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Development of dual-function catalyst to achieve high efficiency production of balk chemicals from syn-gas

Research Project

Project/Area Number 17H03452
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Reaction engineering/Process system
Research InstitutionTokyo Institute of Technology

Principal Investigator

Tago Teruoki  東京工業大学, 物質理工学院, 教授 (20304743)

Co-Investigator(Kenkyū-buntansha) 藤墳 大裕  東京工業大学, 物質理工学院, 助教 (90757105)
Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥17,550,000 (Direct Cost: ¥13,500,000、Indirect Cost: ¥4,050,000)
Fiscal Year 2019: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2018: ¥5,850,000 (Direct Cost: ¥4,500,000、Indirect Cost: ¥1,350,000)
Fiscal Year 2017: ¥7,670,000 (Direct Cost: ¥5,900,000、Indirect Cost: ¥1,770,000)
Keywords合成ガス / 基礎化学物質 / ゼオライト触媒 / 金属触媒 / 包接構造 / カプセル構造 / バードケージ構造 / ゼオライト / オレフィン / 芳香族 / イソパラフィン / 触媒反応工学 / 低級オレフィン / 貴金属 / バルクケミカル
Outline of Final Research Achievements

Rh, Fe and Co metal nanoparticles encapsulated by MFI-type zeolite, which is called as Bird-Cage structural catalyst, was developed. Rh@MFI catalyst was applied to conversion of methanol, assuming that the alcohol is generated from the synthesis gas. The decomposition of alcohol on Rh to generate hydrogen and and the simulteneous production of lighter olefin on acid sites of zeolite was observed. In addition, in the catalyst containing nanoparticles of Fe and Co (Fe@MFI and Co@MFI), the formation of lighter olefins, aromatics and iso-parafin from syngas. In summary, the direct production of basic chemicals from syngas was achieved using the Bird-Cage structural catalyst with two functions of metal and solid acid catalysts.

Academic Significance and Societal Importance of the Research Achievements

化石資源使用量の低減と二酸化炭素排出抑制のためには,メタンやバイオマスなどから得られる合成ガス(水素と一酸化炭素の混合ガス)からの有機化学物質合成が重要となる.特に,ファインケミカルズの原料である,炭素数が2以上の基礎化学物質(低級オレフィン,イソパラフィン,芳香族等)の新たな合成ルートの開発は不可欠である.金属超微粒子をゼオライト結晶内に内包させた包接構造触媒(バードケージ構造触媒)は,合成ガスから,直接これら有機化学物質の合成が可能である.したがって,本研究で達成した触媒調製法と触媒構造,および触媒反応は,環境問題解決のための重要なキーテクノロジーであると言える.

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (30 results)

All 2020 2019 2018 2017

All Journal Article (5 results) (of which Peer Reviewed: 5 results,  Acknowledgement Compliant: 1 results) Presentation (22 results) (of which Int'l Joint Research: 7 results,  Invited: 2 results) Patent(Industrial Property Rights) (3 results)

  • [Journal Article] Synthesis of Rh nanoparticles encapsulated in ZSM-5 and its application for methanol to olefin over acid sites with simultaneous production of hydrogen over Rh2020

    • Author(s)
      Fujitsuka Hiroyasu、Oshima Shuto、Matsumura Yusei、Tago Teruoki
    • Journal Title

      Catalysis Today

      Volume: - Pages: 360-368

    • DOI

      10.1016/j.cattod.2020.04.007

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of Birdcage-type zeolite catalyst and its application in dry reforming of methane2019

    • Author(s)
      藤墳 大裕、小林 昂仁、多湖 輝興
    • Journal Title

      ゼオライト

      Volume: 36 Issue: 4 Pages: 106-114

    • DOI

      10.20731/zeoraito.36.4.106

    • NAID

      40022052892

    • ISSN
      0918-7774
    • Year and Date
      2019-10-15
    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Birdcage-type zeolite encapsulating ultrafine Pt nanoparticles and its application in dry reforming of methane2019

    • Author(s)
      Kobayashi Takahito、Furuya Takaaki、Fujitsuka Hiroyasu、Tago Teruoki
    • Journal Title

      Chemical Engineering Journal

      Volume: 377 Pages: 120203-120210

    • DOI

      10.1016/j.cej.2018.10.140

    • Related Report
      2019 Annual Research Report 2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Light Olefins from Oxygenated Organic Compounds over Metallosilicates with MFI and MTW-type Zeolite Structures2017

    • Author(s)
      Yuta Nakasaka, Teruoki Tago, Takao Masuda
    • Journal Title

      Journal of the Japan Petroleum Institute

      Volume: 60 Issue: 6 Pages: 277-287

    • DOI

      10.1627/jpi.60.277

    • NAID

      130006192038

    • ISSN
      1346-8804, 1349-273X
    • Year and Date
      2017-11-01
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Kinetic studies on high-pressure methylation of 2-methylnaphthalene over MTW-type zeolite with different crystal sizes2017

    • Author(s)
      G. Watanabe, Y. Nakasaka, T. Taniguchi, T. Yoshikawa, T. Tago, T. Masuda
    • Journal Title

      Chemical Engineering Journal

      Volume: 312 Pages: 288-295

    • DOI

      10.1016/j.cej.2016.11.139

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 合成ガスからのイソパラフィン直接合成を指向したCo微粒子内包ZSM-5触媒の開発2020

    • Author(s)
      鶴迫秀太,藤墳大裕,多湖輝興
    • Organizer
      第85回化学工学会年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 金属超微粒子内包ゼオライト触媒によるメタン改質2020

    • Author(s)
      多湖輝興
    • Organizer
      触媒学会東日本支部講演会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] Low temperature olefin production from naphtha by combining dehydrogenation and cracking using metal loaded zeolite2019

    • Author(s)
      Hiroyasu Fujitsuka, Mai Yamaji, Takashi Yunoue, Teruoki Tago
    • Organizer
      International Symposium on Porous Materials 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 貴金属超微粒子内包ZSM-5ゼオライト触媒によるn-ヘキサンの低温接触分解2019

    • Author(s)
      山地真愛,湯上天史,藤墳大裕,多湖輝興
    • Organizer
      第49回石油・石油化学討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 合成ガスからの芳香族類直接合成を指向した鉄系酸化物内包ZSM-5の調製2019

    • Author(s)
      鶴迫秀太,大島修斗,藤墳大裕,多湖輝興
    • Organizer
      第124回触媒討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] メタンCO2改質用Ni微粒子内包ゼオライト触媒の開発と触媒構造による高活性・安定性の実現2019

    • Author(s)
      藤墳大裕,小林昂仁,丁明岐,多湖輝興
    • Organizer
      第124回触媒討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Preparation of Ni nanoparticles encapsulated in Silicalite-1 zeolite to suppress coke formation during dry reforming of methane2019

    • Author(s)
      Hiroyasu Fujitsuka, Takahito Kobayashi, Teruoki Tago
    • Organizer
      International Zeolite Conference (IZC'19)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] The synthesis of ZSM 5-encapsulated Rh fine particles and its application for methanol-to-olefin reaction2019

    • Author(s)
      Hiroyasu Fujitsuka, Shuto Oshima, Yusei Matsumura, Teruoki Tago
    • Organizer
      The 8th Asia Pacific Congress on Catalysis
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] The preparation of Al-MFI zeolite encapsulated metal nanoparticles via solid-state transformation2019

    • Author(s)
      Natnicha Yotpanya, Bruno Nonohay, Hiroyasu Fujitsuka, Chizu Inaki, Shunji Tsuruta, Akira Nakashima, Teruoki Tago
    • Organizer
      The 8th Asia Pacific Congress on Catalysis
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 酸化鉄内包シリカを出発源とした酸化鉄内包Birdcage型ゼオライトの調製2019

    • Author(s)
      鶴迫 秀太, 大島 修斗, 藤墳 大裕, 多湖 輝興
    • Organizer
      第21回化学工学会学生発表会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Synthesis of birdcage-type zeolite encapsulating ultrafine Pt nanoparticles and its application to dry reforming of methane2018

    • Author(s)
      Takahito Kobayashi, Takaaki Furuya, Hiroyasu Fujitsuka, Teruoki Tago
    • Organizer
      25th International Symposium on Chemical Reaction Engineering
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Solid-phase Transformation of Amorphous Silica with Aluminum into Zeolite2018

    • Author(s)
      Natnicha Yotpanya, Bruno Nonohay, Hiroyasu Fujitsuka, Chizu Inaki, Shunji Tsuruta, Nakashima Akira, Teruoki Tago
    • Organizer
      The 31st International Symposium on Chemical Engineering
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis of Birdcage-type Zeolite Encapsulating Pt Nanoparticles and its Catalytic Activity and Thermal Stability for Dry Reforming of Methane2018

    • Author(s)
      Hiroyasu Fujitsuka, Takahito Kobayashi, Takaaki Furuya, Teruoki Tago
    • Organizer
      International Symposium on Zeolites and Microporous Crystals (ZMPC) 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] コーク抑制を可能とするメタンドライリフォーミング用Ni@Silicalite-1触媒の開発2018

    • Author(s)
      小林昂仁, 藤墳大裕, 多湖輝興
    • Organizer
      ゼオライト研究発表会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 金属超微粒子内包Birdcage構造ゼオライト触媒の開発とMTO反応への適用2018

    • Author(s)
      大島修斗, 松村悠生, 藤墳大裕, 多湖輝興
    • Organizer
      第50回化学工学会秋季大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 金属超微粒子 内包ゼオライトの調製と触媒 反応への展開2018

    • Author(s)
      多湖輝興
    • Organizer
      第122回 触媒討論会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Rh超微粒子内包Birdcage型ゼオライトへの酸点導入とメタノール転換反応活性2018

    • Author(s)
      松村悠生,大島修斗,藤墳大裕,多湖輝興
    • Organizer
      第20回化学工学会学生発表会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Rh超微粒子内包Birdcage型ZSM-5を用いたメタノールからのオレフィン合成2017

    • Author(s)
      大島修斗,古屋貴章,藤墳大裕,多湖輝興
    • Organizer
      第120回触媒討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Pt超微粒子内包Birdcage型ゼオライト触媒の開発とメタンドライリフォーミングへの適用2017

    • Author(s)
      小林昂仁,古屋貴章,藤墳大裕,多湖輝興
    • Organizer
      第120回触媒討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Synthesis Al-MFI zeolites encapsulating Pt nanoparticles2017

    • Author(s)
      Nonohay BrunoTakaaki FuruyaHiroyasu FujitsukaTeruoki Tago
    • Organizer
      第49回化学工学会秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 白金超微粒子内包Birdcage型ゼオライト触媒の合成とメタンの二酸化炭素改質への適用2017

    • Author(s)
      藤墳大裕,小林昂仁,古屋貴章,多湖輝興
    • Organizer
      第47回石油・石油化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 酸量と金属担持量を独立に制御したRh超微粒子内包Birdcage構造ゼオライト触媒の開発2017

    • Author(s)
      大島修斗,松村悠生,藤墳大裕,多湖輝興
    • Organizer
      第33回ゼオライト研究発表会
    • Related Report
      2017 Annual Research Report
  • [Patent(Industrial Property Rights)] 貴金属微粒子が内包されたゼオライトの製造法2018

    • Inventor(s)
      多湖輝興,藤墳大裕,ノノハイ ブルノ,稲木千津,中島昭
    • Industrial Property Rights Holder
      東京工業大学,日揮触媒化成
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2018-183712
    • Filing Date
      2018
    • Related Report
      2018 Annual Research Report
  • [Patent(Industrial Property Rights)] 表面近傍に遷移金属が内包されたゼオライトおよびその製造法2018

    • Inventor(s)
      稲木千津,鶴田俊二,中島昭,多湖輝興,藤墳大裕
    • Industrial Property Rights Holder
      東京工業大学,日揮触媒化成
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2018-222638
    • Filing Date
      2018
    • Related Report
      2018 Annual Research Report
  • [Patent(Industrial Property Rights)] 触媒,触媒の製造方法,及び合成ガスの製造方法2018

    • Inventor(s)
      荒木泰博,多湖輝興,藤墳大裕美裕,小林昂仁
    • Industrial Property Rights Holder
      JXTGエネルギー,東京工業大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2018-199298
    • Filing Date
      2018
    • Related Report
      2018 Annual Research Report

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Published: 2017-04-28   Modified: 2021-02-19  

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