C-H transformations

Research Project

Project/Area Number 17H03016
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Organic chemistry
Research InstitutionKyushu University

Principal Investigator

Kuninobu Yoichiro  九州大学, 先導物質化学研究所, 教授 (40372685)

Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥18,720,000 (Direct Cost: ¥14,400,000、Indirect Cost: ¥4,320,000)
Fiscal Year 2019: ¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2018: ¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2017: ¥8,450,000 (Direct Cost: ¥6,500,000、Indirect Cost: ¥1,950,000)
KeywordsC-H結合変換 / 位置選択性 / 水素結合 / Lewis酸-塩基相互作用 / 超分子相互作用 / 非共有結合性相互作用 / ボリル化 / シリル化 / メタ位 / オルト位 / Lewis酸-塩基相互作用
Outline of Final Research Achievements

We succeeded in the development of several regioselective C-H transformations using noncovalent interactions between two components, such as a ligand of a catalyst and a substrate or a substrate and a reagent, in the reaction mixture. Several novel synthetic organic reactions including C-H transformations have also been developed during investigation of the projects. In addition, we succeeded in the application of the "noncovalent interaction" concept to the development of reactions to synthesize pai-conjugated molecules and to the creation of new type photoluminescent materials.

Academic Significance and Societal Importance of the Research Achievements

研究代表者が以前から着目している反応系中の2成分間での非共有結合性相互作用の利用を鍵とすることで、いくつかの位置選択的なC-H結合変換反応や新規有機合成反応の開発に成功した。有機合成化学分野に指針を与えるとともに、使っていただける反応を開発できたのではないかと考えている。また、非共有結合性相互作用の概念を新しいタイプの有機発光性材料の開発にも拡張できた。マルチカラー発光材料の新たな設計指針になることが期待できる。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (106 results)

All 2020 2019 2018 2017 Other

All Int'l Joint Research (1 results) Journal Article (13 results) (of which Peer Reviewed: 12 results,  Open Access: 1 results) Presentation (83 results) (of which Int'l Joint Research: 20 results,  Invited: 28 results) Book (2 results) Remarks (4 results) Patent(Industrial Property Rights) (3 results) (of which Overseas: 1 results)

  • [Int'l Joint Research] Lanzhou University/Tianjin University(中国)

    • Related Report
      2019 Annual Research Report
  • [Journal Article] Synthesis of six-membered silacycles by borane-catalyzed double sila-Friedel-Crafts reaction2020

    • Author(s)
      Dong Yafang、Sakai Masahiko、Fuji Kazuto、Sekine Kohei、Kuninobu Yoichiro
    • Journal Title

      Beilstein Journal of Organic Chemistry

      Volume: 16 Pages: 409-414

    • DOI

      10.3762/bjoc.16.39

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 2-Position-Selective Trifluoromethylthiolation of Six-Membered Heteroaromatic Compounds2019

    • Author(s)
      Muta Ryuhei、Torigoe Takeru、Kuninobu Yoichiro
    • Journal Title

      Organic Letters

      Volume: 21 Issue: 11 Pages: 4289-4292

    • DOI

      10.1021/acs.orglett.9b01474

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Control of Multicolor and White Emission by Adjusting the Equilibrium between Fluorophores, Lewis Acids, and Their Complexes in Polymers2019

    • Author(s)
      Mori Toshiaki、Yoshigoe Yusuke、Kuninobu Yoichiro
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 58 Issue: 41 Pages: 14457-14461

    • DOI

      10.1002/anie.201903408

    • Related Report
      2019 Annual Research Report
  • [Journal Article] Lewis acid-catalyzed synthesis of silafluorene derivatives from biphenyls and dihydrosilanes via a double sila-Friedel-Crafts reaction2019

    • Author(s)
      Dong Yafang、Takata Yuta、Yoshigoe Yusuke、Sekine Kohei、Kuninobu Yoichiro
    • Journal Title

      Chemical Communications

      Volume: 55 Issue: 88 Pages: 13303-13306

    • DOI

      10.1039/c9cc07692a

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydrogen Bond-Accelerated meta-Selective C-H Borylation of Aromatic Compounds and Expression of Functional Group and Substrate Specificities2019

    • Author(s)
      Lu, X.; Yoshigoe, Y.; Ida, H.; Nishi, M.; Kanai, M.; Kuninobu, Y.
    • Journal Title

      ACS Catal.

      Volume: 9 Issue: 3 Pages: 1705-1709

    • DOI

      10.1021/acscatal.8b05005

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydrogen-Bond-Controlled Formal Meta-Selective C-H Transformations and Regioselective Synthesis of Multisubstituted Aromatic Compounds2019

    • Author(s)
      Wang, J.; Torigoe, T.; Kuninobu, Y.
    • Journal Title

      Org. Lett.

      Volume: 21 Issue: 5 Pages: 1342-1346

    • DOI

      10.1021/acs.orglett.9b00030

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Development of Novel C-H Bond Transformations and Their Application to the Synthesis of Organic Functional Molecules2018

    • Author(s)
      Kuninobu, Y.
    • Journal Title

      Synlett

      Volume: 29 Issue: 16 Pages: 2093-2107

    • DOI

      10.1055/s-0037-1610531

    • NAID

      130005433327

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of Solid-state Luminescent Materials by Complexation between π-Conjugated Molecules and Activators2018

    • Author(s)
      Yamakawa, T.; Yoshigoe, Y.; Wang, Z.; Kanai, M.; Kuninobu, Y.
    • Journal Title

      Chem. Lett.

      Volume: 47 Issue: 11 Pages: 1391-1394

    • DOI

      10.1246/cl.180735

    • NAID

      130007504927

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Palladium-Catalyzed Synthesis of Diaryl Ketones from Aldehydes and (Hetero)Aryl Halides via C?H Bond Activation2018

    • Author(s)
      Wakaki Takayuki、Togo Takaya、Yoshidome Daisuke、Kuninobu Yoichiro、Kanai Motomu
    • Journal Title

      ACS Catal.

      Volume: 8 Issue: 4 Pages: 3123-3128

    • DOI

      10.1021/acscatal.8b00440

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Iron-Catalyzed Acyloxyalkylation of Styrenes Using Hypervalent Iodine Reagents2017

    • Author(s)
      Wang Zijia、Kanai Motomu、Kuninobu Yoichiro
    • Journal Title

      Org. Lett.

      Volume: 19 Issue: 9 Pages: 2398-2401

    • DOI

      10.1021/acs.orglett.7b00923

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Iron-Catalyzed ortho-Selective C?H Borylation of 2-Phenylpyridines and Their Analogs2017

    • Author(s)
      Yoshigoe Yusuke、Kuninobu Yoichiro
    • Journal Title

      Org. Lett.

      Volume: 19 Issue: 13 Pages: 3450-3453

    • DOI

      10.1021/acs.orglett.7b01423

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Iridium/Bipyridine-Catalyzed ortho-Selective C?H Borylation of Phenol and Aniline Derivatives2017

    • Author(s)
      Li Hong-Liang、Kanai Motomu、Kuninobu Yoichiro
    • Journal Title

      Org. Lett.

      Volume: 19 Issue: 21 Pages: 5944-5947

    • DOI

      10.1021/acs.orglett.7b02936

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rhenium-Catalyzed ortho-Alkylation of Phenols2017

    • Author(s)
      Yoichiro Kuninobu, Masaki Yamamoto, Mitsumi Nishi, Tomoyuki Yamamoto, Takashi Matsuki, Masahito Murai, Kazuhiko Takai
    • Journal Title

      Organic Syntheses

      Volume: 94 Pages: 280-291

    • DOI

      10.15227/orgsyn.094.0280

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Presentation] Development of Regioselective C-H Bond Transformations2020

    • Author(s)
      Yoichiro Kuninobu
    • Organizer
      International Conference on Chemistry for Human Development (ICCHD-2020)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Development of Regioselective C-H Bond Transformations2020

    • Author(s)
      Yoichiro Kuninobu
    • Organizer
      Advances in Organic Synthesis (AOS 2020)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 有機機能性分子合成を志向した新規炭素-水素結合変換反応の開発2020

    • Author(s)
      國信 洋一郎
    • Organizer
      近畿化学協会有機金属部会第4回例会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] 有機機能性分子合成を志向した新規炭素-水素結合変換反応の開発2020

    • Author(s)
      國信 洋一郎
    • Organizer
      長崎大学工学部講演会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] ホウ素触媒を用いる二重シラFriedel-Crafts反応による含ケイ素六員環化合物の合成2020

    • Author(s)
      酒井 優光、Yafang Dong、藤 和人、関根 康平、國信 洋一郎
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Synthesis of Silepins from Terphenyls and Dihydrosilanes via Double Sila-Friedel-Crafts Reaction2020

    • Author(s)
      Yafang Dong, Kohei Sekine, Yoichiro Kuninobu
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 水素結合を利用したイリジウム触媒によるチオアニソール類のオルト位選択的なC-Hボリル化2020

    • Author(s)
      曾 嘉林、内藤 森生、鳥越 尊、山中 正浩、國信 洋一郎
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 含窒素六員環芳香族化合物への位置選択的な含フッ素官能基導入反応の開発2020

    • Author(s)
      楢山 光司、牟田 龍平、鳥越 尊、國信 洋一郎
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] アミノ酸側鎖の位置選択的なC-Hトリフルオロメチル化2020

    • Author(s)
      宋 済舟、鳥越 尊、國信 洋一郎
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] シクロデキストリンによる包接を利用した鉄触媒による芳香族化合物の位置選択的C-Hトリフルオロメチル化反応の開発2020

    • Author(s)
      盧 旭、鳥越 尊、國信 洋一郎
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Manganese-catalyzed C(sp3)-H Bromination2020

    • Author(s)
      Kumar Sneh, Takeru Torigoe, Yoichiro Kuninobu
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 2-フェニルピリジン部位を有する六配位ケイ素化合物の合成とその光物性2020

    • Author(s)
      森 俊彰、古田 翔平、吉越 裕介、関根 康平、國信 洋一郎
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] デカタングステン酸塩光触媒によるC(sp3)-H結合官能基化反応の静電相互作用を用いた位置選択性制御2020

    • Author(s)
      曾 嘉林、鳥越 尊、國信 洋一郎
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] ニッケル触媒を用いた分子内および分子間C-Hシリル化反応の開発2020

    • Author(s)
      藤 和人、関根 康平、國信 洋一郎
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Noncovalent Bond-Controlled Regioselective C-H Transformations2019

    • Author(s)
      國信 洋一郎
    • Organizer
      Let’s leap! Challenges in Organic Chemistry
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] ベンゾフェノン誘導体とLewis酸の錯形成による蛍光材料の開発とポリマー担持による固体発光特性の評価2019

    • Author(s)
      森 敏彰、吉越裕介、國信 洋一郎
    • Organizer
      三地区交歓会
    • Related Report
      2019 Annual Research Report
  • [Presentation] ポリマーを利用する蛍光色素-ルイス酸間での平衡の調整によるマルチカラーおよび白色発光の制御2019

    • Author(s)
      森 敏彰、吉越裕介、國信 洋一郎
    • Organizer
      第29回万有福岡シンポジウム
    • Related Report
      2019 Annual Research Report
  • [Presentation] 有機機能性分子合成を志向した新規炭素-水素結合変換反応の開発2019

    • Author(s)
      國信 洋一郎
    • Organizer
      武蔵野大学講演会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] Hydrogen Bond-Accelerated meta-Selective C-H Borylation of Aromatic Compounds and Expression of Substrate Specificity2019

    • Author(s)
      Xu Lu, Yusuke Yoshigoe, Haruka Ida, Mitsumi Nishi, Motomu Kanai, Yoichiro Kuninobu
    • Organizer
      第1回ハイブリッド触媒国際シンポジウム
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 有機機能性分子合成を志向した新規炭素-水素結合変換反応の開発2019

    • Author(s)
      國信 洋一郎
    • Organizer
      北海道大学講演会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] 2-Position-selective trifluoromethylthiolation of six-membered heteroaromatic compounds2019

    • Author(s)
      Takeru Torigoe, Ryuhei Muta, Yoichiro Kuninobu
    • Organizer
      20th Tetrahedron Symposium
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Hydrogen Bond-Controlled meta-selective C-H Borylation and Its Applications2019

    • Author(s)
      Yoichiro Kuninobu
    • Organizer
      The 47th NAITO CONFERENCE, “C-H Bond Activation and Transformation”
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] One-pot meta-Selective Functionalizations of Aromatic Compounds Utilizing Iridium-catalyzed C-H Borylated Products2019

    • Author(s)
      Jie Wang, Takeru Torigoe, Yoichiro Kuninobu
    • Organizer
      第56回化学関連支部合同九州大会・外国人研究者交流 国際シンポジウム
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Double C-H Silylation for the Synthesis of Silafluorenes by Borane Catalyst2019

    • Author(s)
      Yafang Dong, Yuta Takata, Kohei Sekine, Yusuke Yoshigoe, Yoichiro Kuninobu
    • Organizer
      第56回化学関連支部合同九州大会・外国人研究者交流 国際シンポジウム
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ポリマーを利用する蛍光色素ールイス酸間での平衡の調整によるマルチカラーおよび白色発光2019

    • Author(s)
      森 敏彰、吉越 裕介、國信 洋一郎
    • Organizer
      第56回化学関連支部合同九州大会・外国人研究者交流 国際シンポジウム
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 六員環ヘテロ芳香族化合物の2位選択的C-Hトリフルオロメチルチオ化反応の開発2019

    • Author(s)
      牟田 龍平、鳥越 尊、國信 洋一郎
    • Organizer
      第56回化学関連支部合同九州大会・外国人研究者交流 国際シンポジウム
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Hydrogen Bond-Accelerated meta-Selective C-H Borylation of Aromatic Compounds and Expression of Substrate Specificity2019

    • Author(s)
      Xu Lu, Yusuke Yoshigoe, Yoichiro Kuninobu
    • Organizer
      第56回化学関連支部合同九州大会・外国人研究者交流 国際シンポジウム
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 単純なビピリジン系配位子をもつイリジウム触媒による芳香族イオウ化合物のオルト位選択的C-Hボリル化2019

    • Author(s)
      曾 嘉林、鳥越 尊、國信 洋一郎
    • Organizer
      第56回化学関連支部合同九州大会・外国人研究者交流 国際シンポジウム
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Noncovalent Bond-Controlled Regioselective C-H Transformations2019

    • Author(s)
      Yoichiro Kuninobu
    • Organizer
      OMCOS 20
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 有機機能性分子合成を志向した新規炭素-水素結合変換反応の開発2019

    • Author(s)
      國信 洋一郎
    • Organizer
      CRESTxIoLセンタージョイントシンポジウム
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] ヨウ素化合物をハロゲン結合ドナーとして用いる発光材料の開発2019

    • Author(s)
      吉越 裕介、山川 健司、王 子嘉、金井 求、國信 洋一郎
    • Organizer
      第22回ヨウ素学会シンポジウム
    • Related Report
      2019 Annual Research Report
  • [Presentation] ポリマーを利用する蛍光色素-ルイス酸間での平衡の調整によるマルチカラーおよび白色発光2019

    • Author(s)
      森 敏彰、吉越 裕介、國信 洋一郎
    • Organizer
      第31回若手研究者のためのセミナー
    • Related Report
      2019 Annual Research Report
  • [Presentation] 六員環ヘテロ芳香族化合物の2位選択的C-Hトリフルオロメチルチオ化反応の開発2019

    • Author(s)
      牟田 龍平、鳥越 尊、國信 洋一郎
    • Organizer
      第31回若手研究者のためのセミナー
    • Related Report
      2019 Annual Research Report
  • [Presentation] 単純なビピリジン系配位子をもつイリジウム触媒による芳香族イオウ化合物のオルト位選択的C-Hボリル化2019

    • Author(s)
      曾 嘉林、鳥越 尊、國信 洋一郎
    • Organizer
      第31回若手研究者のためのセミナー
    • Related Report
      2019 Annual Research Report
  • [Presentation] Double C-H Silylation for the Synthesis of Silafluorenes by Borane Catalyst2019

    • Author(s)
      Yafang Dong, Yuta Takata, Kohei Sekine, Yusuke Yoshigoe, Yoichiro Kuninobu
    • Organizer
      第66回有機金属化学討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] ortho-Selective C-H Borylation of Thioanisole Derivatives Using Iridium Catalyst Bearing a Simple Bipyridine-Type Ligand2019

    • Author(s)
      Jialin Zeng, Takeru Torigoe, Yoichiro Kuninobu
    • Organizer
      第66回有機金属化学討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] ルイス酸―塩基相互作用を利用した蛍光色素のマルチカラー発光とポリマー担持による固体発光特性の制御2019

    • Author(s)
      森 敏彰、吉越 裕介、國信 洋一郎
    • Organizer
      第30回基礎有機化学討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 位置選択的なフッ素系官能基化反応の開発2019

    • Author(s)
      國信 洋一郎
    • Organizer
      第6回次世代の有機化学・広島シンポジウム
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] Lewis Acid-Catalyzed Synthesis of Silafluorenes from Biphenyls and Dihydrosilanes via Double Sila-Friedel-Crafts Reaction2019

    • Author(s)
      Yafang Dong, Yuta Takata, Kohei Sekine, Yusuke Yoshigoe, Yoichiro Kuninobu
    • Organizer
      第23回ケイ素化学協会シンポジウム
    • Related Report
      2019 Annual Research Report
  • [Presentation] 非共有結合性相互作用を利用する炭素-水素結合変換反応における位置選択性制御法の開発2019

    • Author(s)
      國信 洋一郎
    • Organizer
      統合物質創製化学研究推進機構 第5回国内シンポジウム
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] ホウ素触媒を用いる連続的なC-Hシリル化反応によるシラフルオレンの合成2019

    • Author(s)
      関根 康平、Yafang Dong、高田 雄大、吉越 裕介、國信 洋一郎
    • Organizer
      統合物質創製化学研究推進機構 第5回国内シンポジウム
    • Related Report
      2019 Annual Research Report
  • [Presentation] Development of C-H Bond Transformations Directed Towards the Synthesis of Organic Functional Molecules2019

    • Author(s)
      Yoichiro Kuninobu
    • Organizer
      東京大学大学院理学系研究科化学専攻雑誌会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] 触媒配位子による基質認識を利用する位置選択的なC-H結合変換反応の開発2019

    • Author(s)
      國信 洋一郎
    • Organizer
      新学術「ハイブリッド」第2回公開シンポジウム
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 有機機能性分子合成を志向した新規炭素-水素結合変換反応の開発2019

    • Author(s)
      國信 洋一郎
    • Organizer
      富山大学講演会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 水素結合部位をもつ配位子の改良によるメタ位選択的なC-Hボリル化反応の加速および基質特異性の発現2019

    • Author(s)
      盧 旭、吉越 裕介、井田 悠、西 光海、金井 求、國信 洋一郎
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] meta-Selective Functionalizations of Aromatic Compounds via Iridium-catalyzed C-H Borylation2019

    • Author(s)
      Jie Wang, Takeru Torigoe, Yoichiro Kuninobu
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 非共有結合性相互作用を利用した蛍光材料の開発2019

    • Author(s)
      高田 雄大、吉越 裕介、國信 洋一郎
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 非共有結合性相互作用を利用した蛍光材料の開発2019

    • Author(s)
      森 俊彰、吉越 裕介、國信 洋一郎
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 6員環ヘテロ芳香族化合物の位置選択的なC-Hトリフルオロメチルチオ化反応の開発2019

    • Author(s)
      牟田 龍平、鳥越 尊、國信 洋一郎
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] キノリン類に対するC2位選択的なトリフルオロメチル化反応の開発2019

    • Author(s)
      白井孝宏、國信洋一郎、金井求
    • Organizer
      日本薬学会第139年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] パラジウム触媒を用いた2,5-に置換イミダゾールのアリール化反応の開発2019

    • Author(s)
      藤後貴也、相馬洋平、國信洋一郎、金井求
    • Organizer
      日本薬学会第139年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 非共有結合性相互作用が引き起こす蛍光性π共役系分子の発光挙動変化2018

    • Author(s)
      吉越 裕介、山川 健司、金井 求、國信 洋一郎
    • Organizer
      第28回万有福岡シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] Development of Regioselective C-H Bond Transformations2018

    • Author(s)
      Yoichiro Kuninobu
    • Organizer
      The 2nd Japan-Spain Symposium on Organic Synthesis
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Control of Polarity and Improvement of Fluorescent Property of π-Conjugated Molecules Using Noncovalent Interaction2018

    • Author(s)
      Toshiaki Mori, Yusuke Yoshigoe, Kenji Yamakawa, Motomu Kanai, and Yoichiro Kuninobu
    • Organizer
      第55回化学関連支部合同九州大会・外国人研究者交流 国際シンポジウム
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 有機機能性分子合成を志向した新規炭素-水素結合変換反応の開発2018

    • Author(s)
      國信 洋一郎
    • Organizer
      愛媛大学第249回応用化学科セミナーミニシンポジウム
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 水素結合によるメタ位選択的C-Hボリル化反応の加速および基質特異性の発現2018

    • Author(s)
      盧 旭、吉越 裕介、井田 悠、西 光海、金井 求、國信 洋一郎
    • Organizer
      第30回若手研究者のためのセミナー
    • Related Report
      2018 Annual Research Report
  • [Presentation] meta-Selective Introduction of Functional Groups into Aromatic Compounds Based on Iridium-catalyzed C-H Borylation2018

    • Author(s)
      Jie Wang, Takeru Torigoe, Yoichiro Kuninobu
    • Organizer
      第30回若手研究者のためのセミナー
    • Related Report
      2018 Annual Research Report
  • [Presentation] マルチカラー発光を指向した非共有結合性相互作用を有する固体蛍光材料の開発2018

    • Author(s)
      森 敏彰、吉越 裕介、山川 健司、金井 求、國信 洋一郎
    • Organizer
      第30回若手研究者のためのセミナー
    • Related Report
      2018 Annual Research Report
  • [Presentation] 遷移金属触媒による炭素-水素結合変換反応2018

    • Author(s)
      國信 洋一郎
    • Organizer
      第12回触媒道場
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Formal meta-C-H Functionalizations via Iridium-catalyzed C-H Borylation2018

    • Author(s)
      Jie Wang, Takeru Torigoe, Yoichiro Kuninobu
    • Organizer
      第65回有機金属化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Hydrogen Bond-Accelerated meta-Selective C-H Borylation of Aromatic Compounds and Expression of Substrate Specificity2018

    • Author(s)
      Xu Lu, Yusuke Yoshigoe, Haruka Ida, Mitsumi Nishi, Motomu Kanai, Yoichiro Kuninobu
    • Organizer
      第65回有機金属化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 非共有結合性相互作用を利用する位置選択的なC-H結合変換反応の開発2018

    • Author(s)
      國信 洋一郎
    • Organizer
      第5回次世代の有機化学・広島シンポジウム
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] イリジウム触媒によるC-Hボリル化に基づく形式的なメタ位選択的C-H変換2018

    • Author(s)
      鳥越 尊、王 杰、國信 洋一郎
    • Organizer
      統合物質創製科学研究推進機構 第4回国内シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] 非共有結合性相互作用による分極制御を利用したマルチカラー蛍光分子の開発2018

    • Author(s)
      森 敏彰、吉越 裕介、山川 健司、金井 求、國信 洋一郎
    • Organizer
      統合物質創製科学研究推進機構 第4回国内シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] メタ位選択的なC-Hボリル化反応における反応の加速と基質特異性の発現2018

    • Author(s)
      盧 旭、吉越 裕介、井田 悠、西 光海、金井 求、國信 洋一郎
    • Organizer
      統合物質創製科学研究推進機構 第4回国内シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] Noncovalent Bond-Controlled Regioselective C-H Transformations2018

    • Author(s)
      Yoichiro Kuninobu
    • Organizer
      International Congress on Pure & Applied Chemistry Langkawi (ICPAC Langkawi 2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Noncovalent Bond-Controlled Regioselective C-H Transformations2018

    • Author(s)
      Yoichiro Kuninobu
    • Organizer
      18th Tateshina Conference
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Noncovalent Bond-Controlled Regioselective C-H Transformations2018

    • Author(s)
      Yoichiro Kuninobu
    • Organizer
      The 13th International Symposium on Organic Reactions (ICPAC Langkawi 2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 含窒素芳香族化合物の位置選択的なC-Hトリフルオロメチルチオ化反応の開発2018

    • Author(s)
      牟田 龍平、鳥越 尊、國信 洋一郎
    • Organizer
      第45回有機典型元素化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Regioselective C-H Trifluoromethylation of 6-Membered Heteroaromatic Compounds2018

    • Author(s)
      Yoichiro Kuninobu
    • Organizer
      International Congress on Pure & Applied Chemistry (ICPAC 2018), Cambodia
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Control of Solid-state Fluorescent Properties of π-Conjugated Molecules by Non-covalent Bonding2018

    • Author(s)
      Yusuke Yoshigoe, Takeshi Yamakawa, Zijia Wang, Motomu Kanai, Yoichiro Kuninobu
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Noncovalent Bond-Controlled Regioselective C-H Borylation2017

    • Author(s)
      Yoichiro Kuninobu
    • Organizer
      International Symposium on Pure & Applied Chemistry (ISPAC 2017), Viet Num
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Noncovalent Bond-Controlled Regioselective C-H Borylation2017

    • Author(s)
      Yoichiro Kuninobu, Haruka Ida, Hong-Liang Li, Mitsumi Nishi and Motomu Kanai
    • Organizer
      Organometallic Chemistry Directed Towards Organic Synthesis (OMCOS19), Korea
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 有機機能性分子合成を志向した新規炭素-水素結合変換反応の開発2017

    • Author(s)
      國信 洋一郎
    • Organizer
      第29回若手研究者のためのセミナー
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 安価な鉄塩によって触媒される2-フェニルピリジンのオルト位選択的C-Hホウ素化2017

    • Author(s)
      吉越裕介, 國信 洋一郎
    • Organizer
      第29回若手研究者のためのセミナー
    • Related Report
      2017 Annual Research Report
  • [Presentation] ピコリン酸アミド配位子をもつパラジウム触媒によるアルデヒドと有機ハロゲン化物からのヘテロアリールケトン合成2017

    • Author(s)
      若木貴行、藤後貴也、吉留大輔、國信洋一郎、金井求
    • Organizer
      第64回有機金属化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Development of C-H Bond Transformations Directed Towards the Synthesis of Organic Functional Molecules2017

    • Author(s)
      Yoichiro Kuninobu
    • Organizer
      Lecture at Tsinghua University, China
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Development of C-H Bond Transformations Directed Towards the Synthesis of Organic Functional Molecules2017

    • Author(s)
      Yoichiro Kuninobu
    • Organizer
      Lecture at Peking University, China
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Development of C-H Bond Transformations Directed Towards the Synthesis of Organic Functional Molecules2017

    • Author(s)
      Yoichiro Kuninobu
    • Organizer
      Lecture at Institute of Chemistry, Chinese Academy of Sciences, China
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 有機機能性分子合成を志向した新規炭素-水素結合変換反応の開発2017

    • Author(s)
      國信 洋一郎
    • Organizer
      第4回次世代の有機化学・広島シンポジウム
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] ホウ素化2‐フェニルピリジン類の固相相転移とその機構解明2017

    • Author(s)
      吉越裕介, 須崎裕司、小坂田耕太郎、國信 洋一郎
    • Organizer
      統合物質創製化学研究推進機構 第3回国内シンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] 有機機能性分子合成を志向した新規炭素-水素結合変換反応の開発2017

    • Author(s)
      國信 洋一郎
    • Organizer
      第44回有機典型元素化学討論会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Photo-induced Coloring of ortho-Borylated 2-Phenylpyridines2017

    • Author(s)
      Yusuke Yoshigoe, Yuji Suzaki, Kohtaro Osakada, Yoichiro Kuninobu
    • Organizer
      IRCCS-JST CREST Joint Symposium “Chemical Sciences facing a difficult challenge”
    • Related Report
      2017 Annual Research Report
  • [Book] ファインケミカルシリーズ「有機フッ素化合物の最新動向」2018

    • Author(s)
      國信 洋一郎
    • Total Pages
      7
    • Publisher
      シーエムシー出版
    • Related Report
      2018 Annual Research Report
  • [Book] ChemGrowing2017

    • Author(s)
      國信洋一郎
    • Total Pages
      4
    • Publisher
      和光純薬
    • Related Report
      2017 Annual Research Report
  • [Remarks] 國信研究室ホームページ(日本語)

    • URL

      https://kuninobu-lab.weebly.com/

    • Related Report
      2019 Annual Research Report 2018 Annual Research Report
  • [Remarks] 國信研究室ホームページ(英語)

    • URL

      https://kuninobu-lab-english.weebly.com/

    • Related Report
      2019 Annual Research Report 2018 Annual Research Report
  • [Remarks] 國信研究室HP(日本語)

    • URL

      http://kuninobu-lab.cm.kyushu-u.ac.jp/

    • Related Report
      2017 Annual Research Report
  • [Remarks] 國信研究室HP(英語)

    • URL

      http://kuninobu-lab-english.cm.kyushu-u.ac.jp/

    • Related Report
      2017 Annual Research Report
  • [Patent(Industrial Property Rights)] 発光色調の制御方法2019

    • Inventor(s)
      國信 洋一郎、森 俊彰、吉越 裕介
    • Industrial Property Rights Holder
      國信 洋一郎、森 俊彰、吉越 裕介
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2019-034658
    • Filing Date
      2019
    • Related Report
      2018 Annual Research Report
  • [Patent(Industrial Property Rights)] 蛍光を有する複合体2018

    • Inventor(s)
      國信洋一郎、金井求、山川健司、吉越裕介、王子嘉ら
    • Industrial Property Rights Holder
      國信洋一郎、金井求、山川健司、吉越裕介、王子嘉ら
    • Industrial Property Rights Type
      特許
    • Filing Date
      2018
    • Related Report
      2018 Annual Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] 蛍光を有する複合体2017

    • Inventor(s)
      國信 洋一郎、金井 求、山川 健司、王 子嘉、吉越 裕介
    • Industrial Property Rights Holder
      國信 洋一郎、金井 求、山川 健司、王 子嘉、吉越 裕介
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2017-161912
    • Filing Date
      2017
    • Related Report
      2017 Annual Research Report

URL: 

Published: 2017-04-28   Modified: 2021-02-19  

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