| Budget Amount *help |
¥18,590,000 (Direct Cost: ¥14,300,000、Indirect Cost: ¥4,290,000)
Fiscal Year 2019: ¥5,850,000 (Direct Cost: ¥4,500,000、Indirect Cost: ¥1,350,000)
Fiscal Year 2018: ¥5,850,000 (Direct Cost: ¥4,500,000、Indirect Cost: ¥1,350,000)
Fiscal Year 2017: ¥6,890,000 (Direct Cost: ¥5,300,000、Indirect Cost: ¥1,590,000)
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| Outline of Final Research Achievements |
The bond cleavage processes of metal bound hypochlorite were studied to reveal the mechanism determining the bond cleavage fashion of various metal bound terminal oxidants. The reactions of heme with hypochlorite were studied with various spectroscopic methods at low temperature. The products from these reactions were also analyzed in detail. These analyses allowed us to propose a new mechanism, which can predict the bond cleavage fashion of various terminal oxidants. In addition, the mechanism controlling the reactivity of the metal bound terminal oxidants was studied with heme complexes. The reactivity of the terminal oxidants can be interpreted by the orbital interactions of the metal d-orbitals with ligand orbitals.
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