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Screening of Novel LED Nitride Phosphors using Vapor Phase Single Crystal Growth Method

Research Project

Project/Area Number 17H03386
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic materials/Physical properties
Research InstitutionNiigata University

Principal Investigator

TODA KENJI  新潟大学, 自然科学系, 研究教授 (20293201)

Co-Investigator(Kenkyū-buntansha) 佐藤 峰夫  新潟大学, 自然科学系, フェロー (30149984)
Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥17,680,000 (Direct Cost: ¥13,600,000、Indirect Cost: ¥4,080,000)
Fiscal Year 2019: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2018: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2017: ¥12,870,000 (Direct Cost: ¥9,900,000、Indirect Cost: ¥2,970,000)
Keywords蛍光体 / 希土類 / 窒化物 / 単結晶 / 構造解析 / 気相成長 / イオン結晶 / 結晶成長 / 光物性 / 無機工業化学
Outline of Final Research Achievements

White LEDs have high luminous efficiency, long life, and low power consumption, making them a promising light source for the next generation. Phosphors play a role in converting excitation light from blue or UV LED to visible light. In this study, we synthesized several single crystals with novel compositions using our developed gas phase method and analyzed crystal structures. We proposed candidate materials for the new phosphor matrix crystals. We also found that the emission and nitride ions have a tendency to substitute specific sites in the phosphor matrix. Unique crystal structures have significant effects on the luminescence properties and chemical stability.

Academic Significance and Societal Importance of the Research Achievements

本研究により、新規蛍光体に対する母体結晶の複数の候補材料を提案できた。発光色は、緑・黄色・赤色など多岐にわたる。得られた単結晶の構造解析を行うことにより、粉末の構造解析では得られない精密な構造データを得ることができた。
本研究で得られた知見は、白色LEDを用いたより演色性(色の再現性)が高く明るいLED照明や、より鮮やかな液晶ディスプレイの実現に貢献できる。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (7 results)

All 2019 2018

All Journal Article (3 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 3 results,  Open Access: 2 results) Presentation (4 results) (of which Int'l Joint Research: 3 results,  Invited: 3 results)

  • [Journal Article] Single Crystal Growth and Crystal Structure Analysis of Novel Orange-Red Emission Pure Nitride CaAl2Si4N8:Eu2+ Phospho2019

    • Author(s)
      Shota Hasegawa,Takuya Hasegawa,Sun Woog Kim, Ryota Yamanashi, Kazuyoshi Uematsu, Kenji Toda, and Mineo Sato
    • Journal Title

      ACS Omega

      Volume: 4 Issue: 6 Pages: 9939-9945

    • DOI

      10.1021/acsomega.9b00606

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Single crystal growth of nitride and oxynitride phosphors using a gas-solid phase hybrid synthesis method2019

    • Author(s)
      Yuya Higuchi, Masato Iwaki, Atsuya Koizumi, Ryota Yamanashi, Kazuyoshi Uematsu, Kenji Toda, and Mineo Sato
    • Journal Title

      Japanese Journal of Applied Physics 58, SFFD01 (2019)

      Volume: 58 Issue: SF Pages: SFFD01-SFFD01

    • DOI

      10.7567/1347-4065/ab0c74

    • NAID

      210000155948

    • Related Report
      2019 Annual Research Report 2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Blue-yellow multicolor phosphor, Eu2+-activated Li3NaSiO4: Excellent thermal stability and quenching mechanism2019

    • Author(s)
      Masato Iwaki, Shota Kumagai, Shoma Konishi, Atsuya Koizumi, Takuya Hasegawa, Kazuyoshi Uematsu, Atsushi Itadani, Kenji Toda, Mineo Sato
    • Journal Title

      Journal of Alloys and Compounds

      Volume: 776 Pages: 1016-1024

    • DOI

      10.1016/j.jallcom.2018.10.299

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Presentation] Abnormal Luminescence Property of Phosphor Materials Synthesized by the Melt Quenching Technique2019

    • Author(s)
      Kenji Toda
    • Organizer
      The 13th Pacific Rim Conference of Ceramic Societies
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Synthesis of phosphor materials using abnormally accelerated solid-state reaction2019

    • Author(s)
      Kenji Toda
    • Organizer
      International Symposium on Luminescent Materials (Phosphor Safari 2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Crystal Growth of Silicate Phosphors using SiO Vapor2018

    • Author(s)
      Kenji Toda
    • Organizer
      42nd International Conference & Exposition on Advanced Ceramics and Composites
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Single Crystal Growth of Nitride and Oxynitride Phosphors using a Gas-Solid Phase Hybrid Synthesis Method2018

    • Author(s)
      Yuya Higuchi, Mineori Katsu, Masato Iwaki, Kazuyoshi Uematsu, Kenji Toda, Mineo Sato
    • Organizer
      19th International Workshop on Inorganic and Organic Electroluminescence (EL2018)
    • Related Report
      2018 Annual Research Report

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Published: 2017-04-28   Modified: 2021-02-19  

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