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Controllingmagnetism in 3d transition metal oxides through spin-orbit interactions

Research Project

Project/Area Number 17H04813
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Thin film/Surface and interfacial physical properties
Research InstitutionKyoto University

Principal Investigator

Kan Daisuke  京都大学, 化学研究所, 准教授 (40378881)

Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥26,000,000 (Direct Cost: ¥20,000,000、Indirect Cost: ¥6,000,000)
Fiscal Year 2019: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2018: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2017: ¥19,500,000 (Direct Cost: ¥15,000,000、Indirect Cost: ¥4,500,000)
Keywords遷移金属酸化物 / スピン軌道相互作用 / 磁気異方性 / ヘテロ構造 / 遷移金属-酸素結合 / エピタキシャル薄膜 / 酸化物ヘテロ構造 / 異常ホール効果 / 磁性 / 原子レベル構造制御 / ストレイン / 格子歪み / 磁気輸送特性
Outline of Final Research Achievements

In this research project, we explored functional properties originating from spin-orbit interactions in oxide heterostructures. We find that magnetic anisotropy in transition metal oxides can be controlled by heterostructuring them and modulating their metal-oxygen bonds. Imposing compressive strain through the structural mismatch is found to be useful to stabilize the perpendicular magnetic anisotropy in oxides. In addition, we successfully fabricated the inverse spinel oxide NiCo2O4 that has both half-metallic band structure and sufficient perpendicular magnetic anisotropy, although these two properties rarely coexist. We also clarified the physical origin of anomalies in transverse resistivity, which resemble what has been claimed to be the topological Hall effect in oxide heterostructures,

Academic Significance and Societal Importance of the Research Achievements

遷移金属酸化物は、古くから磁性材料として、研究・開発されてきた。今回スピン軌道相互作用に関連した磁気特性である磁気異方性の制御などについて新たな知見が得られた。今後の材料開発の新たな指針となると期待できる。例えばハーフメタルなど、これまで磁気異方性の制御が困難と考えられていた材料に垂直磁気異方性を付与することで新機能創出につながる。またスピン軌道相互作用に着目することで、酸化物ヘテロ構造におけるトポロジカルホール効果など新奇現象の発見も期待できる。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (46 results)

All 2020 2019 2018 2017

All Journal Article (15 results) (of which Peer Reviewed: 15 results) Presentation (31 results) (of which Int'l Joint Research: 17 results,  Invited: 12 results)

  • [Journal Article] Field-sweep-rate and time dependence of transverse resistivity anomalies in ultrathin SrRuO3 films2020

    • Author(s)
      Kan Daisuke、Moriyama Takahiro、Shimakawa Yuichi
    • Journal Title

      Physical Review B

      Volume: 101 Issue: 1

    • DOI

      10.1103/physrevb.101.014448

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Tuning of ferrimagnetism and perpendicular magnetic anisotropy in NiCo2O4 epitaxial films by the cation distribution2020

    • Author(s)
      Shen Yufan、Kan Daisuke、Tan Zhenhong、Wakabayashi Yusuke、Shimakawa Yuichi
    • Journal Title

      Physical Review B

      Volume: 101 Issue: 9

    • DOI

      10.1103/physrevb.101.094412

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electric field induced modulation of transverse resistivity anomalies in ultrathin SrRuO3 epitaxial films2020

    • Author(s)
      Kan Daisuke、Kobayashi Kento、Shimakawa Yuichi
    • Journal Title

      Physical Review B

      Volume: 101 Issue: 14

    • DOI

      10.1103/physrevb.101.144405

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Correlations between oxygen octahedral distortions and magnetic and transport properties in strained La0.5Sr0.5CoO3 thin films2019

    • Author(s)
      Heo Yooun、Kan Daisuke、Anada Masato、Wakabayashi Yusuke、Tajiri Hiroo、Shimakawa Yuichi
    • Journal Title

      Physical Review B

      Volume: 99 Issue: 17

    • DOI

      10.1103/physrevb.99.174420

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Orbital Magnetic Moments in Strained SrRuO3 Thin Films2019

    • Author(s)
      Kobayashi Kento、Kan Daisuke、Matsumoto Sho、Mizumaki Masaichiro、Shimakawa Yuichi
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 88 Issue: 8 Pages: 084708-084708

    • DOI

      10.7566/jpsj.88.084708

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Strain effect on thermoelectric properties of SrRuO3 epitaxial thin films2019

    • Author(s)
      Kan Daisuke、Shimakawa Yuichi
    • Journal Title

      Applied Physics Letters

      Volume: 115 Issue: 2 Pages: 022403-022403

    • DOI

      10.1063/1.5097927

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Selective growth of α-Fe2O3, γ-Fe2O3 and Fe3O4 at low temperatures and under ambient pressure2019

    • Author(s)
      Kan Daisuke、Sugano Satoshi、Kosugi Yoshihisa、Kobayashi Kento、Uebayashi Nao、Koganezawa Tomoyuki、Shimakawa Yuichi
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 58 Issue: 9 Pages: 095504-095504

    • DOI

      10.7567/1347-4065/ab39d1

    • NAID

      210000156927

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Oxygen octahedral distortions in compressively strained SrRuO3 epitaxial thin films2018

    • Author(s)
      Kan Daisuke、Anada Masato、Wakabayashi Yusuke、Tajiri Hiroo、Shimakawa Yuichi
    • Journal Title

      Journal of Applied Physics

      Volume: 123 Issue: 23 Pages: 235303-235303

    • DOI

      10.1063/1.5036748

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Defect-Induced Anomalous Transverse Resistivity in an Itinerant Ferromagnetic Oxide2018

    • Author(s)
      Kan Daisuke、Shimakawa Yuichi
    • Journal Title

      physica status solidi (b)

      Volume: 255 Issue: 9 Pages: 1800175-1800175

    • DOI

      10.1002/pssb.201800175

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Growth-temperature-dependent coalescence determines structural phase of mist-chemical-vapor-deposition-grown SnO2 thin films2018

    • Author(s)
      D. Kan, Y. Niwa, T. Koganezawa, and Y. Shimakawa
    • Journal Title

      J. Appl. Phys.

      Volume: 124 Issue: 12 Pages: 125303-125303

    • DOI

      10.1063/1.5045327

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nanoscale oxygen ion dynamics in SrFeO3-d epitaxial thin films2018

    • Author(s)
      Y. Heo, D. Kan, and Y. Shimakawa
    • Journal Title

      Appl. Phys. Lett.

      Volume: 113 Issue: 22 Pages: 221904-221904

    • DOI

      10.1063/1.5046749

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Alternative to the topological interpretation of the transverse resistivity anomalies in SrRuO32018

    • Author(s)
      Kan Daisuke、Moriyama Takahiro、Kobayashi Kento、Shimakawa Yuichi
    • Journal Title

      Physical Review B

      Volume: 98 Issue: 18 Pages: 180408-180408

    • DOI

      10.1103/physrevb.98.180408

    • NAID

      130008146098

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Influence of cation off-stoichiometry on structural and transport properties of (Ba,La)SnO3 epitaxial thin films grown by pulsed laser deposition2017

    • Author(s)
      Y. Ozaki, D. Kan, and Y. Shimakawa
    • Journal Title

      J. Appl. Phys.

      Volume: 121 Issue: 21 Pages: 215304-215304

    • DOI

      10.1063/1.4984317

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Melting of oxygen vacancy order at oxide-heterostructure interface2017

    • Author(s)
      K. Hirai, R. Aso, Y. Ozaki, D. Kan, M. Haruta, N. Ichikawa, H. Kurata, and Y. Shimakawa
    • Journal Title

      ACS Appl. Mater. Interfaces

      Volume: 9 Issue: 35 Pages: 30143-30148

    • DOI

      10.1021/acsami.7b08134

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electric field induced modulations of Anomalous Hall effect in a heterostructured itinerant ferromagnet SrRuO32017

    • Author(s)
      H. Mizuno, K. T. Yamada, D. Kan, T. Moriyama, Y. Shimakawa, and T. Ono
    • Journal Title

      Physical Review B

      Volume: 96 Issue: 21 Pages: 214422-214422

    • DOI

      10.1103/physrevb.96.214422

    • NAID

      130007511162

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Presentation] 垂直磁化を有するNiCo2O4薄膜におけるカチオン価数状態と軌道磁気モーメント2020

    • Author(s)
      菅 大介、水牧 仁一朗、北村 未歩、小谷 佳範、瀋 昱帆、鈴木 郁美、堀場 弘司、島川 祐一
    • Organizer
      第67回 応用物理学会春季学術講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] NiCo2O4薄膜中の酸素欠損が磁気特性に与える影響2020

    • Author(s)
      鈴木 郁美、菅 大介、瀋 昱帆、島川 祐一
    • Organizer
      第67回 応用物理学会春季学術講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Cation-distribution-tuned ferrimagnetism and perpendicular magnetic anisotropy in NiCo2O4 epitaxial films2020

    • Author(s)
      Y. Shen, T. Zhenhong, D. Kan, and Y. Shimakawa
    • Organizer
      IRCCS The 3rd Joint International Symposium
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 酸化鉄エピタキシャル薄膜の低温合成と構造・価数制御2019

    • Author(s)
      菅 大介、菅野 聡、小杉 佳久、小林 顕斗、上林 奈央、島川 祐一
    • Organizer
      第4回固体化学フォーラム研究会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 酸化鉄エピタキシャル薄膜の低温合成と構造・価数制御2019

    • Author(s)
      菅 大介、菅野 聡、小杉 佳久、小林 顕斗、上林 奈央、小金澤 智之、島川 祐一
    • Organizer
      第80回応用物理学会秋季学術講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Manipulating Cation Arrangements and Perpendicular Magnetization Anisotropy in the spinel oxide NiCo2O42019

    • Author(s)
      瀋 昱帆、菅 大介、若林 裕介、島川 祐一
    • Organizer
      第80回応用物理学会秋季学術講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Dynamics of Oxygen Ions in SrFeO2.5+d Thin Films2019

    • Author(s)
      Y. Heo, D. Kan, Y. Shimakawa
    • Organizer
      IRCCS The 2nd International Symposium
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Influence of growth conditions on structural and magnetic properties of the ferrimagnetic spinel NiCo2O42019

    • Author(s)
      Y. Shen, D Kan, Z. Tan, Y. Shimakawa
    • Organizer
      26th International Workshop on Oxide Electronics
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Strain effect on thermoelectric properties of SrRuO3 epitaxial thin films2019

    • Author(s)
      D. Kan Y. Shimakawa
    • Organizer
      26th International Workshop on Oxide Electronics
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Transverse resistivity anomalies in the ferromagnetic oxide SrRuO3 and their interpretation: Topological or Traditional?2019

    • Author(s)
      D. Kan
    • Organizer
      64th Annual Conference on Magnetism and Magnetic Materials (MMM)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Anomalous magnetotransport behavior in a ferromagnetic perovskite oxide with interfacially engineered metal-oxygen bonds2019

    • Author(s)
      D. Kan
    • Organizer
      IUMRS-ICA
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 遍歴強磁性体SrRuO3のトポロジカルホール効果的振舞いの別解釈2019

    • Author(s)
      菅 大介、森山 貴広、小林 顕斗、島川 祐一
    • Organizer
      日本物理学会 第74回年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Nanoscale dynamics of oxygen ions in SrFeO2.5+d epitaxial thin films2019

    • Author(s)
      Y. Heo、D. Kan、Y. Shimakawa
    • Organizer
      第66回応用物理学会春季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 遍歴強磁性体SrRuO3薄膜のトポロジカルホール効果的振舞いの電界変調とその解釈2019

    • Author(s)
      小林 顕斗、菅 大介、島川 祐一
    • Organizer
      第66回応用物理学会春季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Anomalous magnetotransport behavior in an itinerant ferromagnetic oxide2018

    • Author(s)
      Daisuke Kan
    • Organizer
      7th International Symposium Transparent Conductive Materials and 4th E-MRS & MRS-J Bilateral Symposium
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Anomalous magnetotransport behavior in an itinerant ferromagnetic oxide with interfacially engineered metal-oxygen bonds2018

    • Author(s)
      Daisuke Kan
    • Organizer
      2018 Hsinchu Oxide Forum
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Nanoscale oxygen ion dynamics in SrFeO3-d epitaxial thin films2018

    • Author(s)
      Y. Heo, D. Kan, and Y. Shimakawa
    • Organizer
      E-MRS Fall meeting
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Oxidation Induced Electrical Conduction of SrFeO2.52018

    • Author(s)
      Y. Heo, D. Kan, and Y. Shimakawa
    • Organizer
      ISAF-FMA-AMF-AMEC-PFM Joint Conference
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 機械的変形を利用した遷移金属酸化物の物性制御2018

    • Author(s)
      松本 笙、菅 大介、島川 祐一
    • Organizer
      第79回応用物理学会秋季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 遍歴強磁性体SrRuO3薄膜の軌道磁気モーメントの温度依存性2018

    • Author(s)
      小林 顕斗、水牧 仁一朗、菅 大介、島川 祐一
    • Organizer
      第79回応用物理学会秋季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 原子レベル構造制御で発現する4d 遷移金属酸化物の新奇な磁気輸送特性2018

    • Author(s)
      菅大介
    • Organizer
      第3回固体化学フォーラム研究会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Interface Engineering of Transition Metal Oxides as a New Route for Exploring Functional Properties2018

    • Author(s)
      Daisuke Kan
    • Organizer
      International Congress on Pure & Applied Chemistry (ICPAC) 2018
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Interface engineering of transition metal oxide as a new route for exploring functional properties2018

    • Author(s)
      Daisuke Kan
    • Organizer
      Electronic Materials and Applications (EMA) 2018
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Atomic engineering of transition metal oxides as a new route for exploring their functional properties2017

    • Author(s)
      Daisuke Kan
    • Organizer
      The 3rd East-Asia Microscopy Conference
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Tuning magnetic anisotropy by interfacially engineering the oxygen coordination environment in a transition-metal oxide2017

    • Author(s)
      Daisuke Kan
    • Organizer
      International Workshop on Oxide Electronics (WOE24)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Functional properties emerged in atomically engineered transition metal oxides2017

    • Author(s)
      Daisuke Kan
    • Organizer
      Core-to-Core Workshop "Novel Quantum and Functional Materials -Design and Synthesis-"
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Interface engineering of metal-oxygen bonds as a new route for exploring functional properties of transition metal oxides2017

    • Author(s)
      Daisuke Kan
    • Organizer
      IUMRS-ICAM 2017 The 15th International Conference on Advanced Materials
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Interface engineering of metal-oxygen bonds as a new route for exploring functional properties of transition metal oxides2017

    • Author(s)
      Daisuke Kan
    • Organizer
      3rd Computational Chemistry (CC) Symposium of ICCMSE 2017,
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 原子レベル構造制御による遷移金属酸化物の機能開発2017

    • Author(s)
      菅 大介、島川 祐一
    • Organizer
      粉体粉末冶金協会 秋季大会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 界面制御された磁気異方性を有するSrRuO3薄膜の軌道磁気モーメント2017

    • Author(s)
      菅 大介、水牧 仁一朗、島川 祐一
    • Organizer
      第78回 応用物理学会秋季学術講演会,
    • Related Report
      2017 Annual Research Report
  • [Presentation] 圧縮ストレイン下におけるSrRuO3薄膜のホール抵抗の異常な振る舞い2017

    • Author(s)
      小林 顕斗、菅 大介、島川 祐一
    • Organizer
      第78回 応用物理学会秋季学術講演会
    • Related Report
      2017 Annual Research Report

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Published: 2017-04-28   Modified: 2021-02-19  

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