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Conversion of lignin into functional materials by using poly-ion complex procedure

Research Project

Project/Area Number 17H03842
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Wood science
Research InstitutionNagoya University

Principal Investigator

Matsushita Yasuyuki  名古屋大学, 生命農学研究科, 准教授 (60335015)

Co-Investigator(Kenkyū-buntansha) 福島 和彦  名古屋大学, 生命農学研究科, 教授 (80222256)
青木 弾  名古屋大学, 生命農学研究科, 講師 (80595702)
Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥15,860,000 (Direct Cost: ¥12,200,000、Indirect Cost: ¥3,660,000)
Fiscal Year 2019: ¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2018: ¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2017: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Keywordsリグニン / 機能性物質 / 成長促進剤 / イネ / ニンニク / 根 / 成長促進 / 水熱処理 / カチオン性ポリマー / アニオン性ポリマー / バイオマス / 農林水産物
Outline of Final Research Achievements

Cationic and anionic groups were introduced into lignin and their conversion into functional materials was attempted. Acid-hydrolyzed lignin (SAL) was selected as the least reactive lignin, as it seems to be the most reactive. It was found that the SALs were soluble in water when subjected to alkaline hydrothermal treatment, and the chemical structure of the SALs was analyzed, and it was found that phenolic hydroxyl groups and carboxyl groups were introduced.
The water-soluble HSL was cationized, and it could be applied to the flocculation treatment of the dye waste solution. The carboxyl group was introduced into the water-soluble HSL and the product was applicable to the dispersant of gypsum.
The bioactivity of water-solubilized HSAL was investigated, and it was confirmed that it promoted the growth of plant roots.

Academic Significance and Societal Importance of the Research Achievements

大気中の二酸化炭素増加が明らかとなり、化石資源依存の脱却および再生可能資源への転換が早急の課題となっている。再生可能資源の中でも特に木質バイオマスは豊富な賦存量を誇り、かつ、食料と競合しないことから、その有効活用技術の開発は最優先課題だといえる。本研究では、これまで有効活用されていなかったリグニンに着目し、見事、カチオン性吸着凝集剤、石こう分散剤、植物成長促進剤に変換することができ、石油由来でなくバイオマスから創製できたことは社会的に非常にインパクトがある。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (9 results)

All 2019 2018 2017

All Journal Article (2 results) (of which Peer Reviewed: 2 results,  Open Access: 2 results) Presentation (6 results) (of which Int'l Joint Research: 3 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Industrial utilizations of water-soluble sulfuric acid lignin prepared by hydrothermal treatment as flocculant and dispersant2019

    • Author(s)
      Liu Qiang、Matsushita Yasuyuki、Aoki Dan、Fukushima Kazuhiko
    • Journal Title

      Journal of Wood Science

      Volume: 65 Issue: 1 Pages: 18-18

    • DOI

      10.1186/s10086-019-1797-1

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Effects of hydrothermal reaction of sulfuric acid lignin from Cryptomeria japonica for industrial utilization2018

    • Author(s)
      Q. Liu, Y. Matsushita, D. Aoki, S. Yagami, K. Fukushima
    • Journal Title

      BioResources

      Volume: 13 Pages: 7805-7823

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Presentation] Conversion of byproduct lignin generated during bioethanol generation from woody biomass into plant growth promotor2019

    • Author(s)
      Q. Liu, T. Kawai, Y. Matsushita, Y. Inukai, D.Aoki, K. Fukushima
    • Organizer
      1st International Lignin Symposium
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Industrial utilization of water-soluble sulfuric acid lignin prepared by hydrothermal treatment as flocculant and dispersant2019

    • Author(s)
      Qiang Liu,Yasuyuki Matsushita,Dan Aoki,Kazuhiko Fukushima
    • Organizer
      第69回日本木材学会大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Characterization of water-soluble polymers from surfuric acid lignin by hydrothermal treatment2018

    • Author(s)
      Qiang Liu, Yasuyuki Matsushita, Dan Aoki, Kazuhiko Fukushima
    • Organizer
      2018 Joint Convention Society of Wood Science and Technology (SWST) and The Japan Wood Research Society (JWRS)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Study on the characterization of water-soluble lignin from sulfuric acid lignin by hydrothermal treatment2018

    • Author(s)
      Qiang Liu, Yasuyuki Matsushita, Dan Aoki, Kazuhiko Fukushima
    • Organizer
      nternational Conference on Pulping, Papermaking and Biotechnology 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Effect of hydrothermal reaction on sulfuric acid lignin from Cryptomeria japonica2018

    • Author(s)
      Qiang Liu, Yasuyuki Matsushita, Dan Aoki, Kazuhiko Fukushima
    • Organizer
      第68回日本木材学会大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] リグニン由来新規カチオン性界面活性剤の創製2017

    • Author(s)
      梶原勝,青木弾,松下泰幸,福島和彦
    • Organizer
      2017年度木材学会中部支部大会
    • Related Report
      2017 Annual Research Report
  • [Patent(Industrial Property Rights)] 植物成長促進剤2019

    • Inventor(s)
      松下泰幸、劉強、福島和彦、青木弾、犬飼義明、河合翼
    • Industrial Property Rights Holder
      松下泰幸、劉強、福島和彦、青木弾、犬飼義明、河合翼
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2019-018404
    • Filing Date
      2019
    • Related Report
      2018 Annual Research Report

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Published: 2017-04-28   Modified: 2021-02-19  

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