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Physical and structural properties of hard and crack-resistant oxide glasses prepared by a levitation technique

Research Project

Project/Area Number 17H03121
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic industrial materials
Research InstitutionHirosaki University

Principal Investigator

Masuno Atsunobu  弘前大学, 理工学研究科, 准教授 (00378879)

Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥17,420,000 (Direct Cost: ¥13,400,000、Indirect Cost: ¥4,020,000)
Fiscal Year 2019: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2018: ¥7,020,000 (Direct Cost: ¥5,400,000、Indirect Cost: ¥1,620,000)
Fiscal Year 2017: ¥7,670,000 (Direct Cost: ¥5,900,000、Indirect Cost: ¥1,770,000)
Keywords無容器法 / ビッカース硬度 / クラックレジスタンス / アルミネートガラス / 希土類ガラス / 弾性率 / ガス浮遊炉 / 硬度 / 破壊靱性 / 充填密度 / 高弾性率
Outline of Final Research Achievements

Densely packed oxide glasses that are out of the conventional glass-forming rule were prepared by a levitation technique. Al2O3-Ta2O5-based and Al2O3-SiO2-based glasses exhibited superior mechanical properties such as large elastic modulus (Young's modulus was greater than 150 GPa). In the ternary system of MgO-SiO2-P2O5, the hardness of the MgO-rich glasses was much higher than those of conventional MgO-poor glasses. Structural analyses suggested that the local structures of these hard glasses were clearly different from those of conventional oxide glasses, and led to densely packed atomic arrangements.

Academic Significance and Societal Importance of the Research Achievements

無容器法を用いることで,従来ガラス化しないと思われていた組成域において,これまでのガラスの常識を超える機械的強度をもつ新たな材料,すなわち「本質的に」硬いガラス,割れないガラス,そして,硬くて割れないガラスを開発することに成功した.多角的な構造解析の結果から,これらのガラスの局所構造が従来のネットワークガラスとは大きく異なること,そしてそのことが充填密度を上げ,硬さと割れにくさの向上に寄与していることを明らかにした.硬くて割れないガラスの組成設計指針の確立に資する,構造と物性の相関に関する情報が得られた.

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (62 results)

All 2020 2019 2018 2017 Other

All Int'l Joint Research (6 results) Journal Article (16 results) (of which Int'l Joint Research: 5 results,  Peer Reviewed: 12 results,  Open Access: 3 results) Presentation (34 results) (of which Int'l Joint Research: 14 results,  Invited: 14 results) Remarks (4 results) Patent(Industrial Property Rights) (2 results)

  • [Int'l Joint Research] Carnegie Institution of Washington/Argonne National Laboratory(米国)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] Bath University(英国)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] Deutsches Elektronen- Synchrotron DESY(ドイツ)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] Aalborg University(デンマーク)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] Bath University(英国)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] Deutsches Elektronen-Synchrotron DESY(ドイツ)

    • Related Report
      2017 Annual Research Report
  • [Journal Article] Microstructural effects on hardness and optical transparency of birefringent aluminosilicate nanoceramics2020

    • Author(s)
      Gaida Nico A.、Nishiyama Norimasa、Beermann Oliver、Schurmann Ulrich、Masuno Atsunobu、Giehl Christopher、Niwa Ken、Hasegawa Masashi、Bhat Shrikant、Farla Robert、Kienle Lorenz
    • Journal Title

      International Journal of Ceramic Engineering & Science

      Volume: 2 Issue: 2 Pages: 76-82

    • DOI

      10.1002/ces2.10036

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] 第一原理計算からのTiO2を含む結晶とガラスの光学特性2020

    • Author(s)
      井上博之,馬田拓実,増野敦信
    • Journal Title

      NEW GLASS

      Volume: 1 Pages: 3-7

    • Related Report
      2019 Annual Research Report
  • [Journal Article] Understanding diffraction patterns of glassy, liquid and amorphous materials via persistent homology analyses2019

    • Author(s)
      ONODERA Yohei、KOHARA Shinji、TAHARA Shuta、MASUNO Atsunobu、INOUE Hiroyuki、SHIGA Motoki、HIRATA Akihiko、TSUCHIYA Koichi、HIRAOKA Yasuaki、OBAYASHI Ippei、OHARA Koji、MIZUNO Akitoshi、SAKATA Osami
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 127 Issue: 12 Pages: 853-863

    • DOI

      10.2109/jcersj2.19143

    • NAID

      130007755063

    • ISSN
      1348-6535, 1882-0743
    • Year and Date
      2019-12-01
    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] High refractive index La-rich lanthanum borate glasses composed of isolated BO3 units2019

    • Author(s)
      Masuno Atsunobu、Iwata Takashi、Yanaba Yutaka、Sasaki Shunta、Inoue Hiroyuki、Watanabe Yasuhiro
    • Journal Title

      Dalton Transactions

      Volume: 48 Issue: 29 Pages: 10804-10811

    • DOI

      10.1039/c9dt01715a

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ultrahigh pressure structural changes in a 60 mol. % Al2O3?40 mol. % SiO2 glass2019

    • Author(s)
      Ohira I.、Kono Y.、Shibazaki Y.、Kenney-Benson C.、Masuno A.、Shen G.
    • Journal Title

      Geochemical Perspectives Letters

      Volume: 10 Pages: 41-45

    • DOI

      10.7185/geochemlet.1913

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Fluorescence characterization of heavily Eu3+-doped lanthanum gallate glass spheres with high quenching concentration2019

    • Author(s)
      Yoshimoto Kohei、Ezura Yoshinobu、Ueda Motoi、Masuno Atsunobu、Inoue Hiroyuki、Mizuguchi Masafumi
    • Journal Title

      Optics Letters

      Volume: 44 Issue: 4 Pages: 875-875

    • DOI

      10.1364/ol.44.000875

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Bright greenish-yellow pigments based on Sc2-xFexO3 solid solutions with bixbyite structure2019

    • Author(s)
      Hashimoto Hideki、Sayo Kotaro、Asoh Hidetaka、Fujii Tatsuo、Takano Mikio、Masuno Atsunobu
    • Journal Title

      Materials Research Bulletin

      Volume: 109 Pages: 190-194

    • DOI

      10.1016/j.materresbull.2018.09.035

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] In-situ observation of the structural change in MgO-B2O3-SiO2 glass at high pressure and the permanent structural change2018

    • Author(s)
      Yamada A.、Harada M.、Masuno A.、Yamanaka K.、Higo Y.、Yoshida S.、Ohta T.、Matsuoka J.
    • Journal Title

      Journal of Non-Crystalline Solids

      Volume: 499 Pages: 25-31

    • DOI

      10.1016/j.jnoncrysol.2018.07.002

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of rare-earth ion size on elasticity and crack initiation in rare-earth aluminate glasses2018

    • Author(s)
      Rosales-Sosa Gustavo A.、Masuno Atsunobu、Higo Yuji、Watanabe Yasuhiro、Inoue Hiroyuki
    • Journal Title

      Journal of the American Ceramic Society

      Volume: 101 Issue: 11 Pages: 5030-5036

    • DOI

      10.1111/jace.15760

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Structural analysis of sulfuric acid solutions containing Ti and Mn using x-ray diffraction, x-ray absorption fine structure, and molecular dynamics simulation2018

    • Author(s)
      Tokuda Kazuya、Iihara Junji、Saito Yoshihiro、Masuno Atsunobu、Inoue Hiroyuki
    • Journal Title

      The Journal of Chemical Physics

      Volume: 149 Issue: 1 Pages: 014503-014503

    • DOI

      10.1063/1.5024950

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] ガラス・液体・アモルファス材料の回折パターンの理解2018

    • Author(s)
      小原真司,小野寺陽平,田原周太,増野敦信,井上博之,土谷浩一,坂田修身
    • Journal Title

      NEW GLASS

      Volume: 33 Pages: 3-7

    • Related Report
      2017 Annual Research Report
  • [Journal Article] 2.7 μm Mid-Infrared Emission in Highly Erbium-Doped Lanthanum Gallate Glasses Prepared Via an Aerodynamic Levitation Technique2018

    • Author(s)
      Yoshimoto Kohei、Ezura Yoshinobu、Ueda Motoi、Masuno Atsunobu、Inoue Hiroyuki
    • Journal Title

      Advanced Optical Materials

      Volume: 6 Issue: 8 Pages: 1701283-1701283

    • DOI

      10.1002/adom.201701283

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thermal and optical properties of La2O3-Ga2O3- (Nb2O5 or Ta2O5) ternary glasses2018

    • Author(s)
      Yoshimoto Kohei、Masuno Atsunobu、Ueda Motoi、Inoue Hiroyuki、Yamamoto Hiroshi、Kawashima Tatsunori
    • Journal Title

      Journal of the American Ceramic Society

      Volume: 印刷中 Issue: 8 Pages: 3328-3336

    • DOI

      10.1111/jace.15484

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Transparent polycrystalline nanoceramics consisting of triclinic Al2SiO5 kyanite and Al2O3 corundum2017

    • Author(s)
      Gaida Nico A.、Nishiyama Norimasa、Masuno Atsunobu、Sch?rmann Ulrich、Giehl Christopher、Beermann Oliver、Ohfuji Hiroaki、Bednarcik Jozef、Kulik Eleonora、Holzheid Astrid、Irifune Tetsuo、Kienle Lorenz
    • Journal Title

      Journal of the American Ceramic Society

      Volume: 101 Issue: 3 Pages: 998-1003

    • DOI

      10.1111/jace.15281

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] X線散乱と分子動力学シミュレーションによる硫酸系水溶液の構造解析2017

    • Author(s)
      斎藤吉広,徳田一弥,井上博之,増野敦信
    • Journal Title

      セラミックス

      Volume: 52 Pages: 365-368

    • Related Report
      2017 Annual Research Report
  • [Journal Article] 無容器浮遊法を用いたガラスおよび高温融液の構造と物性2017

    • Author(s)
      水野章敏,増野敦信,岡田純平,石川毅彦
    • Journal Title

      セラミックス

      Volume: 52 Pages: 349-351

    • Related Report
      2017 Annual Research Report
  • [Presentation] 無容器法を用いて合成したLa2O3-Ga2O3系ガラスの機械特性, 誘電特性と構造2020

    • Author(s)
      大矢智貴,増野敦信,小野寺陽平
    • Organizer
      日本セラミックス協会2020年年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] ネットワークが断片化したアルミノリン酸塩ガラスの物性と構造2020

    • Author(s)
      松谷朋治,増野敦信,簗場豊,井上博之
    • Organizer
      日本セラミックス協会2020年年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 無容器法によって合成した Ba(Ti1-xMx)2O5ガラスの熱処理結晶化過程2020

    • Author(s)
      泉智,増野敦信
    • Organizer
      日本セラミックス協会2020年年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Crack-resistant and High Elastic Modulus Oxide Glasses Prepared by a Levitation Technique2019

    • Author(s)
      A. Masuno
    • Organizer
      Materials Research Meeting 2019 (MRM 2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 無容器法により合成した希土類ボレートガラスの物性と構造2019

    • Author(s)
      佐々木俊太,増野敦信,尾原幸治
    • Organizer
      日本セラミックス協会第60回ガラスおよびフォトニクス材料討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Al2O3-SiO2-ZrO2系ガラスの構造と機械特性2019

    • Author(s)
      三上優希,増野敦信,簗場豊,肥後祐司,井上博之
    • Organizer
      日本セラミックス協会第60回ガラスおよびフォトニクス材料討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Control of Refractive Index Dispersion of High Refractive Index Glasses Prepared by a Levitation Technique2019

    • Author(s)
      A. Masuno, Y. Okamura, H. Inoue, Y. Watanabe, Y. Yanaba
    • Organizer
      14th International Conference on The Structure of Non-crystalline Materials (NCM14)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Mechanical properties of Al2O3-Ta2O5-MxOy (MxOy = Nb2O5, Ga2O3, or Y2O3) glasses prepared by a levitation technique2019

    • Author(s)
      Y. Mikami, A. Masuno, Y. Yanaba, H. Inoue
    • Organizer
      The 13th Pacific Rim Conference of Ceramic Societies (PACRIM13)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] High refractive index with low wavelength dispersion of La2O3-rich La2O3-B2O3-Nb2O5 glasses prepared by a levitation technique2019

    • Author(s)
      A. Masuno, Y. Yanaba, S. Sasaki, H. Inoue
    • Organizer
      The 13th Pacific Rim Conference of Ceramic Societies (PACRIM13)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 無容器法で合成した高硬度アルミネートガラスの物性と構造2019

    • Author(s)
      増野敦信,三上優希
    • Organizer
      日本材料学会第5回材料WEEK
    • Related Report
      2019 Annual Research Report
  • [Presentation] Physical and structural properties of MgO-SiO2-PO5/2 invert glasses prepared by a levitation technique2019

    • Author(s)
      A. Masuno, S. Sasaki, Y. Yanaba, H. Inoue
    • Organizer
      25th International Congress on Glass (ICG 2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 浮遊融液から現れる新規準安定相の機能と構造2019

    • Author(s)
      増野敦信
    • Organizer
      日本鉄鋼協会東北支部東北地区講演会・若手フォーラム
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 無容器法を用いたMgO-SiO2-PO5/2三元系ガラスの合成2019

    • Author(s)
      佐々木創,増野敦信
    • Organizer
      日本セラミックス協会2019年年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Al2O3-MxOy-Ta2O5 (MxOy = Nb2O5, Ga2O3, Y2O3)ガラスの合成と機械特性2019

    • Author(s)
      三上優希,増野敦信,簗場豊,井上博之
    • Organizer
      日本セラミックス協会2019年年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 模擬ガラス固化体の局所構造解析2019

    • Author(s)
      増野敦信,三浦吉幸,兼平憲男,簗場豊,井上博之
    • Organizer
      日本セラミックス協会2019年年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 超硬ガラス2018

    • Author(s)
      増野敦信
    • Organizer
      生産開発技術研究所 新材料・新技術利用研究会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 無容器法によって合成した機能性準安定酸化物の物性と構造2018

    • Author(s)
      増野敦信
    • Organizer
      SPRUC 原子分解能ホログラフィー研究会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Structural analyses of functional oxide glasses prepared by a levitation technique2018

    • Author(s)
      A. Masuno
    • Organizer
      THERMEC'2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 無容器溶融技術が拓くガラスの未来2018

    • Author(s)
      増野敦信
    • Organizer
      ニューガラスフォーラム 第130回若手懇談会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Local Structure Analysis of Nuclear Waste Glasses2018

    • Author(s)
      A. Masuno, Y. Miura, N. Kanehira, Y. Yanaba, H. Inoue
    • Organizer
      ICG Annual Meeting 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Masuno Group, Laboratory of Solid State Chemistry, Hirosaki University2018

    • Author(s)
      A. Masuno
    • Organizer
      ICG Annual Meeting 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 廃棄物ガラス固化体の局所構造解析2018

    • Author(s)
      増野敦信,三浦吉幸,兼平憲男,簗場豊,井上博之
    • Organizer
      日本セラミックス協会 2018年年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Densely packed oxide glasses with optical and mechanical functionalities prepared by a levitation technique2017

    • Author(s)
      Atsunobu Masuno
    • Organizer
      JSPM International Conference on Powder and Powder Metallurgy
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] ガラスから結晶化させた(Ba,Ca)Ti2O5の誘電特性と構造2017

    • Author(s)
      増野敦信
    • Organizer
      日本セラミックス協会 第30回秋季シンポジウム
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Functional metastable oxides fabricated by a levitation technique2017

    • Author(s)
      Atsunobu Masuno
    • Organizer
      International Union of Materials Research Society - International Conference of Advanced Materials 2017 (IUMRS-ICAM 2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] High elastic modulus glasses prepared by levitation technique2017

    • Author(s)
      Atsunobu Masuno
    • Organizer
      7th International Workshop on Flow and Fracture of Advanced Glasses (FFAG-7)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 無容器浮遊させた大過冷却液体から現れる機能性酸化物の物性と構造2017

    • Author(s)
      増野敦信
    • Organizer
      第2回固体化学フォーラム研究会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Functional oxide glasses fabricated by aerodynamic levitation technique2017

    • Author(s)
      Atsunobu Masuno
    • Organizer
      12th Pacific Rim Conference on Ceramic and Glass Technology (PACRIM 12)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 無容器浮遊融液から現れる新規機能性材料の特性と構造2017

    • Author(s)
      増野敦信
    • Organizer
      日本鉄鋼協会高温プロセス部会高温物性値フォーラム 平成29年度第1回研究会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 無容器法で合成する高充填密度ガラスの優れた機能と特異な構造2017

    • Author(s)
      増野敦信
    • Organizer
      新化学技術推進協会 先端化学・材料技術部会 新素材分科会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 無容器法で合成した希土類酸化物を多く含むホウ酸塩ガラスの物性と構造2017

    • Author(s)
      増野敦信,簗場豊,渡辺康裕,井上博之,東正樹
    • Organizer
      日本セラミックス協会第58回ガラスおよびフォトニクス材料討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] (研究室紹介)弘前大学大学院理工学研究科増野研究室2017

    • Author(s)
      増野敦信
    • Organizer
      日本セラミックス協会第58回ガラスおよびフォトニクス材料討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Optical and magnetic properties of binary rare earth borate glasses2017

    • Author(s)
      A. Masuno, Y. Watanabe, Y. Yanaba, H. Inoiue, M. Azuma
    • Organizer
      2017 ICG Annual Meeting
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Optical, magnetic, and structural properties of binary rare earth borate glasses prepared by a levitation technique2017

    • Author(s)
      Atsunobu Masuno, Yasuhiro Watanabe, Masaki Azuma, Yutaka Yanaba, Hiroyuki Inoue
    • Organizer
      The Tenth International Conference on the Science and Technology for Advanced Ceramics (STAC-10)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Remarks] 弘前大学理工学部物質創成化学科 増野研究室

    • URL

      http://www.st.hirosaki-u.ac.jp/~masuno/index.html

    • Related Report
      2019 Annual Research Report
  • [Remarks] 弘前大学理工学部物質創成化学科 増野研究室

    • URL

      http://www.st.hirosaki-u.ac.jp/~masuno/

    • Related Report
      2018 Annual Research Report
  • [Remarks] 科研費NEWS 2018年度Vol. 2

    • URL

      https://www.jsps.go.jp/j-grantsinaid/22_letter/e-book/news2018_vol2/index_h5.html#2

    • Related Report
      2018 Annual Research Report
  • [Remarks] 弘前大学大学院理工学研究科 増野研究室

    • URL

      http://www.st.hirosaki-u.ac.jp/~masuno/index.html

    • Related Report
      2017 Annual Research Report
  • [Patent(Industrial Property Rights)] ガラス材の製造方法2018

    • Inventor(s)
      増野敦信,井上博之,佐藤史雄,榎本朋子,小谷修
    • Industrial Property Rights Holder
      増野敦信,井上博之,佐藤史雄,榎本朋子,小谷修
    • Industrial Property Rights Type
      特許
    • Filing Date
      2018
    • Related Report
      2018 Annual Research Report
  • [Patent(Industrial Property Rights)] ガラス材の製造方法2017

    • Inventor(s)
      佐藤史雄,榎本朋子,小谷修,井上博之,増野敦信
    • Industrial Property Rights Holder
      佐藤史雄,榎本朋子,小谷修,井上博之,増野敦信
    • Industrial Property Rights Type
      特許
    • Patent Publication Number
      2017-154972
    • Filing Date
      2017
    • Related Report
      2017 Annual Research Report

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Published: 2017-04-28   Modified: 2022-06-10  

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