| Budget Amount *help |
¥25,480,000 (Direct Cost: ¥19,600,000、Indirect Cost: ¥5,880,000)
Fiscal Year 2019: ¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2018: ¥7,150,000 (Direct Cost: ¥5,500,000、Indirect Cost: ¥1,650,000)
Fiscal Year 2017: ¥13,520,000 (Direct Cost: ¥10,400,000、Indirect Cost: ¥3,120,000)
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| Outline of Final Research Achievements |
In the present work, we attempted to develop (photo)electrocatalysts for selective oxidative upgrading of organics, which are composed of metal-modified covalent triazine frameworks (M-CTF). The specific achievements are as follows.
(1) A single Ru atom-modified covalent triazine framework (Ru-CTF) has selectivity for the electrooxidation of benzyl alcohol in water over the oxygen evolution reaction.
(2) The Cu-CTF/TiO2 hybrid photocatalytically reduced HNO2 without an external bias under artificial and natural sunlight. The dominant reaction product changes from N2O to NH4+ with an increase in the light intensity due to the shift of operating potentials.
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