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From interstellar molecules to meteoritic organics: experimental studies on the pathways toward molecular complexities based on the degree of deuterium enrichment

Research Project

Project/Area Number 17H04862
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Geochemistry/Cosmochemistry
Research InstitutionHokkaido University

Principal Investigator

Oba Yasuhiro  北海道大学, 低温科学研究所, 准教授 (00507535)

Project Period (FY) 2017-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥24,830,000 (Direct Cost: ¥19,100,000、Indirect Cost: ¥5,730,000)
Fiscal Year 2020: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2019: ¥6,630,000 (Direct Cost: ¥5,100,000、Indirect Cost: ¥1,530,000)
Fiscal Year 2018: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2017: ¥9,620,000 (Direct Cost: ¥7,400,000、Indirect Cost: ¥2,220,000)
Keywords化学進化 / 星間分子雲 / 重水素濃集 / 隕石有機物 / ヘキサメチレンテトラミン / 光化学反応 / 熱水変質 / 隕石母天体 / 分子進化 / 熱変質 / 水素同位体分別 / 熱水反応 / 太陽系 / 同位体分別 / 星間分子
Outline of Final Research Achievements

In the present study, in order to better understand molecular evolution in space, variations in the hydrogen isotopic composition of hexamethylenetetramine (HMT) through molecular clouds (MCs) to the solar system were experimentally investigated. Critical parameters to constrain the hydrogen isotopic composition of the HMT formed in MCs were that of methanol used for HMT formation and the temperature where photochemical reactions took place. After the formation by photochemical reactions, the deuterium enrichment of HMT was diluted via hydrogen isotopic exchanges with water, resulting in the formation of less deuterium-enriched HMT. These results suggest that moderately deuterium-enriched signature observed in meteoritic organic compounds can be reproduced from highly deuterium-enriched interstellar molecules.

Academic Significance and Societal Importance of the Research Achievements

生命誕生前の宇宙空間には有機化合物を含む様々な分子が存在するが,それらがどのようなプロセスを経験するのか,全く理解されていない。本研究では,小惑星リュウグウの破片にもその存在が期待される有機化合物,ヘキサメチレンテトラミン(HMT)に着目し,宇宙環境(星間分子雲,太陽系)での化学反応でどのように変化するか,模擬実験を中心としてその詳細を調べた。HMTは星間分子雲での紫外線を利用した光化学反応で生成し,太陽系形成後の小天体上での熱水プロセスによって多様に変化した。また,種々の炭素質隕石からHMTが世界で初めて検出され,本研究で検証したプロセスが実際の宇宙環境でも起こっていることが強く示唆された。

Report

(5 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (39 results)

All 2021 2020 2019 2018 2017 Other

All Int'l Joint Research (8 results) Journal Article (12 results) (of which Int'l Joint Research: 8 results,  Peer Reviewed: 12 results,  Open Access: 11 results) Presentation (16 results) (of which Int'l Joint Research: 10 results,  Invited: 3 results) Remarks (3 results)

  • [Int'l Joint Research] NASA(米国)

    • Related Report
      2020 Annual Research Report
  • [Int'l Joint Research] Osservatorio Astrofisico di Arcetri(イタリア)

    • Related Report
      2020 Annual Research Report
  • [Int'l Joint Research] IPAG, Univ. Grenoble Alpes(フランス)

    • Related Report
      2020 Annual Research Report
  • [Int'l Joint Research] University College London(英国)

    • Related Report
      2020 Annual Research Report
  • [Int'l Joint Research] Centro de Astrobiologia (CSIC-INTA),(スペイン)

    • Related Report
      2020 Annual Research Report
  • [Int'l Joint Research]

    • Related Report
      2020 Annual Research Report
  • [Int'l Joint Research] シュツッツガルト大学(ドイツ)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] シュツッツガルト大学(ドイツ)

    • Related Report
      2017 Annual Research Report
  • [Journal Article] FAUST. II. Discovery of a Secondary Outflow in IRAS 15398-3359: Variability in Outflow Direction during the Earliest Stage of Star Formation?2021

    • Author(s)
      Okoda Yuki、Oya Yoko、Francis Logan、... Nomura Hideko ... et al. (69人中47番目)
    • Journal Title

      The Astrophysical Journal

      Volume: 910 Issue: 1 Pages: 11-11

    • DOI

      10.3847/1538-4357/abddb1

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Analytical development of seamless procedures on cation-exchange chromatography and ion-pair chromatography with high-precision mass spectrometry for short-chain peptides.2021

    • Author(s)
      Takano, Y., Oba, Y., Furota, S., Naraoka, H., Ogawa, N., Blattmann, T. M. and Ohkouchi, N.
    • Journal Title

      Inter. J. Mass Spectrom.

      Volume: 462 Pages: 116529-116529

    • DOI

      10.1016/j.ijms.2021.116529

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Precometary organic matter: A hidden reservoir of water inside the snow line2020

    • Author(s)
      Nakano Hideyuki、Hirakawa Naoki、Matsubara Yasuhiro、Yamashita Shigeru、Okuchi Takuo、Asahina Kenta、Tanaka Ryo、Suzuki Noriyuki、Naraoka Hiroshi、Takano Yoshinori、Tachibana Shogo、Hama Tetsuya、Oba Yasuhiro、Kimura Yuki、Watanabe Naoki、Kouchi Akira
    • Journal Title

      Scientific Reports

      Volume: 10 Issue: 1 Pages: 7755-7755

    • DOI

      10.1038/s41598-020-64815-6

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] An Experimental Study of Chemical Desorption for Phosphine in Interstellar Ice2020

    • Author(s)
      Nguyen T., Oba Y., Shimonishi T., Kouchi A., Watanabe N.
    • Journal Title

      The Astrophysical Journal Letters

      Volume: 898, Issue: 2 Pages: L52-L52

    • DOI

      10.3847/2041-8213/aba695

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Extraterrestrial hexamethylenetetramine in meteorites-a precursor of prebiotic chemistry in the inner solar system.2020

    • Author(s)
      Oba Y., Takano Y., Naraoka H., Furukawa Y., Glavin D. P., Dworkin J. P. and Tachibana S.
    • Journal Title

      Nature Communications

      Volume: 11 Issue: 1 Pages: 6243-6243

    • DOI

      10.1038/s41467-020-20038-x

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] UV-ray irradiation never causes amorphization of crystalline CO2: A transmission electron microscopy study2020

    • Author(s)
      Tsuge M., Nguyen T., Oba Y., Hama T., Kouchi A., Watanabe N.
    • Journal Title

      Chemical Physics Letters

      Volume: 760 Pages: 137999-137999

    • DOI

      10.1016/j.cplett.2020.137999

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] FAUST I. The hot corino at the heart of the prototypical Class I protostar L1551 IRS52020

    • Author(s)
      Bianchi E、Chandler C J、Ceccarelli C ... Nomura, H. ... et al. (66人中46番目)
    • Journal Title

      Monthly Notices of the Royal Astronomical Society: Letters

      Volume: 498 Issue: 1 Pages: L87-L92

    • DOI

      10.1093/mnrasl/slaa130

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Nucleobase synthesis in interstellar ices2019

    • Author(s)
      Y. Oba, Y. Takano, H. Naraoka, N. Watanabe and A. Kouchi
    • Journal Title

      Nature Communications

      Volume: 10 Issue: 1 Pages: 4413-4413

    • DOI

      10.1038/s41467-019-12404-1

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Physico-chemical Behavior of Hydrogen Sulfide Induced by Reactions with H and D Atoms on Different Types of Ice Surfaces at Low Temperature2019

    • Author(s)
      Y. Oba, T.Tomaru, A. Kouchi, N. Naoki
    • Journal Title

      The Astrophysical Journal

      Volume: 874 Issue: 2 Pages: 124-124

    • DOI

      10.3847/1538-4357/ab0961

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] An infrared measurement of chemical desorption from interstellar ice analogues2018

    • Author(s)
      Y. Oba, T. Tomaru, T. Lamberts, A. Kouchi, N. Watanabe
    • Journal Title

      Nature Astronomy

      Volume: 2 Issue: 3 Pages: 228-232

    • DOI

      10.1038/s41550-018-0380-9

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Deuterium Fractionation upon the Formation of Hexamethylenetetramines through Photochemical Reactions of Interstellar Ice Analogs Containing Deuterated Methanol Isotopologues2017

    • Author(s)
      Y. Oba, Y. Takano, H. Naraoka, A. Kouchi, N. Watanabe
    • Journal Title

      The Astrophysical Journal

      Volume: 849 Issue: 2 Pages: 122-122

    • DOI

      10.3847/1538-4357/aa8ea5

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Liquid-like behavior of UV-irradiated interstellar ice analog at low temperatures2017

    • Author(s)
      Tachibana Shogo、Kouchi Akira、Hama Tetsuya、Oba Yasuhiro、Piani Laurette、Sugawara Iyo、Endo Yukiko、Hidaka Hiroshi、Kimura Yuki、Murata Ken-ichiro、Yurimoto Hisayoshi、Watanabe Naoki
    • Journal Title

      Science Advances

      Volume: 3 Issue: 9

    • DOI

      10.1126/sciadv.aao2538

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Presentation] Laboratory studies on the hydrogen-deuterium substitution of hydrogen sulfide on ice surfaces at low temperatures2021

    • Author(s)
      Yasuhiro Oba, Takuto Tomaru, Naoki Watanabe, Akira Kouchi
    • Organizer
      COSPAR 2021
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Recent advances in analytical techniques for the identification of specific COMs in photochemically-processed interstellar ice analogs2021

    • Author(s)
      Yasuhiro Oba, Yoshinori Takano, Hiroshi Naraoka, Naoki Watanabe, Akira Kouchi
    • Organizer
      COSPAR 2021
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Synthesis of nitrogen heterocycles of astrobiological interest in interstellar ice analogs2019

    • Author(s)
      Yasuhiro Oba, Yoshinori Takano, Hiroshi Naraoka, Naoki Watanabe, Akira Kouchi
    • Organizer
      AbSciCon2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Detection of nucleobases and dipeptides in organic residues formed by photochemical reactions in interstellar ice analogs2019

    • Author(s)
      Yasuhiro Oba, Yoshinori Takano, Hiroshi Naraoka, Naoki Watanabe, Akira Kouchi
    • Organizer
      Goldschmidt2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 模擬星間塵氷の光化学反応による核酸塩基生成2019

    • Author(s)
      大場康弘,高野淑識,奈良岡浩,渡部直樹,香内晃
    • Organizer
      日本地球化学会第66回年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 星間分子雲における化学進化:単純分子から核酸塩基生成へ2019

    • Author(s)
      大場康弘,高野淑識,奈良岡浩,渡部直樹,香内晃
    • Organizer
      第37回有機地球化学シンポジウム
    • Related Report
      2019 Annual Research Report
  • [Presentation] H2S, why you no solid at 10 K? -Non thermal desorption from interstellar icy grains.2018

    • Author(s)
      Yasuhiro Oba
    • Organizer
      JPGU Meeting 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Chemical desorption of hydrogen sulfide from the surface of amorphous solid water2018

    • Author(s)
      Yasuhiro Oba, Takuto Tomaru, Akira Kouchi, Naoki Watanabe, Thanja Lamberts
    • Organizer
      The Olympian Symposium 2018 Gas and stars from milli- to mega- parsecs
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] なぜ極低温の星間分子雲で硫化水素はガスとして存在するのか?2018

    • Author(s)
      大場 康弘,都丸 琢斗,渡部 直樹,香内 晃
    • Organizer
      日本地球化学会第65回年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Experimental studies on the surface reaction of hydrogen sulfide with deuterium atoms on amorphous solid water at 10 K2018

    • Author(s)
      Yasuhiro Oba
    • Organizer
      ACS National Meeting 2018
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Deuteration levels of amino acids formed by photolysis of interstellar ice analogs containing deuterated methanol2017

    • Author(s)
      Yasuhiro Oba, Yoshinori Takano, Hiroshi Naraoka, Naoki Watanabe, Akira Kouchi
    • Organizer
      Evolution of Molecules in Space
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Variations in the Deuterium Enrichment of Amino Acids Formed by Photolysis of Ice Mixtures Containing Mono-Deuterated Methanol at 10 K2017

    • Author(s)
      Yasuhiro Oba, Yoshinori Takano, Hiroshi Naraoka, Naoki Watanabe, Akira Kouchi
    • Organizer
      Goldschmidt Conference 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 宇宙での化学進化におけるヘキサメチレンテトラミンの役割2017

    • Author(s)
      大場 康弘,高野 淑識,奈良岡 浩,渡部 直樹,香内 晃
    • Organizer
      第35回有機地球化学シンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] 疑似星間塵氷の光化学反応で生成する ヘキサメチレンテトラミンの重水素存在度2017

    • Author(s)
      大場 康弘,高野 淑識,奈良岡 浩,渡部 直樹,香内 晃
    • Organizer
      2017年度 日本地球化学会年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Formation of deuterated molecules by photolysis of interstellar ice analogs containing deuterated methanol isotopologs2017

    • Author(s)
      Yasuhiro Oba, Yoshinori Takano, Hiroshi Naraoka, Naoki Watanabe, Akira Kouchi
    • Organizer
      Dust and Ice Particles Spectroscopy and Scattering
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 光化学反応による 星間分子の重水素濃集度の変化 ー成果報告ー2017

    • Author(s)
      大場 康弘
    • Organizer
      新学術領域「宇宙分子進化」全体集会
    • Related Report
      2017 Annual Research Report
  • [Remarks] 研究室ホームページ(個人)

    • URL

      http://www.lowtem.hokudai.ac.jp/astro/oba/index1.html

    • Related Report
      2020 Annual Research Report
  • [Remarks] 所属研究室web page

    • URL

      http://www.lowtem.hokudai.ac.jp/astro/oba/index.html

    • Related Report
      2019 Annual Research Report 2018 Annual Research Report
  • [Remarks]

    • URL

      http://www.lowtem.hokudai.ac.jp/astro/oba/index.html

    • Related Report
      2017 Annual Research Report

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Published: 2017-04-28   Modified: 2022-01-27  

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