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Research for magnetic refrigeration cycle for hydrogen liquefaction

Research Project

Project/Area Number 17H03534
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Energy engineering
Research InstitutionKanazawa University

Principal Investigator

MATSUMOTO KOICHI  金沢大学, 数物科学系, 教授 (10219496)

Co-Investigator(Kenkyū-buntansha) 沼澤 健則  国立研究開発法人物質・材料研究機構, 技術開発・共用部門, NIMS特別研究員 (30354319)
阿部 聡  金沢大学, 数物科学系, 教授 (60251914)
Project Period (FY) 2017-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥16,770,000 (Direct Cost: ¥12,900,000、Indirect Cost: ¥3,870,000)
Fiscal Year 2020: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2019: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2018: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2017: ¥12,090,000 (Direct Cost: ¥9,300,000、Indirect Cost: ¥2,790,000)
Keywords水素エネルギー / 磁性 / 熱機関 / 冷凍機 / 水素 / エネルギー効率化 / 熱工学
Outline of Final Research Achievements

Magnetic refrigerator for hydrogen liquefaction was developed with active magnetic regenerator cycle that is expected to improve thermal efficiency compare with gas expansion. Reciprocating AMR bed could produce large temperature span around hydrogen liquefaction temperature and liquefaction was confirmed using liquid hydrogen level meter for the first time. In order to develop magnetic material for practical use, we studied rare-earth intermettalic compounds. Magnetocarolic effect, thermal conductivity and other properties were measured and evaluated as magnetic refrigerants. Magnetic refrigeration cycles were analyzed with new developed simulation code which takes void gas, thermal conductivity loss and so on.

Academic Significance and Societal Importance of the Research Achievements

脱炭素社会のエネルギー源として期待される水素エネルギーの貯蔵、輸送に有利な液体水素を製造する高効率の方式である磁気冷凍法による液化が実証された。特に本研究により、蓄冷型磁気冷凍サイクルによる水素液化に世界で初め成功した。さらに磁性体駆動方式という実用に近い形を用いて実現する大きな成果が得られた。今後、日本が水素エネルギー利用で世界をリードする新しい技術の端緒を開いたという意義がある。

Report

(5 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (25 results)

All 2021 2020 2019 2018 2017 Other

All Int'l Joint Research (3 results) Journal Article (9 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 9 results,  Open Access: 6 results) Presentation (12 results) (of which Int'l Joint Research: 7 results,  Invited: 3 results) Remarks (1 results)

  • [Int'l Joint Research] カザン連邦大学(ロシア連邦)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] カザン連邦大学(ロシア連邦)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] カザン連邦大学(ロシア連邦)

    • Related Report
      2017 Annual Research Report
  • [Journal Article] Thermal expansion and thermal conductivity of RT2 (R:Gd,Dy,Er; T:Al,Ni) intermetallic compounds for magnetic refrigerator2021

    • Author(s)
      WATANABE Shota, KOMATSU Shunsuke, FUTATSUKA Kazumi, KUMAZAWA Naoya, MATSUMOTO Koichi (Kanazawa U.); KAMIYA Koji, OYOSHI Keiji, TAKEYA Hiroyuki, NUMAZAWA Takenori (NIMS)
    • Journal Title

      Journal of Physics: Conference Series

      Volume: 1857 Issue: 1 Pages: 012003-012003

    • DOI

      10.1088/1742-6596/1857/1/012003

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Improvement of 4 K cooling power by coaxial pipe regenerator for a Gifford-McMahon cryocooler2021

    • Author(s)
      MASUYAMA Shinji (NIT, Oshima College); MATSUMOTO Koichi (Kanazawa Univ.); NUMAZAWA Takenori (NIMS)
    • Journal Title

      Journal of Physics: Conference Series

      Volume: 1857 Issue: 1 Pages: 012007-012007

    • DOI

      10.1088/1742-6596/1857/1/012007

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Thermal expansion and thermal conductivity of RT2 (R: Gd, Dy, Er; T: Al, Ni) intermetallic compounds for magnetic refrigerator2020

    • Author(s)
      Shota Watanabe, Shunsuke Komatsu, Kazumi Futatsuka, Naoya Kumazawa, Koichi Matsumoto, Koji Kamiya, Keiji Oyoshi, Hiroyuki Takeya and Takenori Numazawa
    • Journal Title

      journal of Physics: Conference Series

      Volume: -

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Magnetocaloric effect in single crystal GdTiO32019

    • Author(s)
      Hideki Omote, Shota Watanabe, Koichi Matsumoto, Ildar Gilmutdinov, Airat Kiiamov, Dmitrii Tayurskii
    • Journal Title

      Cryogenics

      Volume: 101 Pages: 58-62

    • DOI

      10.1016/j.cryogenics.2019.05.008

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Thermal expansion and magnetostriction of clathrate compound Pr3Pd20Ge62018

    • Author(s)
      Matsumoto K、Sekiguchi Y、Iwakami O、Ono T、Abe S、Ano G、Akatsu M、Mitsumoto K、Nemoto Y、Goto T、Takeda N、Kitazawa H
    • Journal Title

      Journal of Physics: Conference Series

      Volume: 969 Pages: 012120-012120

    • DOI

      10.1088/1742-6596/969/1/012120

    • Related Report
      2018 Annual Research Report 2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Superfluidity of 4He in dense aerogel studied using quartz tuning fork2018

    • Author(s)
      K Matsumoto, R Okamoto, A Nakajima, S Abe
    • Journal Title

      Journal of Physics: Conference Series

      Volume: 969 Pages: 012019-012019

    • DOI

      10.1088/1742-6596/969/1/012019

    • Related Report
      2018 Annual Research Report 2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Non-Fermi-Liquid Behavior in CeRu2Si2 at Ultralow Temperatures Studied by Thermal Expansion and Magnetostriction2017

    • Author(s)
      Daiki Inoue, Hiroyuki Takama, Daisuke Kaidou, Mitsuyuki Minegishi, Keisuke Ueno, Koichi Matsumoto, Satoshi Abe, Shigeyuki Murayama
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 86 Issue: 12 Pages: 124712-124712

    • DOI

      10.7566/jpsj.86.124712

    • NAID

      210000134634

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thermal and magnetic properties of regenerator material Gd2O2S2017

    • Author(s)
      K Matsumoto, T Numazawa, Y Ura, T Ujiyama and S Abe
    • Journal Title

      Journal of Physics: Conference Series

      Volume: 897 Pages: 012010-012010

    • DOI

      10.1088/1742-6596/897/1/012010

    • NAID

      120006375097

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Magnetocaloric effect, thermal conductivity, and magnetostriction of epoxy-bonded La(Fe0.88Si0.12) 13 hydrides2017

    • Author(s)
      K Matsumoto, D Murayama, M Takeshita, Y Ura, S Abe, T Numazawa, H Takata, Y Matsumoto and T Kuriiwa
    • Journal Title

      Journal of Physics: Conference Series 897 (2017) 012011

      Volume: 897 Pages: 012011-012011

    • DOI

      10.1088/1742-6596/897/1/012011

    • NAID

      120006375096

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Presentation] Development of active magnetic regenerator refrigerator (AMRR) with reciprocating AMR bed2020

    • Author(s)
      MATSUMOTO Koichi, WATANABE Shota, KOMATSU Shunsuke, KUMAZAWA Naoya, FUTATSUKA Kazumi (Kanazawa U.); KAMIYA Koiji, NUMAZAWA Takenori (NIMS)
    • Organizer
      10th ACASC/2nd Asian-ICMC/CSSJ Joint Conference
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Improvement of 4 K cooling power by coaxial pipe regenerator for a Gifford-McMahon cryocooler2020

    • Author(s)
      MASUYAMA Shinji (NIT, Oshima College); MATSUMOTO Koichi (Kanazawa Univ.); NUMAZAWA Takenori (NIMS)
    • Organizer
      10th ACASC/2nd Asian-ICMC/CSSJ Joint Conference
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Thermal expansion and thermal conductivity of RT2 (R:Gd,Dy,Er; T:Al,Ni) intermetallic compounds for magnetic refrigerator2020

    • Author(s)
      WATANABE Shota, KOMATSU Shunsuke, FUTATSUKA Kazumi, KUMAZAWA Naoya, MATSUMOTO Koichi (Kanazawa U.); KAMIYA Koji, OYOSHI Keiji, TAKEYA Hiroyuki, NUMAZAWA Takenori (NIMS)
    • Organizer
      10th ACASC/2nd Asian-ICMC/CSSJ Joint Conference
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 磁性蓄冷材HoCu2の磁場中比熱、磁化2018

    • Author(s)
      渡辺 祥太, 表 秀樹, 松本 宏一 (金沢大); 平山 貴士, 李 瑞 (住重)
    • Organizer
      2018年度秋季低温工学・超電導学会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 磁場中における小型4K冷凍機の冷凍性能の研究2018

    • Author(s)
      平山 貴士, 森江 孝明, 白石 太祐, 許 名堯 (住重); 松本 宏一 (金沢大)
    • Organizer
      2018年度秋季低温工学・超電導学会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 高出力4K-GM冷凍機開発への試み2018

    • Author(s)
      増山 新二 (大島商船高専); 松本 宏一 (金沢大); 沼澤 健則 (NIMS)
    • Organizer
      2018年度秋季低温工学・超電導学会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Magnetic Refrigerator for Hydrogen Liquefaction2018

    • Author(s)
      Koichi Matsumoto
    • Organizer
      Muroran-IT Rare Earth Workshop 2018 (国際学会)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Magnetocaloric Materials with Rare-Earth Element for Magnetic Refrigeration at Cryogenic Temperatures2017

    • Author(s)
      Koichi Matsumoto
    • Organizer
      Muroran-IT Workshop 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Thermal expansion and magnetostriction of clathrate compound Pr3Pd20Ge62017

    • Author(s)
      K Matsumoto, Y Sekiguchi, O Iwakami, T Ono, S Abe, G Ano, M Akatsu, K Mitsumoto, Y Nemoto, T Goto, N Takeda, and H Kitazawa
    • Organizer
      28th international conference on low temperature physics
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Superfluidity of 4He in dense aerogel studied using quartz tuning fork2017

    • Author(s)
      K Matsumoto, R Okamoto, A Nakajima, S Abe
    • Organizer
      28th international conference on low temperature physics
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 磁気熱量効果における磁性体の形状・反磁場効果の研究2017

    • Author(s)
      松本 宏一, 裏 雄太郎, 宇治山 崇, 表 秀樹, 木嵜 剛志, 野村 隆次郎
    • Organizer
      2017年度春季低温工学・超電導学会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 水素液化磁気冷凍用磁性体GdTiO3単結晶の磁気熱量効果2017

    • Author(s)
      表 秀樹, 宇治山 崇, 松本 宏一, GILMUTDINOV I.F., KIIAMOV A.G., TAYURSKII D.A.
    • Organizer
      2017年度秋季低温工学・超電導学会
    • Related Report
      2017 Annual Research Report
  • [Remarks]

    • URL

      http://www.s.kanazawa-u.ac.jp/phys/physics_MC/ult_html/index.html

    • Related Report
      2017 Annual Research Report

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Published: 2017-04-28   Modified: 2022-07-19  

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