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Preparation of precious metal-metal oxide interfaces by using metal oxide nanosheets

Research Project

Project/Area Number 17H03461
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Catalyst/Resource chemical process
Research InstitutionDoshisha University

Principal Investigator

Takenaka Sakae  同志社大学, 理工学部, 教授 (10302936)

Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥17,290,000 (Direct Cost: ¥13,300,000、Indirect Cost: ¥3,990,000)
Fiscal Year 2019: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2018: ¥7,280,000 (Direct Cost: ¥5,600,000、Indirect Cost: ¥1,680,000)
Fiscal Year 2017: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Keywords金属酸化物ナノシート / 貴金属 / 界面 / 触媒 / 貴金属ー酸化物界面 / ナノシート / グラフェン / 触媒・化学プロセス / ナノ材料 / コアシェル型触媒
Outline of Final Research Achievements

Precious metals have been frequently utilized as catalytically active components. The precious metal loading in the catalysts should be reduced due to their high costs. The catalytic performance of precious metals can be modified by their deposition on the catalytic supports. The precious metals are strongly interacted with the support materials, which results in the improvement of the catalytic performance of precious metals. We have prepared metal oxide nanosheets using graphene oxide. In the present study, Pt nanoparticles were supported on graphene oxide and then the samples thus obtained were covered with metal oxide nanosheets. Finally, the samples were treated in air at high temperatures for the removal of graphene oxide. Pt metal particles in the samples were covered with metal oxide nanosheets. Thus, the catalysts showed the catalytic performance based on the Pt-metal oxide interface.

Academic Significance and Societal Importance of the Research Achievements

代替エネルギーの開発,環境保全,ファインケミカル合成など様々な分野で触媒の高機能化が求められている.また元素戦略の観点から,貴金属使用量低減も求められている.限られた貴金属使用量で触媒を高機能化するには,活性点あたりの機能性向上が必要となる.その方法の1つに貴金属―酸化物界面の精密設計があると考えている.本研究で開発した触媒は,貴金属―酸化物界面を優先的に有するコア-シェル型触媒である.これらの触媒を利用すれば,触媒化学で古くから注目されている担体効果を明らかにでき,触媒化学の学術的発展に大きく貢献できると考えている.

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (6 results)

All 2019 2018 2017

All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (5 results) (of which Invited: 3 results)

  • [Journal Article] Preparation of composite catalysts composed of Pt nanoparticles and metal2018

    • Author(s)
      S. Takenaka, R. Kaji, K. Sugiyama and R. Ida
    • Journal Title

      Applied Catalysis A: General

      Volume: 566 Pages: 52-59

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Presentation] タンタル酸化物ナノシートを利用したグラフェン担持Ptカソード触媒の高耐久化2019

    • Author(s)
      杉山晃次郎,竹中 壮
    • Organizer
      第49回石油・石油化学討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] PEFC用Pt触媒の高耐久化に向けた取り組み2018

    • Author(s)
      竹中 壮
    • Organizer
      KRIワークショップ2
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 相界面設計によるPEFC用Ptカソード触媒の高活性化・高耐久化2018

    • Author(s)
      竹中 壮
    • Organizer
      第6回 元素戦略に基づいた触媒設計シンポジウム
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] ナノスケール炭素をテンプレートに利用した触媒創成2017

    • Author(s)
      竹中 壮
    • Organizer
      平成29年度第1回キャタリストクラブ例会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 酸化グラフェンを利用したコアーシェル型Pt-金属酸化物ナノシート触媒の調製2017

    • Author(s)
      竹中 壮,杉山晃次郎,井田 涼,岸田昌浩
    • Organizer
      第120回触媒討論会
    • Related Report
      2017 Annual Research Report

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Published: 2017-04-28   Modified: 2021-02-19  

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