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Single Crystal Patterning beyond the Law of Nature by Laser and Optical Active Functions

Research Project

Project/Area Number 17H03387
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic materials/Physical properties
Research InstitutionNagaoka University of Technology

Principal Investigator

KOMATSU TAKAYUKI  長岡技術科学大学, 工学研究科, 特任教授 (60143822)

Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥17,550,000 (Direct Cost: ¥13,500,000、Indirect Cost: ¥4,050,000)
Fiscal Year 2019: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2018: ¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2017: ¥8,970,000 (Direct Cost: ¥6,900,000、Indirect Cost: ¥2,070,000)
Keywords単結晶パターニング / ガラス / 結晶化 / レーザー / 光アクティブ機能
Outline of Final Research Achievements

The origin and mechanism of the c-axis orientation along laser scanning direction were clarified from the viewpoints of surface energy and interfacial free energy between crystal and surrounding glassy phase. The mechanism of the c-axis rotation in laser-patterned ferroelastic Gd2(MoO4)3 single crystals was clarified. The orientation patterning of c-axis oriented LiNbO3 particles was realized, resulting in a new phase in laser-patterning engineering. The distribution model of composition fluctuations was proposed for the first time from the data on crystallization of oxide glasses, especially the relationship between crystalline phases and glass compositions. In the present study, the mechanism of crystal orientation in single crystal patterning beyond the providence of nature in oxide glasses by laser irradiations was clarified, leading to the development of innovative optical active devices.

Academic Significance and Societal Importance of the Research Achievements

本研究は、レーザー誘起結晶化法を用い、ガラス表面および内部にらせん状などの様々な形状を有する自然の摂理を超えると呼べる単結晶ラインを自在にパターニングし、革新的光アクティブデバイス創製に展開することを目的としたものである。本研究で得られた単結晶配向機構の解明、結晶軸回転機構の解明、組成ゆらぎ分布モデルを用いた不均一ナノ構造モデルの提案は、レーザー誘起結晶化法をさらに深化させ、結晶成長分野にブレイクスルーをもたらすと共に、 物質材料科学・工学の分野に多大な貢献をしている。得られた成果は、革新的機能材料の創出を目指す独創的な基盤研究であり、社会産業分野への波及効果は大きい。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (45 results)

All 2020 2019 2018 2017 Other

All Int'l Joint Research (8 results) Journal Article (17 results) (of which Int'l Joint Research: 5 results,  Peer Reviewed: 17 results) Presentation (17 results) (of which Int'l Joint Research: 17 results,  Invited: 5 results) Book (1 results) Remarks (2 results)

  • [Int'l Joint Research] Univ. Chem. Tech. Metall.(ブルガリア)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] BAM Fed. Inst. Mater. Res. Test(ドイツ)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] BAM Fed. Inst. Mater. Res. Test(ドイツ)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] Coe College(米国)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] Univ. Chem. Tech. Metall.(ブルガリア)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] Coe College(米国)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] BAM Fed. Inst. Mater. Res. Test.(Germany)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] University Chem. Tech. Metall.(Bulgaria)

    • Related Report
      2017 Annual Research Report
  • [Journal Article] Features of electronic polarizability and approach to unique properties in tellurite glasses2020

    • Author(s)
      T. Komatsu, V. Dimitrov
    • Journal Title

      International Journal of Applied Glass Science

      Volume: 11 Issue: 2 Pages: 253-271

    • DOI

      10.1111/ijag.14776

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Phase selective crystallization of Na2Mn0.9Fe0.1P2O7 glass by laser irradiation2020

    • Author(s)
      Tsuyoshi Honma, Yu Kumagai, Takayuki Komatsu
    • Journal Title

      International Journal of Applied Glass Science

      Volume: 11 Issue: 1 Pages: 112-119

    • DOI

      10.1111/ijag.14102

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structural origin of high-density Gd2O3-MoO3-B2O3 glass and low-density β'-Gd2(MoO4)3 crystal: a study conducted using high-energy x-ray diffraction and EXAFS at high temperatures2020

    • Author(s)
      Kenji Shinozaki, Hiroki Tsuchiya, Tsuyoshi Honma, Koji Ohara, Hirokazu Masai,Toshiaki Ina, Takayuki Komatsu
    • Journal Title

      Journal of Physics: Condensed Matter

      Volume: 32 Issue: 5 Pages: 055705-055705

    • DOI

      10.1088/1361-648x/ab4e64

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Laser patterning and growth mechanism of orientation designed crystals in oxide glasses: A Review2019

    • Author(s)
      T. Komatsu, T. Honma
    • Journal Title

      Journal of Solid State Chemistry

      Volume: 275 Pages: 210-222

    • DOI

      10.1016/j.jssc.2019.04.020

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Crystallization data-driven proposal on distribution model of composition fluctuations in structure of oxide glasses2019

    • Author(s)
      T. Komatsu, T. Honma
    • Journal Title

      Journal of Solid State Chemistry

      Volume: 288 Pages: 121379-121379

    • DOI

      10.1016/j.jssc.2020.121379

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Pressureless all-solid-state sodium ion battery consisting of Na2FeP2O7 glass-ceramics and beta’’-alumina electrolyte2019

    • Author(s)
      H. Yamauchi, J. Ikejiri, F. Sato, H. Oshita, T. Honma, T. Komatsu
    • Journal Title

      Journal of the American Ceramic Society

      Volume: 102 Pages: 6658-6667

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Formation of bismuth metal in bismuth borate glass by reductive heat treatment and its electrochemical property as anode in lithium ion battery2018

    • Author(s)
      Y. Omori, T. Honma, T. Komatsu
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 126 Issue: 10 Pages: 820-825

    • DOI

      10.2109/jcersj2.18083

    • NAID

      130007491234

    • ISSN
      1348-6535, 1882-0743
    • Year and Date
      2018-10-01
    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Control of self-powdering phenomenon in ferroelastiic beta'-Gd2(MoO4)3 crystallization in boro-tellurite glasses2018

    • Author(s)
      M. Kotaka, T. Honma, T. Komatsu, K. Shinozaki, M. Affatigato, R. Müller
    • Journal Title

      Journal of Non-Crystalline Solids

      Volume: 印刷中 Pages: 85-92

    • DOI

      10.1016/j.jnoncrysol.2017.12.006

    • Related Report
      2018 Annual Research Report 2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Updated definition of glass-ceramics2018

    • Author(s)
      J. Deubener, T. Komatsu (他16名)
    • Journal Title

      Journal of Non-Crystalline Solids

      Volume: 501 Pages: 3-10

    • DOI

      10.1016/j.jnoncrysol.2018.01.033

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Laser patterning of oriented LiNbO3 crystal particle arrays in NiO-doped lithium niobium silicate glasses2018

    • Author(s)
      M. Shimada, T. Honma, T. Komatsu
    • Journal Title

      nternational Journal of Applied Glass Science

      Volume: 9 Issue: 4 Pages: 518-529

    • DOI

      10.1111/ijag.12390

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Crystallization behavior of beta’-Gd2(MoO4)3 and Gd4Mo7O27 in composition designed Gd2O3-MoO3-B2O3 glasses2018

    • Author(s)
      M. Kotaka, T. Honma, T. Komatsu
    • Journal Title

      Journal of Non-Crystalline Solids

      Volume: 印刷中 Pages: 437-442

    • DOI

      10.1016/j.jnoncrysol.2018.02.027

    • Related Report
      2018 Annual Research Report 2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Tb 3+ -doped BaF 2 -Al 2 O 3 -B 2 O 3 glass and glass-ceramic for radiation measurements2018

    • Author(s)
      Okada Go、Shinozaki Kenji、Komatsu Takayuki、Kawano Naoki、Kawaguchi Noriaki、Yanagida Takayuki
    • Journal Title

      Journal of Non-Crystalline Solids

      Volume: - Pages: 101-105

    • DOI

      10.1016/j.jnoncrysol.2018.02.013

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Group optical basicity and single bond strength of oxide glasses2018

    • Author(s)
      V. Dimitrov, T. Komatsu, T. Tasheva
    • Journal Title

      Journal of Chemical Technology and Metallurgy

      Volume: 53 Pages: 1038-1046

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Photoluminescence features of new Eu3+-doped Gd4Mo7O27 phosphors synthesized using glass crystallization technique2018

    • Author(s)
      M. Kotaka, T. Honma, T. Komatsu,
    • Journal Title

      Journal of Asian Ceramic Societies

      Volume: 6 Issue: 4 Pages: 314-321

    • DOI

      10.1080/21870764.2018.1511231

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Correlation between thermal expansion coefficient and interionic interaction parameter in ZnO&ndash;Bi<sub>2</sub>O<sub>3</sub>&ndash;B<sub>2</sub>O<sub>3</sub> glasses2018

    • Author(s)
      T. Komatsu, T. Inoue, T. Tesheva, T. Honma, V. Dimitrov
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 126 Issue: 1 Pages: 8-15

    • DOI

      10.2109/jcersj2.17176

    • NAID

      130006301636

    • ISSN
      1348-6535, 1882-0743
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Simultaneous surface and bulk crystallization of Bi1.5ZnNb1.5O7-type pyrochlores and related crystals in glasses2018

    • Author(s)
      K. Shimamura, T. Honma, K. Shinozaki, T. Komatsu
    • Journal Title

      International Journal of Applied Glass Science

      Volume: 9 Issue: 2 Pages: 296-304

    • DOI

      10.1111/ijag.12343

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Formation of nonlinear optical Na2TeW2O9 crystals and laser irradiation in tangusten-tellurite glasses2017

    • Author(s)
      Y. Wang, T. Honma, T. Komatsu
    • Journal Title

      Journal of Asian Ceramic Societies

      Volume: 5 Issue: 4 Pages: 489-493

    • DOI

      10.1016/j.jascer.2017.10.006

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Presentation] A new insight for nucleation and crystal growth in laser-induced crystallization2019

    • Author(s)
      T. Komatsu, T. Honma
    • Organizer
      25th International Congress on Glasses (ICG2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Spatially designed assembly of nanocrystals in glasses by laser2019

    • Author(s)
      T. Komatsu, K. Shinozaki, T. Honma
    • Organizer
      25th International Congress on Glasses (ICG2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Optically transparent glass-ceramics in the system Na2O-FeO-MnO-SiO22019

    • Author(s)
      T. Honma, M. Terasawa, T. Komatsu
    • Organizer
      25th International Congress on Glasses (ICG2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Laser-induced structural modification in Na2FeP2O7 glass-ceramics2019

    • Author(s)
      M. Hiratsuka, T. Honma, T. Komatsu
    • Organizer
      25th International Congress on Glasses (ICG2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis, structure and physical properties of 1La2O3.2WO3.1B2O3 glass containing Nb2O52019

    • Author(s)
      5.L.I. Aleksandrov, R. Iordanova, M. Milanova, K. Shinozaki, T. Komatsu
    • Organizer
      25th International Congress on Glasses (ICG2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Relationship between composition and crystallization in Gd2O3-MoO3-B2O3 glasses2019

    • Author(s)
      T. Komatsu, T. Honma
    • Organizer
      The 13th Pacific Rim Conference of Ceramic Societies (PACRIM13)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Preparation of oxide glass-ceramic derived all-solid-state battery by laser irradiation2019

    • Author(s)
      M. Hiratsuka, T. Honma, T. Komatsu
    • Organizer
      The 13th Pacific Rim Conference of Ceramic Societies (PACRIM13)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Crystal growth direction and rotation in crystals patterned by laser in glasses2018

    • Author(s)
      T. Komatsu, T. Honma
    • Organizer
      International Congress on Glass (ICG) Annual Meeting 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis of ferroelastic β’-Gd2(MoO4) bulk glass-ceramics by melt cooling and their characterization2018

    • Author(s)
      H. Tsuchiya, T. Honma, T. Komatsu, R. Mueller
    • Organizer
      International Congress on Glass (ICG) Annual Meeting 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Formation of bismuth metal particles in bismuth borate glass2018

    • Author(s)
      T. Honma, Y. Omori, T. Komatsu
    • Organizer
      International Congress on Glass (ICG) Annual Meeting 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Microstructure and mechanical property of ferroelastic β’-Gd2(MoO4)3 bulk glass ceramics prepared by melt slow cooling2018

    • Author(s)
      H. Tsuchiya, T. Honma, T. Komatsu, R. Mueller
    • Organizer
      The 35th International Korea-Japan Seminar on Ceramics
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Design of crystal growth direction in laser patterned lines in glasses2017

    • Author(s)
      T. Komatsu, T. Honma
    • Organizer
      Seventh Balkan Conference on Glass Science and Technology, October 1-4, 2017, Nessebar, Bulgaria
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Stress formation and unique crystal growth in Boro-Molybdate glasses2017

    • Author(s)
      M. Kotaka, T. Honma, T. Komatsu
    • Organizer
      The 34th International Japan-Korea Seminar on Ceramics (JK-Ceramics 34), November 22-25, 2017, Hamamatsu, Japan
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Long-Persistent Luminescence of High Temperature Phase of SrAl2O4 Synthesized by Crystallization of Glass2017

    • Author(s)
      K. Shinozaki, M. Affatigato, T. Komatsu
    • Organizer
      The 34th International Japan-Korea Seminar on Ceramics (JK-Ceramics 34), November 22-25, 2017, Hamamatsu, Japan
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Design and Control of Crystallization in Oxide Glasses2017

    • Author(s)
      T. Komatsu
    • Organizer
      12th Pacific Rim Conference on Ceramic and Glass Technology (PACRIM 12), May 21-16, Hilton Waikoloa Village, Waikoloa, Hawaii, USA
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Unique crystallization behavior of Na2MnP2O7 glass and its electrochemical performances for eco-friendly sodium ion batteries2017

    • Author(s)
      T. Honma, M. Tanabe, C. Akatsuka, T. Komatsu
    • Organizer
      12th International Symposium on Crystallization in Glasses and Liquids, September 10-13, 2017, Segovia, Spain
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Unique growth behavior of ferroelastic beta’-Gd2(MoO4)3 crystals in glasses2017

    • Author(s)
      M. Kotaka, T. Honma, K. Shinozaki, M. Affatigato, R. M&uuml;ller, T. Komatsu,.
    • Organizer
      12th International Symposium on Crystallization in Glasses and Liquids, September 10-13, 2017, Segovia, Spain
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Book] Handbook of Solid Sate Chemistry, Volume 2: Synthesis2017

    • Author(s)
      T. Komatsu (分担)
    • Total Pages
      31
    • Publisher
      Wiley-VCH, Weinheim Germany
    • ISBN
      9783527325870
    • Related Report
      2017 Annual Research Report
  • [Remarks]

    • URL

      http://mst.nagaokaut.ac.jp/amorph/

    • Related Report
      2018 Annual Research Report
  • [Remarks] http://mst.nagaokaut.ac.jp/amorph/

    • Related Report
      2017 Annual Research Report

URL: 

Published: 2017-04-28   Modified: 2022-05-23  

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