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Co-evaporant induced crystallization and organic photovoltaic cells

Research Project

Project/Area Number 17H04807
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Applied materials
Research InstitutionTokyo University of Agriculture and Technology

Principal Investigator

Kaji Toshihiko  東京農工大学, 工学(系)研究科(研究院), 准教授 (90463794)

Project Period (FY) 2017-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2021)
Budget Amount *help
¥25,740,000 (Direct Cost: ¥19,800,000、Indirect Cost: ¥5,940,000)
Fiscal Year 2020: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2019: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2018: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2017: ¥14,560,000 (Direct Cost: ¥11,200,000、Indirect Cost: ¥3,360,000)
Keywords有機薄膜太陽電池 / 有機薄膜 / 薄膜成長 / 結晶成長 / 有機半導体エレクトロニクス / 太陽電池 / 有機半導体
Outline of Final Research Achievements

We have confirmed the phenomenon of obtaining higher current density and quantum yield than using standing waves at a film thickness of 500 nm or more, which is thicker than the optimum value for polymer systems, by crystallizing the photoelectric conversion layer of ZnPc:C60, a standard material bends for small molecule donor:acceptor systems, which was conventionally considered disadvantageous for thicker films than 100 nm. The main purpose of this study was to apply this phenomenon to various material systems, and to demonstrate it even for materials that exhibit higher photoelectric conversion efficiency.
As a result, although higher current densities could not be obtained, similar trends were confirmed for many donor materials. In addition, we were able to select new small molecule-based acceptor materials for future application of this technique.

Academic Significance and Societal Importance of the Research Achievements

本研究の開始時の背景としては、有機薄膜太陽電池の研究開発において、低分子真空蒸着系と高分子塗布系で報告されていた光電変換効率の最高値は同程度であった。その後、高分子塗布系においては、非フラーレンアクセプターの新規合成により急激に光電変換効率の向上が報告されている。本研究成果においては、低分子真空蒸着系の有機薄膜太陽電池において、光電変換効率の向上こそは得られなかったものの、多くのドナー材料において厚膜化が可能であることや低分子真空蒸着系に用いることのできるアクセプター材料を見出したことは、今後、低分子真空蒸着系においても高分子塗布系と同様の光電変換効率の向上を見込めることを示唆している。

Report

(5 results)
  • 2021 Final Research Report ( PDF )
  • 2020 Annual Research Report
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (34 results)

All 2022 2021 2020 2019 2018 2017 Other

All Journal Article (2 results) (of which Peer Reviewed: 2 results,  Open Access: 1 results) Presentation (28 results) (of which Int'l Joint Research: 11 results,  Invited: 6 results) Book (2 results) Remarks (1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Ultra-Thick Organic Pigment Layer Up to 10 μm Activated by Crystallization in Organic Photovoltaic Cells2020

    • Author(s)
      Katayama Mikimasa、Kaji Toshihiko、Nakao Satoru、Hiramoto Masahiro
    • Journal Title

      Frontiers in Energy Research

      Volume: 8

    • DOI

      10.3389/fenrg.2020.00004

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Organic photovoltaic cell using near-infrared absorbing nickel complex2018

    • Author(s)
      Enokido Fuka、Katayama Mikimasa、Kaji Toshihiko
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 57 Issue: 3S2 Pages: 03EJ05-03EJ05

    • DOI

      10.7567/jjap.57.03ej05

    • NAID

      210000148785

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Presentation] 低濃度型有機薄膜太陽電池の開放端電圧の結晶化による変化2022

    • Author(s)
      嘉治寿彦,森承宇,余語正輝,榎戸風花
    • Organizer
      電子情報通信学会有機エレクトロニクス研究会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 共蒸発分子誘起結晶化法で作製したペンタセン:フラーレン混合層の励起子分裂2021

    • Author(s)
      嘉治寿彦, 関直人,島崎七海
    • Organizer
      電子情報通信学会有機エレクトロニクス研究会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Co-evaporant induced crystallization in vacuum for growth and crystallinity control of organic thin film devices2021

    • Author(s)
      Toshihiko Kaji
    • Organizer
      ICFPE2021
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 両極性受光素子材料の探索2021

    • Author(s)
      辻亮汰, 嘉治寿彦
    • Organizer
      電子情報通信学会2021年ソサエティ大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Suppression of Grain Density by the Introduction of liquids during Vacuum Deposition of C60 Thin Films2021

    • Author(s)
      Michihiro Nakayama, Tetsu Katayama, and Toshihiko Kaji
    • Organizer
      KJF-ICOMEP2021
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 有機半導体を結晶化する新奇薄膜成長法と太陽電池応用2021

    • Author(s)
      嘉治寿彦
    • Organizer
      兵庫県立大学「フォトンサイエンスセミナー」
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] 結晶化した低分子型有機薄膜太陽電池の暗電流のダイオード解析2021

    • Author(s)
      嘉治寿彦,榎戸風花,森承宇,余語正輝,阿部優樹,片山美樹雅
    • Organizer
      電子情報通信学会有機エレクトロニクス研究会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Exploration of Lead-Free Organic Inorganic Halide Material for Photovoltaic Applications2020

    • Author(s)
      Shotaroh Nakamura, Toshihiko Kaji
    • Organizer
      ISOME2020
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research
  • [Presentation] CsSnI3 ペロブスカイトの酸化における混合物の影響2020

    • Author(s)
      嘉治寿彦, 角田智亮, 林和輝, 中村翔大郎, 石橋浩伸
    • Organizer
      電子情報通信学会2020年ソサエティ大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Variations of the crystal grain density by liquid-introduction during vacuum deposition of thin films2019

    • Author(s)
      Tetsu Katayama, Toshihiko Kaji
    • Organizer
      M&BE10
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Relationships between thin film growth and incident angle on substrate surface2019

    • Author(s)
      Tsukasa Komagome, Toshihiko Kaji
    • Organizer
      M&BE10
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Co-evaporant induced crystallization for extremely thick vacuum-deposited organic photovoltaic cells2018

    • Author(s)
      Toshihiko Kaji
    • Organizer
      ThinFilms2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Fullerene separation by sublimation and its influence on the performance of organic photovoltaic cells2018

    • Author(s)
      Yuki Abe, Mikimasa Katayama, Toshihiko KAJI
    • Organizer
      SSDM2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 低ドナー濃度有機薄膜太陽電池における高電圧化の決定要因2018

    • Author(s)
      榎戸風花, 余語正輝, 片山美樹雅, 嘉治寿彦
    • Organizer
      第79回応用物理学会秋季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 共蒸発分子誘起結晶化法によるフラーレン薄膜の結晶粒密度の変化2018

    • Author(s)
      片山哲, 嘉治寿彦
    • Organizer
      第79回応用物理学会秋季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 有機薄膜太陽電池の結晶化と太陽電池特性への影響2018

    • Author(s)
      嘉治寿彦
    • Organizer
      平成30年電気学会 電子・情報・システム部門大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] キナクリドンを用いた緑色光吸収有機薄膜太陽電池2018

    • Author(s)
      牛久結貴,嘉治寿彦
    • Organizer
      電気学会電子材料研究会「フレキシブル電子材料とデバイス作製技術」
    • Related Report
      2018 Annual Research Report
  • [Presentation] フラーレン薄膜真空蒸着中の液体導入による結晶粒密度の変化2018

    • Author(s)
      片山 哲,嘉治寿彦
    • Organizer
      電気学会電子材料研究会「フレキシブル電子材料とデバイス作製技術」
    • Related Report
      2018 Annual Research Report
  • [Presentation] 真空蒸着中の液体導入による 結晶化と有機系太陽電池 への応用2018

    • Author(s)
      嘉治寿彦
    • Organizer
      電子情報通信学会2018年電子情報通信学会総合大会チュートリアル「近未来の電子情報社会を支える次世代蓄電・発電デバイスの新展開」
    • Related Report
      2017 Annual Research Report
  • [Presentation] 真空蒸着中の液体導入による薄膜成長制御と混合膜の結晶化2017

    • Author(s)
      嘉治寿彦
    • Organizer
      応用物理学会 有機分子・バイオエレクトロニクス分科会講習会「ドライとウェットを繋ぐ薄膜成長・デバイス作製プロセス技術」~有機ELから太陽電池まで~
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 10µmを越える膜厚の有機薄膜太陽電池2017

    • Author(s)
      嘉治寿彦
    • Organizer
      第8回 有機分子・バイオエレクトロニクスの未来を拓く若手研究者討論会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 有機太陽電池材料とその真空蒸着時の液体導入による結晶化2017

    • Author(s)
      嘉治寿彦
    • Organizer
      電子情報通信学会レーザ・量子エレクトロニクス研究会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] μM-THICK VACUUM DEPOSITED PHTHALOCYANINE:C60 PHOTOVOLTAIC CELLS UTILIZING CO-EVAPORANT INDUCED CRYSTALLIZATION2017

    • Author(s)
      Toshihiko Kaji
    • Organizer
      PVSEC27
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] The research on the principle of high VOC in Schottky type organic photovoltaic cells with low concentrated donors2017

    • Author(s)
      Fuka Enokido, Masateru Yogo, Mikimasa Katayama, Toshihiko Kaji
    • Organizer
      SSDM 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Organic photovoltaic cells with active layer thickness beyond optical optimizations up to 10 μm2017

    • Author(s)
      Toshihiko Kaji, Mikimasa Katayama, Satoru Nakao, Ching W. Tang, and Masahiro Hiramoto
    • Organizer
      13th International Symposium on Functional π-Electron Systems
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Organic photovoltaic cell using near-infrared absorbing nickel complex2017

    • Author(s)
      Fuka Enokido, Mikimasa Katayama, and Toshihiko Kaji
    • Organizer
      9th International Conference on Molecular Electronics and Bioelectronics
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 低濃度混合ショットキー接合型有機薄膜太陽電池への共蒸発分子導入2017

    • Author(s)
      余語政輝,榎戸風花,片山美樹雅,嘉治寿彦
    • Organizer
      電子情報通信学会有機エレクトロニクス研究会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ピグメントグリーンを用いた有機薄膜太陽電池の検討2017

    • Author(s)
      嘉治寿彦,片山美樹雅
    • Organizer
      有機エレクトロニクス・バイオエレクトロニクスに関する見学会および研究討論会
    • Related Report
      2017 Annual Research Report
  • [Book] 「OPV with a crystalline organic pigment active layer up to 10 μm」『Organic solar cells』Chapter 42020

    • Author(s)
      Toshihiko Kaji
    • Total Pages
      13
    • Publisher
      Springer Nature
    • Related Report
      2020 Annual Research Report
  • [Book] 「10 μm 超の有機顔料半導体層でも動作する結晶化有機薄膜太陽電池」『機能材料』7月号2020

    • Author(s)
      嘉治寿彦
    • Total Pages
      8
    • Publisher
      (株)シーエムシー出版
    • Related Report
      2020 Annual Research Report
  • [Remarks] 嘉治寿彦准教授がPVSEC-27「Young Researcher Paper Award」を受賞

    • URL

      https://www.tuat.ac.jp/NEWS/winning/20171222_01.html

    • Related Report
      2017 Annual Research Report
  • [Patent(Industrial Property Rights)] 光電変換膜及び光電変換素子2019

    • Inventor(s)
      嘉治寿彦,牛久結貴
    • Industrial Property Rights Holder
      国立大学法人東京農工大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2019-032045
    • Filing Date
      2019
    • Related Report
      2018 Annual Research Report

URL: 

Published: 2017-04-28   Modified: 2023-01-30  

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