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Construction of precise step terrace structure with high surface atom density and minimized point defect density

Research Project

Project/Area Number 17H03378
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Physical properties of metals/Metal-base materials
Research InstitutionNagoya University

Principal Investigator

Yamamoto Takahisa  名古屋大学, 工学研究科, 教授 (20220478)

Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥17,940,000 (Direct Cost: ¥13,800,000、Indirect Cost: ¥4,140,000)
Fiscal Year 2019: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2018: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2017: ¥9,230,000 (Direct Cost: ¥7,100,000、Indirect Cost: ¥2,130,000)
Keywords酸化物結晶 / 原子構造 / STEM / TEM / 結晶表面 / 表面 / EELS / チタン酸ストロンチウム / 電子状態 / 点欠陥 / SrTiO3 / ステップテラス構造 / 熱処理
Outline of Final Research Achievements

An atomic level flat step terrace structure is required on the surface of the crystal substrate used for film growth. For the construction of this structure, a heat treatment method using surface diffusion on the substrate surface is often used. However, by performing the heat treatment, point defects having a concentration equilibrium with the heat treatment temperature are formed on the outermost surface portion of the substrate, and the atom density of the outermost surface portion may decrease. In this study, we collected basic knowledge about adjustment of oxygen partial pressure during heat treatment and use of ultrapure water as a method to alleviate this decrease in atomic density as much as possible. We also worked on the effect of electric field application as a method of changing the state of the substrate surface.

Academic Significance and Societal Importance of the Research Achievements

結晶最表面部の原子構造に関する研究はこれまでに多数報告されている。その主な内容は、原子構造自体の変化や、組成変化に関するものである。一方、結晶表面のような格子不整合となる領域は点欠陥の生成消滅箇所として作用することが知られている。これまでに、このような点欠陥生成に伴う原子密度の変化という視点からの研究はなされていない。原子密度という観点からの基礎的な知見が得られれば、表面構造の新たな制御方法の確立へと結びつく可能性が考えられる。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (11 results)

All 2019 2018 2017

All Journal Article (6 results) (of which Peer Reviewed: 5 results) Presentation (5 results) (of which Int'l Joint Research: 1 results,  Invited: 1 results)

  • [Journal Article] LSAT:(La0.3Sr0.7)(Al0.65Ta0.35)O3単結晶のBサイト秩序構造2019

    • Author(s)
      山本剛久 徳永智春 小林俊介
    • Journal Title

      まてりあ

      Volume: 58 Pages: 93-93

    • NAID

      130007600450

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Atomic Structure of (Al0.3Sr0.7)(Al0.65Ta0.35)O3 (001) Single Crystal Substrate Treated by Ultrapure Water2019

    • Author(s)
      Y. Tokuda, T. Irimoto, N. Nishiyama, T. Tokunaga, T. Yamamoto
    • Journal Title

      International Journal of Advanced Microscopy and Theoretical Calculations

      Volume: 6 Pages: 164-165

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 酸化物系セラミックのフラッシュ焼結と 今後の進展2018

    • Author(s)
      山本 剛久、吉田 英弘
    • Journal Title

      まてりあ

      Volume: 57 Pages: 373-380

    • NAID

      130007429770

    • Related Report
      2018 Annual Research Report
  • [Journal Article] Intergranular amorphous films formed by DC electric field in pure zirconia2018

    • Author(s)
      Morisaki Nobuhiro、Yoshida Hidehiro、Kobayashi Tetsuro、Tokunaga Tomoharu、Yamamoto Takahisa
    • Journal Title

      Journal of the American Ceramic Society

      Volume: 未定 Issue: 8 Pages: 1-6

    • DOI

      10.1111/jace.15485

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Consolidation of undoped, monoclinic zirconia polycrystals by flash-sintering2017

    • Author(s)
      Nobuhiro Morisaki, Hidehiro Yoshida, Tomoharu Tokunaga, Katsuhiro Sasaki, Takahisa Yamamoto
    • Journal Title

      Journal of the American Ceramics Society

      Volume: 100 Issue: 9 Pages: 3851-3857

    • DOI

      10.1111/jace.14954

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fundamentals and Future Prospects of Flash Sintering of Advanced Ceramics2017

    • Author(s)
      吉田 英弘, 山本 剛久
    • Journal Title

      Journal of the Japan Society of Powder and Powder Metallurgy

      Volume: 64 Issue: 10 Pages: 523-531

    • DOI

      10.2497/jjspm.64.523

    • NAID

      130007311761

    • ISSN
      0532-8799, 1880-9014
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Presentation] Atomic Structure of (Al0.3Sr0.7)(Al0.65Ta0.35)O3 (001) Single Crystal Substrate Treated by Ultrapure Water2019

    • Author(s)
      Y. Tokuda, T. Irimoto, N. Nishiyama, T. Tokunaga, T. Yamamoto
    • Organizer
      The 6th International Symposium on Advanced Microscopy and Theoretical Calculations ( AMTC6 )
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 酸化物系セラミックのフラッシュ焼結における印加電界の波形効果2018

    • Author(s)
      山本 剛久 吉田 英弘
    • Organizer
      日本金属学会2018年秋季(第163回)講演大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 酸化物セラミックスのフラッシュ焼結2018

    • Author(s)
      山本剛久
    • Organizer
      粉体粉末冶金協会 平成 30 年 度 春 季 大 会 (第121回講演大会)
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 熱処理に伴うSrTiO3単結晶表面の組成変化2017

    • Author(s)
      浜田 哲, 徳永 智春, 山本 剛久
    • Organizer
      日本セラミック協会第30回秋季シンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] SrTiO3単結晶のフラッシュ現象2017

    • Author(s)
      山田 康暉, 吉田 英弘, 徳永 智春, 山本 剛久
    • Organizer
      日本セラミック協会第30回秋季シンポジウム
    • Related Report
      2017 Annual Research Report

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Published: 2017-04-28   Modified: 2021-02-19  

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