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Development of innovative metal nanoparticle catalyst based on the interfacial cooperative effect

Research Project

Project/Area Number 17H03457
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Catalyst/Resource chemical process
Research InstitutionOsaka University

Principal Investigator

Mitsudome Takato  大阪大学, 基礎工学研究科, 准教授 (00437360)

Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥17,680,000 (Direct Cost: ¥13,600,000、Indirect Cost: ¥4,080,000)
Fiscal Year 2019: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2018: ¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2017: ¥9,360,000 (Direct Cost: ¥7,200,000、Indirect Cost: ¥2,160,000)
Keywordsナノ粒子 / 触媒 / グリーンケミストリ― / 還元反応 / 金属ナノ粒子 / 合金 / 界面 / グリーンケミストリー / 協奏効果
Outline of Final Research Achievements

Amine synthesis via amide hydrogenation is of crucial importance in organic synthesis. However, amide groups have low reactivity and are difficult to reduce. In 2005, a Roundtable of the ACS Green Chemistry Institute and leading global pharmaceutical companies decided “the catalytic hydrogenation of amides to amines with H2 under mild conditions, ideally lower than 30 bar H2 and 70 oC” is one of 12 key innovative research areas for the future sustainable production of pharmaceuticals. However, until now, no catalysts that are effective under the mild conditions have been developed.
Herein, we present VOx-decorated Pt nanoparticle catalyst that enables hydrogenation of amides to amines under mild conditions, i.e., lower than 30 bar H2/70 oC.2 Especially, the bimetallic catalyst could promote the hydrogenation under just 1 bar of H2 at 70 oC or 5 bar of H2 at room temperature. This is the first time that hydrogenation of amides to amines under mild conditions has been achieved.

Academic Significance and Societal Importance of the Research Achievements

研究成果の学術的意義:白金とバナジウムを複合すると、白金で水素を、バナジウムでアミドを活性化する協奏的触媒作用により高難度の還元反応を促進させることに成功した。本成果は、異種金属を複合化することで、異種金属間の協奏効果を最大限に発現させる新規なバイメタルナノ粒子の触媒設計指針を与える。

社会的意義:本研究成果により、世界で初めて常圧の水素ガスでアミドを還元することができることを示し、次世代の高機能化学品製造プロセスにおける夢の反応の一つを実現したことから、省エネルギーかつ安全で、有害な廃棄物を一切副生しないアミドの還元反応プロセスの開発が期待されます。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (75 results)

All 2020 2019 2018 2017

All Journal Article (15 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 15 results,  Open Access: 13 results) Presentation (60 results) (of which Int'l Joint Research: 15 results,  Invited: 5 results)

  • [Journal Article] Unique Catalysis of Nickel Phosphide Nanoparticles to Promote the Selective Transformation of Biofuranic Aldehydes into Diketones in Water2020

    • Author(s)
      Fujita, Shu; Nakajima, Kiyotaka; Yamasaki, Jun; Mizugaki, Tomoo; Jitsukawa, Koichiro; Mitsudome, Takato
    • Journal Title

      ACS Catalysis

      Volume: 10 Issue: 7 Pages: 4261-4267

    • DOI

      10.1021/acscatal.9b05120

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Pd/Cu-Catalyzed Dehydrogenative Coupling of Dimethyl Phthalate: Synchrotron Radiation Sheds Light on the Cu Cycle Mechanism2020

    • Author(s)
      Kanazawa, Yuki; Mitsudome, Takato; Takaya, Hikaru; Hirano, Masafumi
    • Journal Title

      ACS Catalysis

      Volume: 10 Issue: 10 Pages: 5909-5919

    • DOI

      10.1021/acscatal.0c00918

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Efficient synthesis of benzofurans via cross-coupling of catechols with hydroxycoumarins using O2 as an oxidant catalyzed by AlPO4-supported Rh nanoparticle2019

    • Author(s)
      Z. Maeno, M. Yamamoto, T. Mitsudome, T. Mizugaki, K. Jitsukawa
    • Journal Title

      ChemistrySelect

      Volume: 4 Issue: 38 Pages: 11394-11397

    • DOI

      10.1002/slct.201903117

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Air-stable and reusable cobalt ion-doped titanium oxide catalyst for alkene hydrosilylation2019

    • Author(s)
      T. Mitsudome, S. Fujita, M. Sheng, J. Yamasaki, K. Kobayashi, T. Yoshida, Z. Maeno, T. Mizugaki, K. Jitsukawa, K. Kaneda
    • Journal Title

      Green Chemistry

      Volume: 21 Issue: 16 Pages: 4566-4570

    • DOI

      10.1039/c9gc01981b

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] アミドからアミンへの環境調和型還元反応2019

    • Author(s)
      満留敬人
    • Journal Title

      触媒

      Volume: 61 Pages: 260-265

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Solution XAS analysis for exploring active species in syndiospecific styrene polymerization and 1-hexene polymerization using half-titanocene - MAO catalysts: Significant changes in the oxidation state in the presence of styrene2019

    • Author(s)
      K. Nomura, I. Izawa, J. Yi, N. Nakatani, H. Aoki, T. Ina, T. Mitsudome, N. Tomotsu, S. Yamazoe
    • Journal Title

      Organometallics

      Volume: 38 Issue: 22 Pages: 4497-4507

    • DOI

      10.1021/acs.organomet.9b00638

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] XAS Analysis for reactions of (arylimido)vanadium(V) dichloride complexes containing anionic NHC that contains weakly coordinating B(C6F5)3 moiety (WCA-NHC) or phenoxide ligands with Al alkyls: A potential ethylene polymerization catalyst with WCA-NHC ligand2019

    • Author(s)
      K. Nomura, G. Nagai, I. Izawa, T. Mitsudome, M. Tamm, S. Yamazoe
    • Journal Title

      ACS Omega

      Volume: 4 Issue: 20 Pages: 18833-18845

    • DOI

      10.1021/acsomega.9b02828

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Oxidative cross-coupling reaction of catechols with active methylene compounds in an aqueous medium using an AlPO4-supported Ru catalyst2018

    • Author(s)
      Maeno Zen、Yamamoto Masanobu、Mitsudome Takato、Mizugaki Tomoo、Jitsukawa Koichiro
    • Journal Title

      Catalysis Science & Technology

      Volume: 8 Issue: 21 Pages: 5401-5405

    • DOI

      10.1039/c8cy01425f

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Mechanistic Insights on Pd/Cu-Catalyzed Dehydrogenative Coupling of Dimethyl Phthalate2018

    • Author(s)
      Hirano Masafumi、Sano Kosuke、Kanazawa Yuki、Komine Nobuyuki、Maeno Zen、Mitsudome Takato、Takaya Hikaru
    • Journal Title

      ACS Catalysis

      Volume: 8 Issue: 7 Pages: 5827-5841

    • DOI

      10.1021/acscatal.8b01095

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Synthesis of glycol diesters through the depolymerization of polyethylene glycols with carboxylic acids using a proton-exchanged montmorillonite catalyst2018

    • Author(s)
      Maeno Zen、Midogochi Kaoru、Mitsudome Takato、Mizugaki Tomoo、Jitsukawa Koichiro
    • Journal Title

      Tetrahedron Letters

      Volume: 59 Issue: 9 Pages: 832-835

    • DOI

      10.1016/j.tetlet.2018.01.056

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] A Titanium Dioxide Supported Gold Nanoparticle Catalyst for the Selective N-Formylation of Functionalized Amines with Carbon Dioxide and Hydrogen2017

    • Author(s)
      Mitsudome Takato、Urayama Teppei、Fujita Shu、Maeno Zen、Mizugaki Tomoo、Jitsukawa Koichiro、Kaneda Kiyotomi
    • Journal Title

      ChemCatChem

      Volume: 9 Issue: 19 Pages: 3632-3636

    • DOI

      10.1002/cctc.201700726

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Mild Hydrogenation of Amides to Amines over a Platinum-Vanadium Bimetallic Catalyst2017

    • Author(s)
      Mitsudome Takato、Miyagawa Kazuya、Maeno Zen、Mizugaki Tomoo、Jitsukawa Koichiro、Yamasaki Jun、Kitagawa Yasutaka、Kaneda Kiyotomi
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 56 Issue: 32 Pages: 9381-9385

    • DOI

      10.1002/anie.201704199

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Effective management of polyethers through depolymerization to symmetric and unsymmetric glycol diesters using a proton-exchanged montmorillonite catalyst2017

    • Author(s)
      Maeno Zen、Yamada Shota、Mitsudome Takato、Mizugaki Tomoo、Jitsukawa Koichiro
    • Journal Title

      Green Chemistry

      Volume: 19 Issue: 11 Pages: 2612-2619

    • DOI

      10.1039/c7gc00817a

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] A dual-functional heterogeneous ruthenium catalyst for the green one-pot synthesis of biphenols2017

    • Author(s)
      Maeno Zen、Mitsudome Takato、Mizugaki Tomoo、Jitsukawa Koichiro
    • Journal Title

      Catalysis Science & Technology

      Volume: 7 Issue: 15 Pages: 3205-3209

    • DOI

      10.1039/c7cy00919d

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] New Routes for Refinery of Biogenic Platform Chemicals Catalyzed by Cerium Oxide-supported Ruthenium Nanoparticles in Water2017

    • Author(s)
      Mizugaki Tomoo、Togo Keito、Maeno Zen、Mitsudome Takato、Jitsukawa Koichiro、Kaneda Kiyotomi
    • Journal Title

      Scientific Reports

      Volume: 7 Issue: 1 Pages: 14007-14007

    • DOI

      10.1038/s41598-017-14373-1

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Presentation] ニトリルの環境調和型水素化反応を指向したリン化コバルトナノ粒子触媒の開発2020

    • Author(s)
      満留敬人・盛 敏・水垣共雄
    • Organizer
      第125回触媒討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Pt-Mo系個体触媒によるカルボン酸誘導体の選択的還元反応2020

    • Author(s)
      水垣共雄・硲田捷将・近藤大貴・満留敬人
    • Organizer
      第125回触媒討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Cobalt Phosphide Nano Crystalline as a Green Hydrogenation Catalyst2019

    • Author(s)
      盛 敏
    • Organizer
      第10回触媒科学研究発表会
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Design of nano-structured catalysts for environmentally benign and selective molecular transformations2019

    • Author(s)
      満留敬人
    • Organizer
      9th European Chemistry Congress
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] アミドからアミンへ環境調和型水素化反応を可能にする バイメタルナノ粒子触媒の開発2019

    • Author(s)
      木村未歩・高橋一広・満留敬人・水垣共雄
    • Organizer
      第 8 回 JACI/GSC シンポジウム
    • Related Report
      2019 Annual Research Report
  • [Presentation] Cobalt phosphide nanorod as an air-stable catalyst for hydrogenation of furfural derivatives2019

    • Author(s)
      石川浩也
    • Organizer
      the 8th Asia-Pacific Congress in Catalysis (APCAT-8)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Selective C-C Bond Cleavage of Primary Alcohols Catalyzed by Cerium Oxide-Supported Pd Nanoparticle2019

    • Author(s)
      近藤大貴
    • Organizer
      第13回触媒道場
    • Related Report
      2019 Annual Research Report
  • [Presentation] Pd/CeO2触媒を用いた環境調和型の脱ヒドロキシメチル化反応2019

    • Author(s)
      水垣共雄・近藤大貴・満留敬人・實川浩一郎
    • Organizer
      第124回触媒討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] ロジウム-モリブデン合金ナノ粒子触媒による環境調和型アミド還元反応2019

    • Author(s)
      満留敬人・木村未歩・水垣共雄・實川浩一郎
    • Organizer
      第124回触媒討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Development of Highly Efficient Catalyst System for Chemoselective One-carbon Degradation of Primary Alcohols Using Pd/CeO22019

    • Author(s)
      Hiroki Kondo, Takato Mitsudome, Koichiro Jitsukawa, Tomoo Mizugaki
    • Organizer
      the 3rd Osaka-Kansai International Symposium on Catalysis (OKCAT2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Design of Nano-structured Catalysts for Environmentally Benign and Selective Molecular Transformations2019

    • Author(s)
      満留敬人
    • Organizer
      OKCAT2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Transformations using High Performance Nano Catalysts2019

    • Author(s)
      満留敬人
    • Organizer
      Catalysis Engineering & Technology (CatET-2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 高難度還元反応を促進させる複合金属ナノ触媒2019

    • Author(s)
      満留敬人
    • Organizer
      令和元年度触媒技術セミナー
    • Related Report
      2019 Annual Research Report
  • [Presentation] 高難度還元反応を促進させる環境調和型金属ナノ触媒の開発とXAFSによる活性発現因子の解明2019

    • Author(s)
      満留敬人
    • Organizer
      第8回Spring-8グリーンサスティナブルケミストリー研究会/第47回Spring-8先端利用技術ワ-クショップ
    • Related Report
      2019 Annual Research Report
  • [Presentation] 酸化セリウム担持パラジウム触媒による一級アルコールの選択的C-C結合切断反応2019

    • Author(s)
      近藤 大貴・満留 敬人・水垣 共雄・實川 浩一郎
    • Organizer
      日本化学会第99春季年会(2019)
    • Related Report
      2018 Annual Research Report
  • [Presentation] 温和な反応条件下において効率的にアミドをアミンへと変換するRh-Moバイメタル触媒の開発2019

    • Author(s)
      高橋 一広・木村 未歩・満留 敬人・水垣 共雄・實川 浩一郎
    • Organizer
      日本化学会第99春季年会(2019)
    • Related Report
      2018 Annual Research Report
  • [Presentation] アルケンの選択的ヒドロシリル化反応を促進する酸化チタン担持コバルト酸化物ナノ粒子触媒の開発2019

    • Author(s)
      盛 敏・藤田 周・満留 敬人・水垣 共雄・實川 浩一郎
    • Organizer
      日本化学会第99春季年会(2019)
    • Related Report
      2018 Annual Research Report
  • [Presentation] Pt-Mo系触媒を用いたエステル共存下でのカルボン酸の選択的還元反応2019

    • Author(s)
      新田晃大・近藤大貴・満留敬人・水垣共雄・實川浩一郎
    • Organizer
      第123回触媒討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Pd/CeO2触媒を用いた水素フリーの1級アルコールの位置選択的炭素-炭素結合切断反応2019

    • Author(s)
      水垣共雄・近藤大貴・新田晃大・満留敬人・實川浩一郎
    • Organizer
      第123回触媒討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] CO2を炭素源としたアミン類の選択的ホルミル化反応を促進する酸化チタン担持金ナノ粒子触媒の開発2018

    • Author(s)
      藤田 周
    • Organizer
      第 7 回 JACI/GSC シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] Development of a Titanium Dioxide-Supported Gold Nanoparticle Catalyst for the Selective N-Formylation of Functionalized Amines Using Carbon Dioxide2018

    • Author(s)
      Shu FUJITA, Takato MITSUDOME, Zen MAENO, Tomoo MIZUGAKI, Koichiro JITSUKAWA, Kiyotomi KANEDA
    • Organizer
      The 8th Tokyo Conference on Advanced Catalytic Science and Technology (TOCAT8)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Development of Vanadium-decorated Platinum Nanoparticle Catalyst for Green Sustainable Hydrogenation of Amides to Amines2018

    • Author(s)
      Takato MITSUDOME, Kazuhiro TAKAHASHI, Zen MAENO, Tomoo MIZUGAKI, Koichiro JITSUKAWA
    • Organizer
      The 8th Tokyo Conference on Advanced Catalytic Science and Technology (TOCAT8)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] アルケンの選択的ヒドロシリル化反応を促進する酸化チタン担持コバルト酸化物ナノ粒子触媒の開発2018

    • Author(s)
      盛敏・藤田周・満留敬人・水垣共雄・實川浩一郎・金田清臣
    • Organizer
      第121回触媒討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Pt-Mo系触媒を用いたカルボン酸からアルコールへの選択的水素化反応2018

    • Author(s)
      新田晃大・近藤大貴・満留敬人・水垣共雄・實川浩一郎・金田清臣
    • Organizer
      第121回触媒討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] ホスフィンオキシドの脱酸素反応を促進する酸化チタン担持金ナノ粒子触媒の開発2018

    • Author(s)
      藤田周・盛敏・満留敬人・水垣共雄・實川浩一郎・金田清臣
    • Organizer
      第121回触媒討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 温和な条件下でアミドをアミンへと還元するPt-Vバイメタル触媒―VによるPt表面被服効果2018

    • Author(s)
      木村未歩・高橋一広・満留敬人・水垣共雄・實川浩一郎・金田清臣
    • Organizer
      第121回触媒討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Development of the highly efficient bimetallic nanoparticle catalyst for mild hydrogenation of amides to amines.2018

    • Author(s)
      Kazuhiro Takahashi, Miho Kimura, Takato Mitsudome, Tomoo Mizugaki, Koichiro Jitsukawa
    • Organizer
      OKCAT2018(Osaka-Kansai International Symposium on Catalysis)
    • Related Report
      2018 Annual Research Report
  • [Presentation] Selective carbon-carbon bond cleavage of primary alcohols using Pd/CeO2 Catalyst2018

    • Author(s)
      Hiroki Kondo, Takato Mitsudome, Tomoo Mizugaki, Koichiro Jitsukawa
    • Organizer
      OKCAT2018(Osaka-Kansai International Symposium on Catalysis)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Pd触媒の特性を利用した1級アルコールの酸化的脱ヒドロキシメチル化反応2018

    • Author(s)
      水垣共雄、近藤大貴、上杉晃平、満留敬人、實川浩一郎
    • Organizer
      第51回酸化反応討論会2018
    • Related Report
      2018 Annual Research Report
  • [Presentation] ハイブリッド金属ナノ粒子触媒による環境調和型分子変換とCO2の有効利用2018

    • Author(s)
      満留敬人
    • Organizer
      石油化学部会シンポジウム CCUS-エネルギーと化学におけるCO2回収固定・利用
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Mild Hydrogenation of Amides to Amines Over Pt-V bimetal Catalyst2018

    • Author(s)
      Takato Mitsudome
    • Organizer
      C&FC2018 ファインケミカルズ合成触媒国際会議2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Highly selective N-formylation of amines using CO2 as a carbonyl source over titania supported gold nanoparticle catalyst2018

    • Author(s)
      藤田 周
    • Organizer
      C&FC2018 ファインケミカルズ合成触媒国際会議2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Hydrosilylation of Alkenes by Titanium Dioxide-supported Cobalt Oxide Catalyst2018

    • Author(s)
      盛 敏
    • Organizer
      C&FC2018 ファインケミカルズ合成触媒国際会議2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Hybrid Metal Nanoparticles for Green Sustanable Hydrogenation of Amides2018

    • Author(s)
      満留敬人
    • Organizer
      RSC Symposium: Frontiers of Catalysis and Photocatalysis for Energy Chemistry
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 固定化ルテニウム触媒を用いたカテコール類と活性メチレン化合物の酸化的クロスカップリング反応2018

    • Author(s)
      前野禅・山本昌信・満留敬人・水垣共雄・實川浩一郎
    • Organizer
      第121回触媒討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 酸化セリウム固定化ルテニウムナノ粒子触媒による含酸素化合物の位置選択的炭素-炭素結合切断反応2018

    • Author(s)
      水垣共雄・上杉晃平・新田晃大・前野禅・満留敬人・實川浩一郎・金田清臣
    • Organizer
      第121回触媒討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 温和な条件下でアミドの還元反応を促進するPt-Vバイメタルナノ粒子触媒の開発2018

    • Author(s)
      満留敬人・高橋 一広・前野禅・水垣共雄・實川浩一郎・金田清臣
    • Organizer
      第121回触媒討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Pd担持CeO2触媒を用いた一級アルコール類の位置選択的炭素-炭素結合切断反応2018

    • Author(s)
      上杉 晃平・水垣 共雄・前野 禅・満留 敬人・實川 浩一郎・金田 清臣
    • Organizer
      98回春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 酸化チタン担持金ナノ粒子触媒によるCO2をカルボニル源としたアミン類の選択的ホルミル化反応2018

    • Author(s)
      藤田 周・満留 敬人・前野 禅・水垣 共雄・實川 浩一郎・金田 清臣
    • Organizer
      98回春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 固定化金属触媒を用いたカテコール類と活性メチレン化合物の酸化的クロスカップリング反応2018

    • Author(s)
      山本 昌信・前野 禅・満留 敬人・水垣 共雄・實川 浩一郎
    • Organizer
      98回春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Valorization of Polyether Wastes through Efficient Depolymerization Using Layered Solid Acid Catalysts2018

    • Author(s)
      MAENO Zen, MITSUDOME Takato, MIZUGAKI Tomoo, JITSUKAWA Koichiro
    • Organizer
      98回春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 温和な条件でアミドの還元を促進するハイブリッド金属ナノ粒子触媒の開発2018

    • Author(s)
      満留 敬人・高橋 一広・前野 禅・水垣 共雄・實川 浩一郎・金田 清臣
    • Organizer
      98回春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ルテニウム担持酸化セリウム触媒を用いたバイオマス由来含酸素化合物の位置選択的炭素-炭素結合切断反応2018

    • Author(s)
      水垣 共雄・上杉 晃平・新田 晃大・前野 禅・満留 敬人・實川 浩一郎・金田 清臣
    • Organizer
      98回春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 温和な条件下でアミドを還元するバイメタルナノ粒子触媒の開発2018

    • Author(s)
      満留敬人・ 高橋 一広・前野禅・水垣共雄・實川浩一郎・金田清臣
    • Organizer
      化学工学会第83年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ルテニウム担持酸化セリウム触媒を用いたバイオマス由来含酸素化合物の選択的炭素-炭素結合切断反応系の開発2018

    • Author(s)
      水垣共雄・上杉 晃平・ 新田晃大・前野禅・満留敬人・實川浩一郎・金田清臣
    • Organizer
      化学工学会第83年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Development of Gold Nanoparticle Catalyst for Safe, Clean and On-demand Hydrogen Production from Organosilane Wastes2018

    • Author(s)
      満留敬人
    • Organizer
      3D活性サイト科学 第7回成果発表会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Sustainable Amine Production through Hydrogenation of Amides under Mild Conditions2017

    • Author(s)
      満留敬人
    • Organizer
      6th Shimadzu International Collaborative Laboratory Forum
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] ナノ粒子担持触媒の構造と触媒活性・選択性2017

    • Author(s)
      満留敬人
    • Organizer
      岡山大学 ナノ材料シンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] カテコール類と活性メチレン化合物の酸化的カップリング反応を促進する固定化金属触媒の開発2017

    • Author(s)
      前野禅, 山本 昌信, 満留敬人, 水垣共雄, 實川浩一郎
    • Organizer
      第50回酸化反応討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Vanadium-decorated Platinum Nanoparticle Catalyst for Green Sustainable Hydrogenation of Amides to Amines2017

    • Author(s)
      T. Mitsudome, Z. Maeno, T. Mizugaki, K. Jitsukawa and K. Kaneda
    • Organizer
      国際シンポジウム “Future Earth”エネルギー課題に資する新奇なナノ物質・触媒・表面
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Selective C-C bond cleavage of glycerol derivative using Pd/CeO2catalyst2017

    • Author(s)
      Kohei Uesugi,Tomoo Mizugaki,Zen Maeno,Takato Mitsudome,Koichiro Jitsukawa,Kiyotomi Kaneda
    • Organizer
      第2回キャタリストクラブ例会・第10回触媒表面化学研究発表会・ OKCAT2018
    • Related Report
      2017 Annual Research Report
  • [Presentation] Highly selective N-formylation of amines using CO2and H2catalyzed by TiO2-supported gold nanoparticles2017

    • Author(s)
      Shu Fujita,Takato Mitsudome,Zen Maeno,Tomoo Mizugaki,Koichiro Jitsukawa,Kiyotomi Kaneda
    • Organizer
      第2回キャタリストクラブ例会・第10回触媒表面化学研究発表会・ OKCAT2017
    • Related Report
      2017 Annual Research Report
  • [Presentation] カテコール類と活性メチレン化合物の脱水素クロスカップリング反応を促進する固定化金属触媒の開発2017

    • Author(s)
      前野禅・山本昌信・満留敬人・水垣共雄・實川浩一郎
    • Organizer
      第119回触媒討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 酸化セリウム固定化ルテニウム触媒を用いた還元的炭素-炭素結合切断反応2017

    • Author(s)
      水垣共雄・前野禅・満留敬人・實川浩一郎・金田清臣
    • Organizer
      第119回触媒討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] CO2をカルボニル源としたアミンの選択的ホルミル化反応を促進する酸化チタン担持金ナノ粒子触媒の開発2017

    • Author(s)
      藤田周・満留敬人・前野禅・水垣共雄・實川浩一郎・金田清臣
    • Organizer
      第119回触媒討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ハイドロキシアパタイト固定化白金-モリブデン触媒によるカルボン酸の高選択的水素化反応2017

    • Author(s)
      満留敬人・水垣共雄・新田晃大・前野禅・實川浩一郎・金田清臣
    • Organizer
      第119回触媒討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 層状固体酸触媒によるカルボン酸誘導体を用いたポリエーテルの解重合反応2017

    • Author(s)
      實川浩一郎・前野禅・山田翔太・御堂河内薫・満留敬人・水垣共雄
    • Organizer
      第119回触媒討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] バイオマス由来有機酸の高度利用を指向したハイドロキシアパタイト固定化Pt-MoOx触媒のXAFS解析2017

    • Author(s)
      金田清臣, 水垣共雄, 前野禅, 満留敬人, 實川浩一郎, 小野圭輔, 梶川泰照 and 平井雄一郎
    • Organizer
      第14回SPring-8 産業利用報告会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 高選択的分子変換を可能とする高活性複合金属ナノ粒子触媒の設計と開発2017

    • Author(s)
      満留敬人
    • Organizer
      第401回触媒科学研究所コロキウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] Development of Gold Nanoparticle Catalyst for Safe, Clean and On-demand Hydrogen Production from Organosilane Wastes2017

    • Author(s)
      満留敬人
    • Organizer
      Shimadzu Global Innovation Summit 2017
    • Related Report
      2017 Annual Research Report

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Published: 2017-04-28   Modified: 2021-02-19  

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