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Construction of nanostructures using polymer sheets of electroresponsive columnar liquid crystals

Research Project

Project/Area Number 17H03035
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Functional solid state chemistry
Research InstitutionChiba University

Principal Investigator

Kishikawa Keiki  千葉大学, 大学院工学研究院, 教授 (40241939)

Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥18,330,000 (Direct Cost: ¥14,100,000、Indirect Cost: ¥4,230,000)
Fiscal Year 2019: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2018: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2017: ¥11,700,000 (Direct Cost: ¥9,000,000、Indirect Cost: ¥2,700,000)
Keywords強誘電性 / 液晶 / 柱状相 / 電場応答 / ポリマーシート / 記録素子 / 超分子 / 自己組織化 / 電圧応答 / ナノ構造 / ポリマー / 分極 / 第二次高調波発生 / ナノ材料 / 柱状構造
Outline of Final Research Achievements

It is necessary to maintain a nano-level polarized state in liquid crystal compounds to realize high-density memory devices with electric field response, but no practical compounds have been found at present. In this study, we have realized ferroelectricity (a property that polarizes in response to an external voltage and maintains its polarized state even after voltage removal) in an optically active urea derivative. Furthermore, by comparing the polarity and stability of optically active and optically inactive derivatives, we have succeeded in elucidating the mechanism for generation of the ferroelectricity.

Academic Significance and Societal Importance of the Research Achievements

生体内で行われているような「ナノの世界で構造体を形成すること」が今後の産業や医療の技術において、革新的な発展を生むと考えられる。本研究の成果は、非接触で液晶シート上へのナノレベルの情報記録をする基礎技術の成功であり、1)ナノレベルの情報記録、2)重合性分子の配置、3)光重合によるナノ構造体の構築、という方法論の第一段階の達成に相当する。さらに、本研究では、新しい有機圧電体を作製する方法の開発にも成功している。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (60 results)

All 2020 2019 2018 2017

All Journal Article (17 results) (of which Peer Reviewed: 17 results,  Open Access: 1 results,  Acknowledgement Compliant: 3 results) Presentation (42 results) (of which Int'l Joint Research: 6 results,  Invited: 3 results) Patent(Industrial Property Rights) (1 results) (of which Overseas: 1 results)

  • [Journal Article] Full-Color Magnetic Nanoparticles Based on Holmium-Doped Polymers2020

    • Author(s)
      Kohaku Kotona、Inoue Mizuki、Kanoh Hirofumi、Taniguchi Tatsuo、Kishikawa Keiki、Kohri Michinari
    • Journal Title

      ACS Applied Polymer Materials

      Volume: 2 Issue: 5 Pages: 1800-1806

    • DOI

      10.1021/acsapm.0c00038

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of liquid crystal nanocapsules by polymerization of oil-in-water emulsion monomer droplets2020

    • Author(s)
      R. Kojima, S. Hidaka, M. Taira, M. Kohri, *T. Taniguchi, K Kishikawa, T. Karatsu, E. Okabe, and F. Kondo
    • Journal Title

      J. Colloid Interface Sci.

      Volume: 563 Pages: 122-130

    • DOI

      10.1016/j.jcis.2019.12.050

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Does introduction of a bent tail stabilize biaxiality and lateral switching behavior of smectic A liquid crystal phases of rodlike molecules?2019

    • Author(s)
      C. Koga, M. Kohri, T. Taniguchi, and *K. Kishikawa
    • Journal Title

      J. Phys. Chem. B

      Volume: 123 Issue: 19 Pages: 4324-4332

    • DOI

      10.1021/acs.jpcb.9b00589

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Artificial melanin particles: new building blocks for biomimetic structural coloration2019

    • Author(s)
      Kohri Michinari
    • Journal Title

      Polymer Journal

      Volume: 51 Issue: 11 Pages: 1127-1135

    • DOI

      10.1038/s41428-019-0231-2

    • NAID

      40022176636

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nanogel particle-based lanthanide composites for transparent magnetic materials2019

    • Author(s)
      Kohri Michinari、Aoki Yukika、Kohaku Kotona、Kishikawa Keiki
    • Journal Title

      Materials Letters

      Volume: 254 Pages: 278-281

    • DOI

      10.1016/j.matlet.2019.07.090

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Acid-induced control of surface properties using a catecholic silane coupling reagent2019

    • Author(s)
      *M. Kohri, S. Irie, S. Yamazaki, K. Kohaku, T. Taniguchi, and K. Kishikawa
    • Journal Title

      Chem. Lett.

      Volume: 48 Issue: 6 Pages: 551-554

    • DOI

      10.1246/cl.190138

    • NAID

      130007659779

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Polarity-adjustable Columnar Liquid Crystalline Compound by Intermittent Voltage Application2019

    • Author(s)
      Ohno Takaya、Nagaoka Nozomi、Kohri Michinari、Taniguchi Tatsuo、Kishikawa Keiki
    • Journal Title

      Chemistry Letters

      Volume: 48 Issue: 4 Pages: 315-318

    • DOI

      10.1246/cl.180982

    • NAID

      130007624456

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of photochromic liquid core nanocapsules based on theoretical design2019

    • Author(s)
      Tsuru Yosuke、Kohri Michinari、Taniguchi Tatsuo、Kishikawa Keiki、Karatsu Takashi、Hayashi Masaki
    • Journal Title

      Journal of Colloid and Interface Science

      Volume: 547 Pages: 318-329

    • DOI

      10.1016/j.jcis.2019.04.008

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ellipsoidal Artificial Melanin Particles as Building Blocks for Biomimetic Structural Coloration2019

    • Author(s)
      Kohri Michinari、Tamai Yuki、Kawamura Ayaka、Jido Keita、Yamamoto Mikiya、Taniguchi Tatsuo、Kishikawa Keiki、Fujii Syuji、Teramoto Naozumi、Ishii Haruyuki、Nagao Daisuke
    • Journal Title

      Langmuir

      Volume: 未定 Issue: 16 Pages: 5574-5580

    • DOI

      10.1021/acs.langmuir.9b00400

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Adhesion Control of Branched Catecholic Polymers by Acid Stimulation2018

    • Author(s)
      Kohri Michinari、Yamazaki Shigeaki、Irie Saki、Teramoto Naozumi、Taniguchi Tatsuo、Kishikawa Keiki
    • Journal Title

      ACS Omega

      Volume: 3 Issue: 12 Pages: 16626-16632

    • DOI

      10.1021/acsomega.8b02768

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Melanin Precursor Influence on Structural Colors from Artificial Melanin Particles: PolyDOPA, Polydopamine, and Polynorepinephrine2018

    • Author(s)
      Iwasaki Takeshi、Tamai Yuki、Yamamoto Mikiya、Taniguchi Tatsuo、Kishikawa Keiki、Kohri Michinari
    • Journal Title

      Langmuir

      Volume: 34 Issue: 39 Pages: 11814-11821

    • DOI

      10.1021/acs.langmuir.8b02444

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Magnetically Responsive Polymer Network Constructed by Poly(acrylic acid) and Holmium2018

    • Author(s)
      Kohri Michinari、Yanagimoto Kenshi、Kohaku Kotona、Shiomoto Shohei、Kobayashi Motoyasu、Imai Akira、Shiba Fumiyuki、Taniguchi Tatsuo、Kishikawa Keiki
    • Journal Title

      Macromolecules

      Volume: 51 Issue: 17 Pages: 6740-6745

    • DOI

      10.1021/acs.macromol.8b01550

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Polydopamine-Based 3D Colloidal Photonic Materials: Structural Color Balls and Fibers from Melanin-Like Particles with Polydopamine Shell Layers2017

    • Author(s)
      Kohri Michinari、Yanagimoto Kenshi、Kawamura Ayaka、Hamada Kosuke、Imai Yoshihiko、Watanabe Takaichi、Ono Tsutomu、Taniguchi Tatsuo、Kishikawa Keiki
    • Journal Title

      ACS Applied Materials & Interfaces

      Volume: 10 Issue: 9 Pages: 7640-7648

    • DOI

      10.1021/acsami.7b03453

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A chemiluminescence sensor with signal amplification based on a self-immolative reaction for the detection of fluoride ion at low concentrations2017

    • Author(s)
      Hisamatsu Shugo、Suzuki Shinichi、Kohmoto Shigeo、Kishikawa Keiki、Yamamoto Yusuke、Motokawa Ryuhei、Yaita Tsuyoshi
    • Journal Title

      Tetrahedron

      Volume: 73 Issue: 27-28 Pages: 3993-3998

    • DOI

      10.1016/j.tet.2017.05.084

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structural color tuning: Mixing melanin-like particles with different diameters to create neutral colors2017

    • Author(s)
      A. Kawamura, M. Kohri, S. Yoshioka, T. Taniguchi, and K. Kishikawa
    • Journal Title

      Langmuir

      Volume: 33 Issue: 15 Pages: 3824-3830

    • DOI

      10.1021/acs.langmuir.7b00707

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Bright structural color films independent of background prepared by the dip-coating of biomimetic melanin-like particles having polydopamine shell layers2017

    • Author(s)
      M. Kohri, S. Yamazaki, A. Kawamura, T. Taniguchi, and K. Kishikawa
    • Journal Title

      Colloids Surf. A: Physicochem. Eng. Aspects

      Volume: - Pages: 564-569

    • DOI

      10.1016/j.colsurfa.2017.03.035

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Structural Color Materials from Polydopamine-Inorganic Hybrid Thin Films Inspired by Rock Pigeon Feathers2017

    • Author(s)
      河村彩香,桑折道済,奥博行,濵田紘佑,中川恵介,谷口竜王,岸川圭希
    • Journal Title

      KOBUNSHI RONBUNSHU

      Volume: 74 Issue: 1 Pages: 54-58

    • DOI

      10.1295/koron.2016-0044

    • NAID

      130005296434

    • ISSN
      0386-2186, 1881-5685
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 屈曲した末端鎖の導入による二軸性スメクチックA相の実現2019

    • Author(s)
      古賀千晴・桑折道済・谷口竜王・岸川圭希
    • Organizer
      第9回CSJ化学フェスタ2019
    • Related Report
      2019 Annual Research Report
  • [Presentation] 電場応答性カラムナー液晶における二重螺旋構造の発現と分極緩和の抑制2019

    • Author(s)
      増田匡哉・桑折道済・岸川圭希
    • Organizer
      第9回CSJ化学フェスタ2019
    • Related Report
      2019 Annual Research Report
  • [Presentation] 強誘電性カラムナー液晶相の発現メカニズム2019

    • Author(s)
      秋山吾篤・慈道圭太・桑折道済・谷口竜王・岸川圭希
    • Organizer
      第9回CSJ化学フェスタ2019
    • Related Report
      2019 Annual Research Report
  • [Presentation] ラセミ体分岐アルキル鎖の導入による強誘電性カラムナー液晶相の発現2019

    • Author(s)
      森谷美優・桑折道済・谷口竜王・岸川圭希
    • Organizer
      第9回CSJ化学フェスタ2019
    • Related Report
      2019 Annual Research Report
  • [Presentation] 屈曲した末端鎖の導入による二軸性スメクチックA相の実現2019

    • Author(s)
      古賀千晴・桑折道済・谷口竜王・岸川圭希
    • Organizer
      2019年日本液晶学会討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] カラムナー液晶高分子薄膜における軸方向操作および表面機能制御2019

    • Author(s)
      金田有義・桑折道済・谷口竜王・岸川圭希
    • Organizer
      2019年日本液晶学会討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 強誘電性カラムナー液晶相の発現メカニズム2019

    • Author(s)
      秋山吾篤・慈道圭太・桑折道済・谷口竜王・岸川圭希
    • Organizer
      2019年日本液晶学会討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] ラセミ体分岐アルキル鎖の導入による強誘電性カラムナー相の発現2019

    • Author(s)
      森谷美優・桑折道済・岸川圭希
    • Organizer
      2019年日本液晶学会討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] キラリティー導入によるカラムナー液晶相における二重螺旋構造の自己組織化2019

    • Author(s)
      増田匡哉・桑折道済・岸川圭希
    • Organizer
      2019年日本液晶学会討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] ラセミ体分岐アルキル鎖の導入による強誘電性カラムナー相の発現2019

    • Author(s)
      森谷美優・桑折道済・岸川圭希
    • Organizer
      第23回液晶化学研究会シンポジウム
    • Related Report
      2019 Annual Research Report
  • [Presentation] 強誘電性カラムナー液晶相の発現メカニズム2019

    • Author(s)
      秋山吾篤・慈道圭太・桑折道済・谷口竜王・岸川圭希
    • Organizer
      第23回液晶化学研究会シンポジウム
    • Related Report
      2019 Annual Research Report
  • [Presentation] キラリティー導入によるカラムナー液晶相の二重螺旋構造の形成2019

    • Author(s)
      増田匡哉・桑折道済・岸川圭希
    • Organizer
      第23回液晶化学研究会シンポジウム
    • Related Report
      2019 Annual Research Report
  • [Presentation] 屈曲した末端鎖の導入による二軸性スメクチックA相の実現2019

    • Author(s)
      古賀千晴・桑折道済・谷口竜王・岸川圭希
    • Organizer
      第23回液晶化学研究会シンポジウム
    • Related Report
      2019 Annual Research Report
  • [Presentation] 電圧応答性カラムナー液晶を用いた分極薄膜の作製2019

    • Author(s)
      金田有義・桑折道済・谷口竜王・岸川圭希
    • Organizer
      第23回液晶化学研究会シンポジウム
    • Related Report
      2019 Annual Research Report
  • [Presentation] キラルドーパントによるブルー相の安定化2019

    • Author(s)
      岸川圭希
    • Organizer
      第6回千葉大学キラリティーネットワーク研究会後援会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] パーフルオロアレーン-アレーン相互作用および屈曲した末端鎖の導入による強誘電性二軸性スメクチックA相の実現2018

    • Author(s)
      古賀千晴・桑折道済・谷口竜王・岸川圭希
    • Organizer
      第22回液晶化学研究会シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] チオール-エンクリック反応を用いた分子間架橋による電場応答性カラムナー液晶相の安定化2018

    • Author(s)
      金田有義・桑折道済・岸川圭希
    • Organizer
      第22回液晶化学研究会シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] Generation of a “Mille-Feuille” structure by shape-assisted self-organization between two nematic phases2018

    • Author(s)
      K. Kishikawa, Y. Yamamoto, G. Watanabe, A. Kawamura, M. Kohri, T. Taniguchi
    • Organizer
      27th International Liquid Crystal Conference
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Realization of ferroelectric biaxial smectic A phases? by introducing perfluoroarene-arene interaction? and a bent terminal chain2018

    • Author(s)
      C. Koga, M. Kohri, T. Taniguchi, K. Kishikawa
    • Organizer
      27th International Liquid Crystal Conference
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Fixation of Electro-Responsive Columnar Liquid Crystal Phases by Thiol-ene Click Reaction2018

    • Author(s)
      A. Kaneda, M. Kohri, T. Taniguchi, K. Kishikawa
    • Organizer
      27th International Liquid Crystal Conference
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Spontaneous chiral symmetry breaking in columnar liquid crystals by intercolumnar interlocking2018

    • Author(s)
      H. Nakagomi, M. Kohri, T. Taniguchi, K. Kishikawa
    • Organizer
      27th International Liquid Crystal Conference
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Stabilization of the polar order by photo cross-linking of liquid crystalline ureas2018

    • Author(s)
      T. Ohno, M. Kohri, T. Taniguchi, K. Kishikawa
    • Organizer
      27th International Liquid Crystal Conference
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] アキラル分子のカラムナー液晶相における自発的不斉誘起2018

    • Author(s)
      中込央資・岸川圭希・谷口竜王・桑折道済
    • Organizer
      2018年日本液晶学会討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 低反応性末端ビニル基の光重合による極性柱状構造の固定化2018

    • Author(s)
      大野貴也・桑折道済・谷口竜王・岸川圭希
    • Organizer
      2018年日本液晶学会討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] カラムナー超構造の固定化とその電場応答挙動2018

    • Author(s)
      金田有義・桑折道済・谷口竜王・岸川圭希
    • Organizer
      2018年日本液晶学会討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 屈曲した末端鎖の導入による強誘電性二軸性スメクチックA相の実現2018

    • Author(s)
      古賀千晴・桑折道済・谷口竜王・岸川圭希
    • Organizer
      2018年日本液晶学会討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 分子の‘かたち’とその並び方2018

    • Author(s)
      岸川圭希
    • Organizer
      2018年日本液晶学会 小サマースクール
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Stabilization of blue phases by addition of chiral dopants2017

    • Author(s)
      K. Kishikawa
    • Organizer
      6th TOYOTA RIKEN International Workshop on Chirality in Soft Matter
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] キラルネマチック相を反応場に用いた自発的不斉誘起2017

    • Author(s)
      須貝加奈・桑折道済・谷口竜王・岸川圭希
    • Organizer
      第7回CSJ化学フェスタ2017
    • Related Report
      2017 Annual Research Report
  • [Presentation] キラリティーの導入による強誘電性カラムナー液晶の実現2017

    • Author(s)
      慈道圭太・桑折道済・谷口竜王・岸川圭希
    • Organizer
      第7回CSJ化学フェスタ2017
    • Related Report
      2017 Annual Research Report
  • [Presentation] 液晶性ウレアの光架橋による強誘電性カラムナー液晶相の実現2017

    • Author(s)
      大野貴也・岸川圭希・谷口竜王・桑折道済
    • Organizer
      第7回CSJ化学フェスタ2017
    • Related Report
      2017 Annual Research Report
  • [Presentation] 強誘電性二軸性ネマチック相・スメクチックA相の実現と低温化2017

    • Author(s)
      古賀千晴・谷口竜王・桑折道済・岸川圭希
    • Organizer
      第7回CSJ化学フェスタ2017
    • Related Report
      2017 Annual Research Report
  • [Presentation] カラムナー液晶相における自発的不斉誘起2017

    • Author(s)
      中込央資・岸川圭希・谷口竜王・桑折道済
    • Organizer
      第7回CSJ化学フェスタ2017
    • Related Report
      2017 Annual Research Report
  • [Presentation] 分子形状アシストによる2つのネマチック相間におけるミルフィーユ構造の発現2017

    • Author(s)
      岸川圭希・山本雄介・渡辺豪・河村彩香・桑折道済・谷口竜王
    • Organizer
      2017年日本液晶学会討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] キラルネマチック相を反応場に用いた自発的不斉誘起2017

    • Author(s)
      須貝加奈・桑折道済・谷口竜王・岸川圭希
    • Organizer
      2017年日本液晶学会討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] キラリティーの導入による強誘電性カラムナー液晶の実現2017

    • Author(s)
      慈道圭太・桑折道済・谷口竜王・岸川圭希
    • Organizer
      2017年日本液晶学会討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 大野貴也・岸川圭希・谷口竜王・桑折道済2017

    • Author(s)
      液晶性ウレアの光架橋による強誘電性カラムナー液晶相の実現
    • Organizer
      2017年日本液晶学会討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 強誘電性二軸性ネマチック相・スメクチックA相の実現と低温化2017

    • Author(s)
      古賀千晴・谷口竜王・桑折道済・岸川圭希
    • Organizer
      2017年日本液晶学会討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 中込央資・岸川圭希・谷口竜王・桑折道済2017

    • Author(s)
      カラムナー液晶相における自発的不斉誘起
    • Organizer
      2017年日本液晶学会討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] キラリティーの導入による強誘電性カラムナー液晶の実現2017

    • Author(s)
      慈道圭太・桑折道済・谷口竜王・岸川圭希
    • Organizer
      第21回液晶化学研究会シンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] 液晶性ウレアの光架橋による強誘電性カラムナー液晶相の実現2017

    • Author(s)
      大野貴也・岸川圭希・谷口竜王・桑折道済
    • Organizer
      第21回液晶化学研究会シンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] カラムナー液晶相における自発的不斉誘起2017

    • Author(s)
      中込央資・岸川圭希・谷口竜王・桑折道済
    • Organizer
      第21回液晶化学研究会シンポジウム
    • Related Report
      2017 Annual Research Report
  • [Patent(Industrial Property Rights)] Liquid crystal compound, liquid crystal composition and liquid crystal display device using same2017

    • Inventor(s)
      K. Kishikawa, et al.
    • Industrial Property Rights Holder
      K. Kishikawa, et al.
    • Industrial Property Rights Type
      特許
    • Filing Date
      2017
    • Related Report
      2017 Annual Research Report
    • Overseas

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Published: 2017-04-28   Modified: 2021-02-19  

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