| Budget Amount *help |
¥18,850,000 (Direct Cost: ¥14,500,000、Indirect Cost: ¥4,350,000)
Fiscal Year 2019: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2018: ¥6,240,000 (Direct Cost: ¥4,800,000、Indirect Cost: ¥1,440,000)
Fiscal Year 2017: ¥8,970,000 (Direct Cost: ¥6,900,000、Indirect Cost: ¥2,070,000)
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| Outline of Final Research Achievements |
(1) We found that Zn-tetra(resorcinol)porphyrin and tetrakis(p-pyridylethynyl)cavitand selectively self-assemble into a 1:2 capsule based on hydrogen bonds or a 2:2 capsule based on hydrogen bonds and coordination bonds with DABCO, which encapsulate different two or three guest molecules. (2) We found that Rh-tetra(aryl)porphyrin and tetra(m-pyridyl)cavitand self-assemble into a 4:1 complex based on Rh-N coordination bonds, which functions as a molecular gear with large cavity. (3) We found that tetrakis(p-pyridylphenyl)cavitand and Pd((R)-BINAP)(OTf)2 self-assemble into a 2:4 chiral capsule based on Pd-N coordination bonds, which induces supramolecular chirality with respect to prochiral biphenyl guests by diastereomeric encapsulation.
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