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Measurement techniques for thermophysical properties of low-dimensional materials for next-generation electronics

Research Project

Project/Area Number 17H03186
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Thermal engineering
Research InstitutionKyushu University

Principal Investigator

Takahashi Koji  九州大学, 工学研究院, 教授 (10243924)

Co-Investigator(Kenkyū-buntansha) 李 秦宜  九州大学, 工学研究院, 助教 (60792041)
生田 竜也  九州大学, 工学研究院, 技術専門職員 (70532331)
西山 貴史  福岡大学, 工学部, 助教 (80363381)
Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥17,680,000 (Direct Cost: ¥13,600,000、Indirect Cost: ¥4,080,000)
Fiscal Year 2019: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2018: ¥6,240,000 (Direct Cost: ¥4,800,000、Indirect Cost: ¥1,440,000)
Fiscal Year 2017: ¥7,410,000 (Direct Cost: ¥5,700,000、Indirect Cost: ¥1,710,000)
Keywords2次元材料 / 熱伝導率 / 界面熱抵抗 / ラマン分光法 / ラマン分光 / 2次元材料 / ナノマイクロ熱工学
Outline of Final Research Achievements

From the viewpoint of next-generation electronics, thermophysical properties of low-dimensional materials are experimentally treated by using new measurement techniques. Variable-spot-size Raman method was developed and applied to WS2 and the effect of substrate was found to degrade the thermal conductivity to one third. Laser-flash Raman method was applied to MoS2. In addition, graphene nano ribbon was found to have very high thermoelectric performance. Nanobubbles at the graphene-liquid interface were also explored by using AFM.

Academic Significance and Societal Importance of the Research Achievements

次世代のエレクトロニクスでは2次元材料とそのヘテロ構造が期待されているが、それらの熱物性は不明なことが多く正確な熱設計ができない原因となっている。本研究では各種2次元材料単体およびそれらを基板上に積層させた構造の熱伝導特性を計測可能な新規手法の開発に成功し、将来の2次元材料応用における基盤的知見となる熱工学的成果を得た。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (33 results)

All 2019 2018 2017 Other

All Int'l Joint Research (4 results) Journal Article (11 results) (of which Int'l Joint Research: 8 results,  Peer Reviewed: 11 results,  Open Access: 1 results) Presentation (18 results) (of which Int'l Joint Research: 10 results,  Invited: 1 results)

  • [Int'l Joint Research] Purdue University(米国)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] Tsinghua University(中国)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] Tsinghua University(中国)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] 清華大学(中国)

    • Related Report
      2017 Annual Research Report
  • [Journal Article] Frequency-domain Raman method to measure thermal diffusivity of one-dimensional microfibers and nanowires2019

    • Author(s)
      Li, Qin-Yi; Takahashi, Koji; Zhang, Xing;
    • Journal Title

      International Journal of Heat and Mass Transfer

      Volume: 134 Pages: 539-546

    • DOI

      10.1016/j.ijheatmasstransfer.2019.01.057

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Water Confined in Hydrophobic Cup-Stacked Carbon Nanotubes beyond Surface-Tension Dominance2019

    • Author(s)
      Li Qin-Yi、Matsushita Ryo、Tomo Yoko、Ikuta Tatsuya、Takahashi Koji
    • Journal Title

      The Journal of Physical Chemistry Letters

      Volume: 10 Issue: 13 Pages: 3744-3749

    • DOI

      10.1021/acs.jpclett.9b00718

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Modification of thermal transport in an individual carbon nanofiber by focused ion beam irradiation2019

    • Author(s)
      Narasaki Masahiro、Li Qin-Yi、Ikuta Tatsuya、Miyawaki Jin、Takahashi Koji
    • Journal Title

      Carbon

      Volume: 153 Pages: 539-544

    • DOI

      10.1016/j.carbon.2019.07.056

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Adsorbed gas layers limit the mobility of micropancakes2019

    • Author(s)
      Teshima Hideaki、Takata Yasuyuki、Takahashi Koji
    • Journal Title

      Applied Physics Letters

      Volume: 115 Issue: 7 Pages: 071603-071603

    • DOI

      10.1063/1.5113810

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enhanced Thermoelectric Performance of As-Grown Suspended Graphene Nanoribbons2019

    • Author(s)
      Q.-Y. Li, T. Feng, W. Okita, Y. Komori, H. Suzuki, T. Kato, T. Kaneko, T. Ikuta, X. Ruan, K. Takahashi
    • Journal Title

      ACS Nano

      Volume: 13 Issue: 8 Pages: 9182-9189

    • DOI

      10.1021/acsnano.9b03521

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Variable-spot-size laser-flash Raman method to measure in-plane and interfacial thermal properties of 2D van der Waals heterostructures2018

    • Author(s)
      Li, Qin-Yi; Zhang, Xing; Takahashi, Koji;
    • Journal Title

      International Journal of Heat and Mass Transfer

      Volume: 125 Pages: 1230-1239

    • DOI

      10.1016/j.ijheatmasstransfer.2018.05.011

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Effective thermal rectification in suspended monolayer graphene2018

    • Author(s)
      Haidong Wang, Xing Zhang, Hiroshi Takamatsu, Koji Takahashi
    • Journal Title

      Proceedings of the 16th International Heat Transfer Conference

      Volume: 1 Pages: 22210-22210

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Heater assisted Raman method to measure interfacial thermal conductance in van der Waals heterostructures2018

    • Author(s)
      Qinyi Li, Koji Takahashi, Xing Zhang
    • Journal Title

      Proceedings of the 16th International Heat Transfer Conference

      Volume: 1 Pages: 21756-21756

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Experimental study of thermal rectification in suspended monolayer graphene2017

    • Author(s)
      Wang Haidong、Hu Shiqian、Takahashi Koji、Zhang Xing、Takamatsu Hiroshi、Chen Jie
    • Journal Title

      Nature Communications

      Volume: 8 Issue: 1 Pages: 15843-15843

    • DOI

      10.1038/ncomms15843

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Measurement of specific heat and thermal conductivity of supported and suspended graphene by a comprehensive Raman optothermal method2017

    • Author(s)
      Li Qin-Yi、Xia Kailun、Zhang Ji、Zhang Yingying、Li Qunyang、Takahashi Koji、Zhang Xing
    • Journal Title

      Nanoscale

      Volume: 9 Issue: 30 Pages: 10784-10793

    • DOI

      10.1039/c7nr01695f

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Experimental study on thermal conductivity of free-standing fluorinated single-layer graphene2017

    • Author(s)
      Narasaki Masahiro、Wang Haidong、Nishiyama Takashi、Ikuta Tatsuya、Takahashi Koji
    • Journal Title

      Applied Physics Letters

      Volume: 111 Issue: 9 Pages: 093103-093103

    • DOI

      10.1063/1.5001169

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Presentation] レーザーフラッシュラマン分光法によるMoS2薄膜の熱拡散率計測2019

    • Author(s)
      赤山直哉、李秦宜、吾郷浩樹、高橋厚史、河野正道
    • Organizer
      第40回日本熱物性シンポジウム、長崎市
    • Related Report
      2019 Annual Research Report
  • [Presentation] 欠陥を有するカーボンナノファイバーのMEMSセンサによる熱計測2019

    • Author(s)
      楢崎将弘, 李秦宜, 宮脇仁, 生田竜也, 高橋厚史
    • Organizer
      第56回日本伝熱シンポジウム、徳島市
    • Related Report
      2019 Annual Research Report
  • [Presentation] グラフェンリボンの熱伝導計測及びサイズ効果2019

    • Author(s)
      李秦宜, 高橋厚史
    • Organizer
      第56回日本伝熱シンポジウム、徳島市
    • Related Report
      2019 Annual Research Report
  • [Presentation] Measurement of thermal contact resistance between individual carbon fibers using a transient Raman mapping method2019

    • Author(s)
      Qin-Yi Li, Koki Katakami, Tatsuya Ikuta, Xing Zhang, Koji Takahashi
    • Organizer
      The 7th International Symposium on Micro and Nano Technology (ISMNT-7), Qingdao, China
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Record-high thermoelectric performance of graphene2019

    • Author(s)
      Qin-Yi Li, Toshiaki Kato, Xiulin Ruan, Koji Takahashi
    • Organizer
      The 12th Asian Thermophysical Properties Conference (ATPC2019), Xi'an, China
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Effective thermal rectification in suspended monolayer graphene2018

    • Author(s)
      Haidong Wang, Xing Zhang, Hiroshi Takamatsu, Koji Takahashi
    • Organizer
      The 16th International Heat Transfer Conference
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Heater assisted Raman method to measure interfacial thermal conductance in van der Waals heterostructures2018

    • Author(s)
      Qinyi Li, Koji Takahashi, Xing Zhang
    • Organizer
      The 16th International Heat Transfer Conference
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Nanomaterials and Nanobubles for Heat Transfer2018

    • Author(s)
      Koji Takahashi
    • Organizer
      The 6th UK Japan Engineering Education League Workshop 2018, 3-5 September 2018, Fukuoka, Japan
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 2次元材料とヘテロ構造の熱物性を計測する周波数領域ラマン分光法の開発2018

    • Author(s)
      李秦宜, 高橋厚史, 張興
    • Organizer
      第55回日本伝熱シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] 非定常ラマン光熱法とその応用2018

    • Author(s)
      李秦宜,張興,高橋厚史
    • Organizer
      第39回日本熱物性シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] 幅40nmの懸架されたグラフェンナノリボンの熱伝導率計測2018

    • Author(s)
      小森陽平, 李秦宜, 大北若奈, 加藤俊顕, 高橋厚史
    • Organizer
      日本機械学会 熱工学コンファレンス2018
    • Related Report
      2018 Annual Research Report
  • [Presentation] Simultaneous measurement of thermal contact resistance between individual carbon fibers and their thermal diffusivity using a laser-flash Raman mapping method2018

    • Author(s)
      Koki Katakami, Qinyi Li, Tatsuya Ikuta, Koji Takahashi
    • Organizer
      3rd Thermal and Fluids Engineering Conference (TFEC) March 4-7, 2018, Ft. Lauderdale, FL, USA
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Dual-mode Raman method to measure in-plane and interfacial thermophysical properties of 2D van der Waals heterostructures2017

    • Author(s)
      Li Q Y, Zhang X, Takahashi K.
    • Organizer
      2017 MRS Spring Meeting. Apr. 17-21, 2017, Phoenix, Arizona, US.
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] フッ化単層グラフェンの熱伝導率計測2017

    • Author(s)
      楢崎将弘、王海東、生田竜也、西山貴史、高橋厚史
    • Organizer
      第54回伝熱シンポジウム. 2017年5月24日-26日,大宮
    • Related Report
      2017 Annual Research Report
  • [Presentation] 2次元材料のヘテロ構造の熱物性を計測するデュアルモードラマン分光法の開発2017

    • Author(s)
      李 秦宜, 張 興, 高橋 厚史
    • Organizer
      第54回伝熱シンポジウム. 2017年5月24日-26日,大宮
    • Related Report
      2017 Annual Research Report
  • [Presentation] Dual-mode Raman method to measure thermal transport properties of 2D materials and van der Waals heterostructures2017

    • Author(s)
      Li Q Y, Zhang X, Takahashi K.
    • Organizer
      The 9th US-Japan Joint Seminar on Nanoscale Transport Phenomena, July 2-5, 2017, Tokyo, Japan.
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Thermal Transport of Fluorinated Single-Layer Graphene2017

    • Author(s)
      Masahiro Narasaki, Haidong Wang, Tatsuya Ikuta, Takashi Nishiyama, Koji Takahashi
    • Organizer
      The 9th World Conference on Experimental Heat Tranfer, Fluid Mechanics and Thermodynamics, 13th June, 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Experimental Approach to Control the Thermal Conductivity of Single-Layer Graphene by Fluorination2017

    • Author(s)
      Masahiro Narasaki, Haidong Wang, Yasuyuki Takata, Tatsuya Ikuta, Koji Takahashi
    • Organizer
      International Mechanical Engineering Congress and Exposition, 8th November, 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research

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Published: 2017-04-28   Modified: 2021-02-19  

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