Preparation of porous polymeric membrane with nano size pore

• Project/Area Number: 17H03115
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Polymer/Textile materials
• Research Institution: Osaka University
• Principal Investigator: Harada Akira 大阪大学, 産業科学研究所, 特任教授(常勤) (80127282)
• Project Period (FY): 2017-04-01 – 2020-03-31
• Project Status: Completed (Fiscal Year 2019)
• Budget Amount: ¥17,550,000 (Direct Cost: ¥13,500,000、Indirect Cost: ¥4,050,000); Fiscal Year 2019: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000); Fiscal Year 2018: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000); Fiscal Year 2017: ¥9,360,000 (Direct Cost: ¥7,200,000、Indirect Cost: ¥2,160,000)
• Keywords: シクロデキストリン / ポリマー膜 / 分離膜 / バルク重合 / 分子認識 / 分離 / 膜 / 環境汚染物質 / 超分子 / ホストーゲスト相互作用 / 多孔性材料 / ホスト－ゲスト / 薄膜

Outline of Final Research Achievements

We have demonstrated an efficient synthetic methodology to prepare polymeric membranes containing CDs. Bulk polymerization of ethyl acrylate containing peracetylated γ-CD (PAcγCD) yields a CD-based porous polymeric membrane [CD membrane (BP)]. Krypton adsorption measurements reveal that the CD membrane (BP) has a porous structure. The specific surface of the CD membrane (BP) is 10 times higher than that of a CD-based polymeric membrane prepared by solution casting using a solution containing poly(ethyl acrylate) and PAcγCD. Due to the large specific surface area of the CD membrane (BP) and molecular recognition of CD, we also demonstrate that the CD membrane (BP) can separate an environmental pollutant from water.

Academic Significance and Societal Importance of the Research Achievements

化学産業におけるエネルギー消費が年々増加し、そのエネルギー消費の約40%が蒸留操作による分離・精製に費やされている。混合物から分離・センシングを可能にする材料として、多孔性材料や高分子膜が知られているが、前者は溶媒に不溶であることから汎用性、製膜性、均一性が、後者は膜中の空孔サイズのコントロールが困難であった。本申請研究はこれらの問題を解決し、簡便にナノメートルサイズの空孔を持つ分離膜を作製した点が特徴である。

Research Products

• [Journal Article] Preparation of hydrophilic polymeric materials with movable cross-linkers and their mechanical property (2020)
  • Author(s): Ikura, R.; Osaki, M.; Yamaguchi, H.; Harada, A.; Takashima, Y.
  • Journal Title: Polymer Volume: accepted Pages: 122465-122465
  • DOI: 10.1016/j.polymer.2020.122465
  • Peer Reviewed / Open Access
• [Journal Article] Bulk Copolymerization of Host?Guest Monomers with Liquid-Type Acrylamide Monomers for Supramolecular Materials Applications (2020)
  • Author(s): Okano Nanami、Osaki Motofumi、Ikura Ryohei、Takashima Yoshinori、Yamaguchi Hiroyasu、Harada Akira
  • Journal Title: ACS Applied Polymer Materials Volume: 2 Issue: 4 Pages: 1553-1560
  • DOI: 10.1021/acsapm.9b01220
  • Peer Reviewed
• [Journal Article] Redox-responsive supramolecular polymeric networks having double-threaded inclusion complexes (2020)
  • Author(s): Aramoto Hikaru、Osaki Motofumi、Konishi Subaru、Ueda Chiharu、Kobayashi Yuichiro、Takashima Yoshinori、Harada Akira、Yamaguchi Hiroyasu
  • Journal Title: Chemical Science Volume: accepted Issue: 17 Pages: 4322-4331
  • DOI: 10.1039/c9sc05589d
  • Peer Reviewed / Open Access
• [Journal Article] Supramolecular self-healing materials from non-covalent cross-linking host?guest interactions (2020)
  • Author(s): Sinawang Garry、Osaki Motofumi、Takashima Yoshinori、Yamaguchi Hiroyasu、Harada Akira
  • Journal Title: Chemical Communications Volume: accepted Issue: 32 Pages: 4381-4395
  • DOI: 10.1039/d0cc00672f
  • Peer Reviewed / Open Access
• [Journal Article] Supramolecular Elastomers with Movable Cross-Linkers Showing High Fracture Energy Based on Stress Dispersion (2019)
  • Author(s): Ikura Ryohei、Park Junsu、Osaki Motofumi、Yamaguchi Hiroyasu、Harada Akira、Takashima Yoshinori
  • Journal Title: Macromolecules Volume: 52 Issue: 18 Pages: 6953-6962
  • DOI: 10.1021/acs.macromol.9b01198
  • Peer Reviewed
• [Journal Article] Preparation of cyclodextrin-based porous polymeric membrane by bulk polymerization of ethyl acrylate in the presence of cyclodextrin (2019)
  • Author(s): Kobayashi Yuichiro、Nakamitsu Yukie、Zheng Yongtai、Takashima Yoshinori、Yamaguchi Hiroyasu、Harada Akira
  • Journal Title: Polymer Volume: 177 Pages: 208-213
  • DOI: 10.1016/j.polymer.2019.06.015
  • Peer Reviewed
• [Journal Article] X-ray crystal structures of α-cyclodextrin?5-hydroxypentanoic acid, β-cyclodextrin?5-hydroxypentanoic acid, β-cyclodextrin?ε-caprolactone, and β-cyclodextrin?ε-caprolactam inclusion complexes (2019)
  • Author(s): Osaki Motofumi、Takashima Yoshinori、Kamitori Shigehiro、Yamaguchi Hiroyasu、Harada Akira
  • Journal Title: Journal of Inclusion Phenomena and Macrocyclic Chemistry Volume: 96 Issue: 1-2 Pages: 93-99
  • DOI: 10.1007/s10847-019-00953-3
  • Peer Reviewed
• [Journal Article] 新たな分子設計による自己修復材料の実現＜切ってもつながる、柔軟・強靭な新材料＞ (2019)
  • Author(s): 大崎 基史、高島 義徳、原田 明
  • Journal Title: プラスチックス Volume: 70 Pages: 37-42
  • Peer Reviewed
• [Journal Article] Preparation of Supramolecular Ionic Liquid Gels Based on Host-Guest Interactions and Their Swelling and Ionic Conductive Properties (2019)
  • Author(s): Sinawang, Garry; Kobayashi, Yuichiro; Zheng, Yongtai; Takashima, Yoshinori; Harada, Akira; Yamaguchi, Hiroyasu
  • Journal Title: Macromolecules Volume: in press Issue: 8 Pages: 2932-2938
  • DOI: 10.1021/acs.macromol.8b02395
  • Peer Reviewed
• [Journal Article] Mechanical and self-recovery properties of supramolecular ionic liquid elastomers based on host-guest interaction and correlation with ionic liquid content (2019)
  • Author(s): Sinawang, G.; Kobayashi, Y.; Osaki, M.; Takashima, Y.; Harada, A.; Yamaguchi, H.
  • Journal Title: RSC Advances Volume: 9 Pages: 22295-22301
  • Peer Reviewed
• [Journal Article] Self-Healing Alkyl Acrylate-Based Supramolecular Elastomers Cross-Linked via Host-Guest Interactions (2019)
  • Author(s): Suguru Nomimura、Motofumi Osaki、Junsu Park、Ryohei Ikura、Yoshinori Takashima、Hiroyasu Yamaguchi、Akira Harada
  • Journal Title: Macromolecules Volume: 印刷中 Issue: 7 Pages: 2659-2668
  • DOI: 10.1021/acs.macromol.9b00471
  • Peer Reviewed / Open Access
• [Journal Article] Cyclodextrin-Based Rotaxanes: from Rotaxanes to Polyrotaxanes and Further to Functional Materials (2019)
  • Author(s): Hashidzume, Akihito; Yamaguchi, Hiroyasu; Harada, Akira
  • Journal Title: European Journal of Organic Chemistry Volume: in press Issue: 21 Pages: 3344-3357
  • DOI: 10.1002/ejoc.201900090
  • Peer Reviewed
• [Journal Article] Mechanical properties of supramolecular polymeric materials cross-linked by donor?acceptor interactions (2019)
  • Author(s): Itano Misaki、Kobayashi Yuichiro、Takashima Yoshinori、Harada Akira、Yamaguchi Hiroyasu
  • Journal Title: Chemical Communications Volume: 55 Issue: 26 Pages: 3809-3812
  • DOI: 10.1039/c9cc01472a
  • Peer Reviewed / Open Access
• [Journal Article] Physical and Adhesion Properties of Supramolecular Hydrogels Cross-linked by Movable Cross-linking Molecule and Host-guest Interactions (2018)
  • Author(s): Kobayashi Yuichiro、Zheng Yongtai、Takashima Yoshinori、Yamaguchi Hiroyasu、Harada Akira
  • Journal Title: Chemistry Letters Volume: 47 Issue: 11 Pages: 1387-1390
  • DOI: 10.1246/cl.180646
  • NAID: 130007504952
  • Peer Reviewed / Open Access
• [Journal Article] Mechanical Properties of Supramolecular Polymeric Materials Formed by Cyclodextrins as Host Molecules and Cationic Alkyl Guest Molecules on the Polymer Side Chain (2018)
  • Author(s): Takashima Yoshinori、Otani Kohei、Kobayashi Yuichiro、Aramoto Hikaru、Nakahata Masaki、Yamaguchi Hiroyasu、Harada Akira
  • Journal Title: Macromolecules Volume: 51 Issue: 16 Pages: 6318-6326
  • DOI: 10.1021/acs.macromol.8b01410
  • Peer Reviewed / Open Access
• [Journal Article] Control of the threading ratio of cyclic molecules in polyrotaxanes consisting of poly(ethylene glycol) and α-cyclodextrins (2018)
  • Author(s): Kobayashi Yuichiro、Nakamitsu Yukie、Zheng Yongtai、Takashima Yoshinori、Yamaguchi Hiroyasu、Harada Akira
  • Journal Title: Chemical Communications Volume: 54 Issue: 51 Pages: 7066-7069
  • DOI: 10.1039/c8cc01776j
  • Peer Reviewed / Open Access
• [Journal Article] Visible Chiral Discrimination via Macroscopic Selective Assembly (2018)
  • Author(s): Zheng Yongtai、Kobayashi Yuichiro、Sekine Tomoko、Takashima Yoshinori、Hashidzume Akihito、Yamaguchi Hiroyasu、Harada Akira
  • Journal Title: Communications Chemistry Volume: 1 Issue: 1 Pages: 4-4
  • DOI: 10.1038/s42004-017-0003-x
  • Peer Reviewed / Open Access
• [Journal Article] Formation of Inclusion Complexes of Poly(hexafluoropropyl ether)s with Cyclodextrins (2018)
  • Author(s): Nomimura Suguru、Osaki Motofumi、Takashima Yoshinori、Yamaguchi Hiroyasu、Harada Akira
  • Journal Title: Chemistry Letters Volume: 47 Issue: 3 Pages: 322-325
  • DOI: 10.1246/cl.171112
  • NAID: 130006434120
  • ISSN: 0366-7022, 1348-0715
  • Peer Reviewed / Open Access
• [Journal Article] Multifunctional Stimuli-Responsive Supramolecular Materials with Stretching, Coloring, and Self-Healing Properties Functionalized via Host?Guest Interactions (2017)
  • Author(s): Takashima Yoshinori、Yonekura Koki、Koyanagi Kohei、Iwaso Kazuhisa、Nakahata Masaki、Yamaguchi Hiroyasu、Harada Akira
  • Journal Title: Macromolecules Volume: 50 Issue: 11 Pages: 4144-4150
  • DOI: 10.1021/acs.macromol.7b00875
  • Peer Reviewed / Open Access
• [Journal Article] A pseudo-rotaxane of α-cyclodextrin and a two-station axis molecule consisting of pyridinium and decamethylene moieties, and its deuteration in deuterium oxide (2017)
  • Author(s): Hashidzume Akihito、Kuse Akihiro、Oshikiri Tomoya、Adachi Seiji、Yamaguchi Hiroyasu、Harada Akira
  • Journal Title: Tetrahedron Volume: 73 Issue: 33 Pages: 4988-4993
  • DOI: 10.1016/j.tet.2017.05.044
  • Peer Reviewed / Open Access
• [Journal Article] Supramolecular Materials Cross-Linked by Host?Guest Inclusion Complexes: The Effect of Side Chain Molecules on Mechanical Properties (2017)
  • Author(s): Takashima Yoshinori、Sawa Yuki、Iwaso Kazuhisa、Nakahata Masaki、Yamaguchi Hiroyasu、Harada Akira
  • Journal Title: Macromolecules Volume: 50 Issue: 8 Pages: 3254-3261
  • DOI: 10.1021/acs.macromol.7b00266
  • Peer Reviewed / Open Access
• [Presentation] Preparation of Materials with Supramolecular Cross-linkingand Their Physical Properties (2019)
  • Author(s): Ryohei Ikura, Junsu Park, Motofumi Osaki, Hiroyasu Yamaguchi, Akira Harada, Yoshinori Takashima
  • Organizer: MATERIALS RESEARCH MEETING 2019 (MRM)
  • Int'l Joint Research
• [Presentation] Tough and Functional Supramolecular Materials from Polymer Mixtures with Host-guest Interaction between Cyclodextrin and Adamantane (2019)
  • Author(s): Junsu Park, Motofumi Osaki, Yoshinori Takashima, Akira Harada, Hiroyasu Yamaguchi
  • Organizer: MATERIALS RESEARCH MEETING 2019 (MRM)
  • Int'l Joint Research
• [Presentation] Supramolecular Ionic Liquid Elastomer based on Host-Guest Interactions (2019)
  • Author(s): Garry Sinawang, Yuichiro Kobayashi, Yoshinori Takashima, Akira Harada, Hiroyasu Yamaguchi
  • Organizer: MATERIALS RESEARCH MEETING 2019 (MRM)
  • Int'l Joint Research
• [Presentation] Relationship between the Dissociation Energy of Reversible Cross-links and Mechanical Properties of Supramolecular Hydrogels with Inclusion Complexes (2019)
  • Author(s): Subaru Konishi, Yoshinori Takashima, Akira Harada, Hiroyasu Yamaguchi
  • Organizer: MATERIALS RESEARCH MEETING 2019 (MRM)
  • Int'l Joint Research
• [Presentation] Design of Supramolecular Materials Based on Controlling Deformation of Reversible Cross-links and Their Mechanical Properties (2019)
  • Author(s): Yoshinori Takashima, Hiroyasu Yamaguchi, Hiroshi Uyama, Akira Harada
  • Organizer: The 7th International Conference on Bio-based Polymers
  • Int'l Joint Research
• [Presentation] Design of Supramolecular Materials Based on Controlling Deformation of Reversible Cross-links and Their Mechanical Properties (2019)
  • Author(s): Subaru Konishi, Yoshinori Takashima, Akira Harada, Hiroyasu Yamaguchi
  • Organizer: The 7th International Conference on Bio-based Polymers
  • Int'l Joint Research
• [Presentation] 可逆性架橋の変形制御を目指した超分子材料の分子設計とその物性評価 (2019)
  • Author(s): 小西 昴・髙島 義徳・原田 明・山口 浩靖
  • Organizer: 第67回 レオロジー討論会
• [Presentation] 1:2 ホストゲスト錯体で架橋されたヒドロゲルの酸化還元刺激応答性 (2019)
  • Author(s): 荒本 光・大崎 基史・小林 裕一郎・髙島 義徳・原 田明・山口 浩靖
  • Organizer: 第67回 レオロジー討論会
• [Presentation] 可動性架橋を用いた高分子材料の設計および力学特性評価 (2019)
  • Author(s): 以倉 崚平・朴 峻秀・大崎 基史・山口 浩靖・原田 明・高島 義徳
  • Organizer: 第67回 レオロジー討論会
• [Presentation] 疎水性シクロデキストリンを有するホストポリマーとゲストポリマーからなる機能性超分子材料 (2019)
  • Author(s): 朴 峻秀・大崎 基史・髙島 義徳・原田 明・山口 浩靖
  • Organizer: 第68回 高分子討論会
• [Presentation] 架橋点の会合・解離の制御に基づいた超分子材料の分子設計とその力学特性 (2019)
  • Author(s): 小西 昴・高島 義徳・原田 明・山口 浩靖
  • Organizer: 第9回CSJ化学フェスタ2019
• [Presentation] ホストゲスト相互作用を用いた高強度自己修復性ウレタン材料の作製 (2019)
  • Author(s): 金 昌明・以倉 崚平・Garry Sinawang・大 崎基史・高島 義徳・原田 明・山口 浩靖
  • Organizer: 第9回CSJ化学フェスタ2019
• [Presentation] 可動性架橋を持つ異種ポリマー混合材料の作製と力学物性評価 (2019)
  • Author(s): 以倉 崚平・朴 峻秀・大崎 基史・山口 浩靖・原田 明・高島 義徳
  • Organizer: 第68回 高分子討論会
• [Presentation] シクロデキストリン存在下におけるエチルアクリレートのバルク重合によるシクロデキストリン誘導体を用いた高分子分離膜の作製 (2019)
  • Author(s): 小林 裕一郎・髙島 義徳・山口 浩靖・原田 明
  • Organizer: 第68回 高分子討論会
• [Presentation] 無溶媒重合による超分子材料の作製とその力学特性評価 (2019)
  • Author(s): 以倉 崚平・朴 峻秀・大崎 基史・山口 浩靖・原田 明・高島 義徳
  • Organizer: 第8回JACI/GSC シンポジウム
• [Presentation] Host-guest Interaction between Hydrophobic Cyclodextrin and Adamantane for Electronic Devices (2019)
  • Author(s): 朴 峻秀・大崎 基史・高島 義徳・原田 明・山口 浩靖
  • Organizer: 第8回JACI/GSC シンポジウム
• [Presentation] Preparation of two kinds of supramolecular materials and their physical properties (2019)
  • Author(s): Ryohei Ikura, Junsu Park, Motofumi Osaki, Yoshinori Takashima, Akira Harada, Hiroyasu Yamaguchi
  • Organizer: 14th International Symposium on Macrocyclic and Supramolecular Chemistry (ISMSC2019)
  • Int'l Joint Research
• [Presentation] Supramolecular Materials via Host-guest Interaction by Mixing Host Polymer and Guest Polymer in Nano Scale: from Functions to Application (2019)
  • Author(s): Junsu Park, Motofumi Osaki, Yoshinori Takashima, Akira Harada, Hiroyasu Yamaguchi
  • Organizer: 14th International Symposium on Macrocyclic and Supramolecular Chemistry (ISMSC2019)
  • Int'l Joint Research
• [Presentation] Self-healing properties of a supramolecular hydrogel consisting of polyrotaxane cross-linked by host-guest interactions. (2019)
  • Author(s): Yuichiro Kobatashi, Yoshinori Takashima, Hiroyasu Yamaguchi, Akira Harada
  • Organizer: 第68回高分子学会年次大会
• [Presentation] シクロデキストリンとアルキル修飾カチオン性ゲストの包接錯体を架橋点とした超分子材料の力学物性 2Pd060 (2019)
  • Author(s): 小西昴・荒本光・髙島義徳・原田明・山口浩靖
  • Organizer: 第68回高分子学会年次大会
• [Presentation] Preparation of Polymeric Materials with Movable Cross-Linking and Their Mechanical Properties (2019)
  • Author(s): IKURA, Ryohei; MURAYAMA, Shunsuke; PARK, Junsu; OSAKI, Motofumi; TAKASHIMA, Yoshinori; YAMAGUCHI, Hiroyasu; HARADA, Akira; IKEMOTO, Yuka; MATSUBA, Go
  • Organizer: German-Japanese Workshop “Aquatic Materials Made to Order”
  • Int'l Joint Research
• [Presentation] Selective adsorption of environmental pollutant by polyethyl acrylate membranes obtained by bulk polymerization of ethyl acrylate in the presence of cyclodextrin (2019)
  • Author(s): KOBAYASHI, Yuichiro; TAKASHIMA, Yoshinori; YAMAGUCHI, Hiroyasu; HARADA, Akira
  • Organizer: 日本化学会第100春季年会
• [Presentation] 酸化還元応答性超分子ヒドロゲルの力学特性評価とその含水率依存性 (2019)
  • Author(s): 植田千晴・・小西昴・以倉崚平・大﨑基史・山口浩靖・原田明・池本夕佳・田中賢・髙島義徳
  • Organizer: 日本化学会第100春季年会
• [Presentation] 可動性架橋ネットワークを用いた異種混合ポリマー材料の力学特性評価 (2019)
  • Author(s): 河合優作・以倉崚平・山口浩靖・原田明・髙島義徳
  • Organizer: 日本化学会第100春季年会
• [Presentation] Design of polymeric materials using movable cross-linking and their mechanical properties (2019)
  • Author(s): IKURA, Ryohei; MURAYAMA, Shunsuke; PARK, Junsu; OSAKI, Motofumi; TAKASHIMA, Yoshinori; YAMAGUCHI, Hiroyasu; HARADA, Akira; IKEMOTO, Yuka; MATSUBA, Go
  • Organizer: 日本化学会第100春季年会
• [Presentation] Self-Healing Supramolecular Hydrogel: Polyrotaxane Cross-Linked By Host-Guest Interactions (2018)
  • Author(s): Yuichiro Kobayashi, Yoshinori Takashima, Hiroyasu Yamaguchi, Akira Harada
  • Organizer: 第28回日本MRS年次大会
  • Int'l Joint Research
• [Presentation] Visible chiral discrimination via macroscopic selective assembly (2018)
  • Author(s): Yongtai ZHENG, Yoshinori Takashima, Hiroyasu Yamaguchi, Akira Haradaa
  • Organizer: 第28回日本MRS年次大会
  • Int'l Joint Research
• [Presentation] Supramolecular polymeric materials functionalized by host-guest interactions and its mechanical properties (2018)
  • Author(s): Yoshinori Takashima, Hiroyasu Yamaguchi, Akira Harada
  • Organizer: The 12th SPSJ International Polymer Conference (IPC2018)
  • Int'l Joint Research
• [Presentation] Supramolecular ionic liquid gel using host-guest inclusion complexes with cyclodextrin (2018)
  • Author(s): Garry Sinawang, Yuichiro Kobayashi, Motofumi Osaki, Yoshinori Takashima, Hiroyasu Yamaguchi, Akira Harada
  • Organizer: The 12th SPSJ International Polymer Conference (IPC2018)
  • Int'l Joint Research
• [Presentation] Novel method to prepare hydrophobic cyclodextrin-based supramolecular materials (2018)
  • Author(s): Junsu Park, Yoshinori Takashima, Aoi Yamada, Takuya Katashima, Tadashi Inoue, Akira Harada, Hiroyasu Yamaguchi
  • Organizer: The 12th SPSJ International Polymer Conference (IPC2018)
  • Int'l Joint Research
• [Presentation] ホスト－ゲスト包接錯体で架橋されたイオン液体ゲル (2018)
  • Author(s): シナワン ガリー・小林 裕一郎・大崎 基史・高島 義徳・山口 浩靖・原田 明
  • Organizer: 第67回高分子討論会
• [Presentation] シクロデキストリンの包接錯体により架橋された超分子ヒドロゲルの力学物性と酸化還元応答性 (2018)
  • Author(s): 荒本 光・高島 義徳・原田 明・山口 浩靖
  • Organizer: 第67回高分子討論会
• [Presentation] シクロデキストリンモノマーを用いた無溶媒重合による超分子架橋材料の作製とその力学特性評価 (2018)
  • Author(s): 以倉 崚平・呑村 優・高島 義徳・原田 明・山口 浩靖
  • Organizer: 第67回高分子討論会
• [Presentation] 高分子の架橋制御により生み出される超分子ソフトマテリアルの機能 (2018)
  • Author(s): 高島 義徳・山口 浩靖・原田 明
  • Organizer: 第67回高分子討論会
• [Presentation] ホスト－ゲスト相互作用によって架橋されたポリロタキサンを含む超分子ゲルの自己修復性挙動 (2018)
  • Author(s): 小林裕一郎・高島義徳・山口 浩靖・原田 明
  • Organizer: 第67回高分子討論会
• [Presentation] 新規な作製方法を取り入れた疎水性シクロデキストリン超分子材料の物性評価 (2018)
  • Author(s): 朴 峻秀・高島義徳・原田 明・山口 浩靖
  • Organizer: 第67回高分子討論会
• [Presentation] シクロデキストリンと種々の疎水性分子を側鎖に導入した超分子ヒドロゲルの作製とその力学物性評価 (2018)
  • Author(s): 小西 昴・高島義徳・原田 明・山口 浩靖
  • Organizer: 第67回高分子討論会
• [Presentation] ビオロゲン修飾アルキル鎖とシクロデキストリンの包接錯体を架橋点とした超分子ヒドロゲル (2018)
  • Author(s): 荒本 光・高島 義徳・原田 明・山口 浩靖
  • Organizer: 第35回シクロデキストリンシンポジウム
• [Presentation] シクロデキストリン及び疎水性ゲスト分子の違いによる超分子ヒドロゲルの力学物性の変化 (2018)
  • Author(s): 高島 義徳・原田 明・山口 浩靖
  • Organizer: 第35回シクロデキストリンシンポジウム
• [Presentation] Self-Healing Supramolecular Hydrogel: Polyrotaxane Cross-Linked By Host-Guest Interactions (2018)
  • Author(s): Yuichiro Kobayashi, Yoshinori Takashima, Hiroyasu Yamaguchi, Akira Harada
  • Organizer: First International Conference on 4D Materials and Systems (4DMS)
  • Int'l Joint Research
• [Presentation] Visible Chiral Discrimination via Macroscopic Selective Assembly (2018)
  • Author(s): Yongtai Zheng, Yuichiro Kobayashi, Tomoko Sekine, Yoshinori Takashima, Akihito Hashidzume, Hiroyasu Yamaguchi, Akira Harada
  • Organizer: The 8th International Symposium on Polymer Chemistry (PC2018)
  • Int'l Joint Research
• [Presentation] シクロデキストリンモノマーを用いた無溶媒重合による超分子架橋材料の作製とその力学特性評価 (2018)
  • Author(s): 以倉 崚平・呑村 優・高島 義徳・原田 明・山口 浩靖
  • Organizer: 第67回高分子学会年次大会
• [Presentation] αCDとPEGからなるポリロタキサンの貫通率の制御 (2018)
  • Author(s): 小林 裕一郎・中満 幸恵・高島 義徳・山口 浩靖・原田 明
  • Organizer: 第67回高分子学会年次大会
• [Presentation] シクロデキストリンを用いたメカニカル材料の構築 (2018)
  • Author(s): 原田明
  • Organizer: 日本化学会第95春季年会
  • Invited
• [Presentation] 無溶媒条件でのポリアクリルアミド系超分子材料の作製とその力学特性評価 (2018)
  • Author(s): 岡野七海・高島義徳・原田明・山口浩靖
  • Organizer: 日本化学会第95春季年会
• [Presentation] 可動性架橋点に有する超分子材料の無溶媒重合による作製とその力学特性評価 (2018)
  • Author(s): 以倉崚平・呑村優・高島義徳・原田明・山口浩靖
  • Organizer: 日本化学会第95春季年会
• [Presentation] Self-healable polymeric materials based on the interaction between cyclodextrins and guest molecules (2017)
  • Author(s): Yoshinori Takashima, Suguru Nomimura, Hiroyasu Yamaguchi, Akira Harada
  • Organizer: 9th Asian Cyclodextrin Conference (9ACC)
  • Int'l Joint Research
• [Presentation] ホスト（シクロデキストリン）-ゲストゲルの調製 (2017)
  • Author(s): 原田 明・高島 義徳・山口 浩靖
  • Organizer: 第26回ポリマー材料フォーラム
  • Invited
• [Presentation] 疎水性シクロデキストリンを用いた包接錯体を架橋点とする超分子エラストマーの作製と物性評価 (2017)
  • Author(s): 呑村 優・荒本光・以倉 峻平・高島 義徳・山口 浩靖・原田 明
  • Organizer: 第7回CSJ化学フェスタ2017
• [Presentation] 無溶媒条件下における可動性架橋材料の作製 (2017)
  • Author(s): 以倉 崚平・高島義徳・原田 明・山口 浩靖
  • Organizer: 第7回CSJ化学フェスタ2017
• [Presentation] 疎水性シクロデキストリンを用いた無溶媒重合法による超分子エラストマーの作製と物性評価 (2017)
  • Author(s): 呑村 優・荒本光・以倉 峻平・高島 義徳・山口 浩靖・原田 明
  • Organizer: 第66回高分子討論会
• [Presentation] シクロデキストリンモノマーを用いた無溶媒重合による超分子材料の作製とその力学特性評価 (2017)
  • Author(s): 以倉 崚平・高島義徳・原田 明・山口 浩靖
  • Organizer: 第66回高分子討論会
• [Presentation] 可動性架橋点を有する超分子材料の作製とその力学特性評価 (2017)
  • Author(s): 以倉 峻平・高島 義徳・原田 明・山口 浩靖
  • Organizer: 第63回 高分子研究発表会（神戸）
• [Presentation] 可動性架橋点を持つ超分子材料の作製とその力学特性評価 (2017)
  • Author(s): 以倉 崚平・高島 義徳・原田 明・山口 浩靖
  • Organizer: 第6回 JACI/GSCシンポジウム
• [Presentation] 無溶媒条件下における超分子エラストマーの作製 (2017)
  • Author(s): 以倉 崚平・呑村優・高島 義徳・原田 明・山口 浩靖
  • Organizer: 第15回ホスト-ゲスト・超分子シンポジウム SHGSC2017
• [Presentation] ロタキサン構造を架橋点に有する超分子材料の作製とその力学特性評価 (2017)
  • Author(s): 以倉 崚平・高島 義徳・山口 浩靖・原田 明
  • Organizer: 第66回高分子学会年次大会
• [Presentation] Supramolecular Materials: Self-healing and Stimuli-responsive Polymeric Materials through Host-Guest Interactions (2017)
  • Author(s): Akira Harada
  • Organizer: 253th ACS San Francisco
  • Int'l Joint Research / Invited
• [Book] Mechanically Responsive Materials for Soft Robotics (2020)
  • Author(s): Harada, A.; Takashima, Y.; Hashidzume, A.; Yamaguchi, H.
  • Total Pages: 448
  • Publisher: Wiley-VCH
  • ISBN: 9783527346202
• [Book] 次世代のポリマー・高分子開発, 新しい用途展開と将来展望, - 生分解, 自己修復, 生物模倣, 刺激応答, 超分子, 医療用途など - (2019)
  • Author(s): 小林裕一郎、山口浩靖、原田 明
  • Total Pages: 608
  • Publisher: 技術情報協会
  • ISBN: 9784861047381
• [Book] 次世代のポリマー・高分子開発，新しい用途展開と将来展望 (2019)
  • Author(s): 小林裕一郎, 山口浩靖, 原田明
  • Total Pages: 608
  • Publisher: 情報技術協会
  • ISBN: 9784861047381
• [Patent(Industrial Property Rights)] 重合用組成物及びその重合体並びに重合体の製造方法 (2017)
  • Inventor(s): 原田明・高島義徳・呑村優・以倉俊平・小林裕一郎
  • Industrial Property Rights Holder: 原田明・高島義徳・呑村優・以倉俊平・小林裕一郎
  • Industrial Property Rights Type: 特許
  • Industrial Property Number: 2017-095058
  • Filing Date: 2017
• [Patent(Industrial Property Rights)] ホスト基含有重合性単量体、高分子材料及びその製造方法、並びに、包接化合物及びその製造方法 (2017)
  • Inventor(s): 原田明・高島義徳・呑村優・以倉俊平
  • Industrial Property Rights Holder: 原田明・高島義徳・呑村優・以倉俊平
  • Industrial Property Rights Type: 特許
  • Industrial Property Number: 2017-039908
  • Filing Date: 2017