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Development of Triboluminescent Lanthanide Coordination Polymer Crystals

Research Project

Project/Area Number 17H04873
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Functional solid state chemistry
Research InstitutionNational Institute for Materials Science (2019-2020)
Tokyo University of Science (2018)
Hokkaido University (2017)

Principal Investigator

NAKANISHI Takayuki  国立研究開発法人物質・材料研究機構, 機能性材料研究拠点, 主任研究員 (30609855)

Project Period (FY) 2017-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥24,830,000 (Direct Cost: ¥19,100,000、Indirect Cost: ¥5,730,000)
Fiscal Year 2020: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2019: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2018: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2017: ¥13,130,000 (Direct Cost: ¥10,100,000、Indirect Cost: ¥3,030,000)
Keywords希土類 / 力学刺激発光 / 光物性 / 配位化合物 / 発光 / 力学刺激 / 配位高分子結晶 / 配位高分子 / 結晶成長 / 物性実験
Outline of Final Research Achievements

Triboluminescence is a phenomenon in which crystals emit light due to mechanical stimulation. In this study, we focused on the tribo-function expressed between the antenna ligands and lanthanides, and conducted research for the purpose of investigating the principle of the specific phenomenon and developing a new material. Specifically, in order to create a new luminescent material, we proposed a molecular doping method as a new synthesis way for coordination polymers and performed new function control. In addition, as a material approach to improve the visibility of triboluminescence, we investigated mixture compounds with an organic binder, which is an elastic body, and succeeded in improving the visibility of emission. The creation of a strong triboluminescent material is also important from the viewpoint of effective utilization of minute energy, and will lead to the creation of unprecedented substances as a new inorganic phosphor.

Academic Significance and Societal Importance of the Research Achievements

トリボルミネッセンス(力学刺激発光)は、接触など機械的刺激で固体が一瞬発光する現象である。本研究では希土類の配位高分子のアンテナ配位子と希土類との間で発現するトリボ機能に注目し、その現象の原理と、新材料開発を目的に研究を行いました。具体的には、新しい機能性発光体創成のため、分子ドーピング法を考案しさらに刹那の発光のトリボ発光の視認性を高めるために、弾性体である有機バインダーと複合化を行い、発光視認性の向上などに成功した。特に強い発光を示す刺激発光体創成は、セキュリティや微小エネルギーの有効利用の観点からも重要であり、新規な有機-無機ハイブリッド蛍光体の物質創生につながると考えています。

Report

(5 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (43 results)

All 2021 2020 2019 2018 2017 Other

All Journal Article (10 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 10 results,  Open Access: 2 results) Presentation (27 results) (of which Int'l Joint Research: 3 results,  Invited: 9 results) Book (3 results) Remarks (1 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Persistent Luminescence Properties of Ti4+-doped K2ZrSi3O9 Wadeite2020

    • Author(s)
      Iida Yuta、Sawamura Kenji、Iwasaki Kenichiro、Nakanishi Takayuki、Iwakura Fumitaka、Nakajima Yasushi、Yasumori Atsuo
    • Journal Title

      Sensors and Materials

      Volume: 32 Issue: 4 Pages: 1427

    • DOI

      10.18494/SAM.2020.2745

    • ISSN
      0914-4935, 2435-0869
    • Year and Date
      2020-04-20
    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Persistent luminescence properties of monoclinic luminescent zirconium oxide annealed under different oxygen partial pressures2020

    • Author(s)
      Kenji SAWAMURA, Kenichiro IWASAKI, Takayuki NAKANISHI, Fumitaka IWAKURA, Yasushi NAKAJIMA, Ken-ichi KATSUMATA, Atsuo YASUMORI
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 128 Issue: 4 Pages: 175-180

    • DOI

      10.2109/jcersj2.19230

    • NAID

      130007825765

    • ISSN
      1348-6535, 1882-0743
    • Year and Date
      2020-04-01
    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Circularly Polarized Absorption and Luminescence of Semiconductor Eu‐OCN Nanocrystals in the Blue Region of the Electromagnetic Spectrum2020

    • Author(s)
      Hasegawa Yasuchika、Koide Katsumasa、Tsurui Makoto、Kitagawa Yuichi、Nakanishi Takayuki、Doi Yoshihiro、Hinatsu Yukio、Fushimi Koji
    • Journal Title

      ChemPhysChem

      Volume: 21 Issue: 17 Pages: 2019-2024

    • DOI

      10.1002/cphc.202000468

    • NAID

      120007145360

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication of a Silica-Silica Nanoparticle Monolayer Array Nanocomposite Film on an Anodic Aluminum Oxide Substrate and Its Optical and Tribological Properties2020

    • Author(s)
      Sekiguchi Kazutoshi、Katsumata Ken-ichi、Segawa Hiroyo、Nakanishi Takayuki、Yasumori Atsuo
    • Journal Title

      ACS Applied Materials & Interfaces

      Volume: 12 Issue: 24 Pages: 27672-27681

    • DOI

      10.1021/acsami.0c03436

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The Role of π-f Orbital Interactions in Eu(III) Complexes for an Effective Molecular Luminescent Thermometer2020

    • Author(s)
      Kitagawa Yuichi、Kumagai Marina、Nakanishi Takayuki、Fushimi Koji、Hasegawa Yasuchika
    • Journal Title

      Inorganic Chemistry

      Volume: 59 Issue: 9 Pages: 5865-5871

    • DOI

      10.1021/acs.inorgchem.9b03492

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication of Silica Nanoparticle Monolayer Arrays Using an Anodic Aluminum Oxide Template2019

    • Author(s)
      Kazutoshi Sekiguchi, Takayuki Nakanishi, Hiroyo Segawa, Atsuo Yasumori
    • Journal Title

      ACS Omega

      Volume: 4 Issue: 10 Pages: 14333-14339

    • DOI

      10.1021/acsomega.9b02114

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Highly luminescent tetranuclear Eu(III) complex with characteristic cavity space.2019

    • Author(s)
      Toru Koizuka, Yuichi Kitagawa, Takayuki Nakanishi, Koji Fushimi, Yasuchika Hasegawa
    • Journal Title

      Inorganica Chimica Acta

      Volume: 486 Pages: 240-244

    • DOI

      10.1016/j.ica.2018.10.063

    • NAID

      120006960646

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Spin-orbit coupling dependent energy transfer in luminescent nonanuclear Yb-Gd / Yb-Lu clusters2018

    • Author(s)
      Omagari Shun、Nakanishi Takayuki、Kitagawa Yuichi、Seki Tomohiro、Fushimi Koji、Ito Hajime、Meijerink Andries、Hasegawa Yasuchika
    • Journal Title

      Journal of Luminescence

      Volume: 201 Pages: 170-175

    • DOI

      10.1016/j.jlumin.2018.04.049

    • NAID

      120006882064

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] A Luminescent Dinuclear EuIII/TbIII Complex with LMCT Band as a Single-Molecular Thermosensor2018

    • Author(s)
      Yanagisawa Kei、Kitagawa Yuichi、Nakanishi Takayuki、Seki Tomohiro、Fushimi Koji、Ito Hajime、Hasegawa Yasuchika
    • Journal Title

      Chemistry - A European Journal

      Volume: 24 Issue: 8 Pages: 1956-1961

    • DOI

      10.1002/chem.201705021

    • NAID

      120006552868

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Origin of Concentration Quenching in Ytterbium Coordination Polymers: Phonon-Assisted Energy Transfer2017

    • Author(s)
      Omagari Shun、Nakanishi Takayuki、Hirai Yuichi、Kitagawa Yuichi、Seki Tomohiro、Fushimi Koji、Ito Hajime、Hasegawa Yasuchika
    • Journal Title

      Eur. J. Inorg. Chem.

      Volume: 2018 Issue: 5 Pages: 545-545

    • DOI

      10.1002/ejic.201701396

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Presentation] 熱耐久性のフッ素ベースEu配位化合物を用いた狭帯赤色LEDの検討2021

    • Author(s)
      中西 貴之, 許 健,高橋 向星,武田 隆史,広崎 尚登
    • Organizer
      第68回応用物理春季学術講演会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 蛍光体単結晶を用いた光励起状態からのエネルギー移動経路の検討2021

    • Author(s)
      中西貴之
    • Organizer
      応用物理学会 極限的励起状態の形成と量子エネルギー変換研究グループ 第1回研究会
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] 賦活蛍光体を用いた光電流測定による電荷担体経路の検討2020

    • Author(s)
      中西 貴之, 樋口 幹雄,竹村 翔太, 高橋 向星,武田 隆史,広崎 尚登
    • Organizer
      第81回応用物理秋季学術講演会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 青色励起可能な高輝度ユウロピウム配位化合物の合成と光機能評価2020

    • Author(s)
      大見拓也、中西貴之、勝又健一、岩崎謙一郎、安盛敦雄、舟橋司朗、武田隆史、広崎尚登
    • Organizer
      第67回応用物理学会春季学術講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 希土類二核錯体を用いた温度センシング発光体の検討2019

    • Author(s)
      勝木友海、中西貴之、岩崎謙一郎、安盛敦雄
    • Organizer
      第 35 回希土類討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 異種配位子ドーピングによる希土類配位高分子結晶の光機能化2019

    • Author(s)
      上野友徳、中西貴之、岩崎謙一郎、武田隆史、廣崎尚登、安盛敦雄
    • Organizer
      第 35 回希土類討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 希土類配位高分子結晶の形態制御と光物性評価2019

    • Author(s)
      渡邊俊祐、中西貴之、岩﨑謙一郎、宇部卓司、武田隆史、廣崎尚登、安盛敦雄
    • Organizer
      第 35 回希土類討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 希土類配位蛍光体の物質設計2019

    • Author(s)
      中西貴之
    • Organizer
      第8回フォトニクスのための材料研究会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] 希土類を用いた配位化合物蛍光体の光機能2019

    • Author(s)
      中西貴之
    • Organizer
      第57回セラミックス基礎科学討論会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 力学刺激発光を示す希土類配位高分子結晶への配位子置換2018

    • Author(s)
      松田賢司, 中西貴之, 北川裕一, 伏見公志, 長谷川靖哉
    • Organizer
      第30回配位化合物の光化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 配位子置換による希土類配位高分子結晶の光機能物性2018

    • Author(s)
      松田賢司, 北川裕一, 中西貴之, 伏見公志, 長谷川靖哉
    • Organizer
      北海道支部2018年夏季研究発表会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 希土類配位高分子結晶へのアンテナ配位子置換とその発光特性2018

    • Author(s)
      松田賢司, 北川裕一, 中西貴之, 伏見公志, 長谷川靖哉
    • Organizer
      第8回CSJ化学フェスタ
    • Related Report
      2018 Annual Research Report
  • [Presentation] 希土類配位結晶の新しい光機能化2018

    • Author(s)
      中西貴之
    • Organizer
      日本セラミック協会第31回秋季シンポジウム
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 異種配位子固溶による希土類配位高分子結晶の光機能化2018

    • Author(s)
      上野友徳  岩崎謙一郎 安盛敦雄 中西貴之
    • Organizer
      第8回CSJ化学フェスタ
    • Related Report
      2018 Annual Research Report
  • [Presentation] 希土類配位高分子結晶の物質機能設計2018

    • Author(s)
      中西貴之
    • Organizer
      第30回配位化合物の光化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 希土類配位構造体の光機能に関する研究2018

    • Author(s)
      中西貴之
    • Organizer
      日本希土類学会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 希土類配位高分子の微細構造評価2017

    • Author(s)
      袴田翔, 中西貴之, 北川裕一, 伏見公志, 長谷川靖哉
    • Organizer
      第33回希土類討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 強発光機能を有するキラル型希土類錯体ポリマーの開発2017

    • Author(s)
      三浦由衣, 北川裕一, 中西貴之, 伏見公志, 長谷川靖哉,
    • Organizer
      第33回希土類討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Mechanism Elucidation and Suppression of Back Energy Transfer in Nonanuclear Tb3+Clusters2017

    • Author(s)
      S. Omagari, T.Nakanishi, Y. Hasegawa
    • Organizer
      Nagoya Univ.-Tsinghua Univ.-Toyota Motor Corp.-Hokkaido Univ. Joint symposium (NTTH)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 九核希土類クラスターにおけるエネルギー移動と発光特性に関する研究2017

    • Author(s)
      大曲駿, 中西貴之, 北川裕一, 伏見公志, 長谷川靖哉
    • Organizer
      第78回応用物理学会秋季学術講演会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Concentration quenching mechanism of Ytterbium(III) coordination polymer2017

    • Author(s)
      S. Omagari, T. Nakanishi, Y. Kitagawa, K. Fushimi, Y. Hasegawa
    • Organizer
      錯体化学会第67回討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 円偏光発光特性を示すEu(III)錯体の高分子化による発光特性変化2017

    • Author(s)
      三浦由衣, 北川裕一, 中西貴之, 伏見公志, 長谷川靖哉
    • Organizer
      錯体化学会第67回討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] フッ素含有ホスフィンオキシド配位子を有する希土類二核錯体の子体光物性2017

    • Author(s)
      袴田翔, 中西貴之, 北川裕一, 伏見公志, 長谷川靖哉
    • Organizer
      第36回 固体・表面光化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 新しい希土類化合物の物質設計とその光機能性2017

    • Author(s)
      中西貴之
    • Organizer
      電気化学会北海道支部第33回ライラックセミナー・第23回若手研究者交流会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 希土類配位高分子の物質設計とその光機能2017

    • Author(s)
      中西貴之
    • Organizer
      2017年北海道高分子研究会 ~ 秩序を生み出す高分子 ~
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Luminescent Lanthanide Coordination Compounds with Inorganic Lattice2017

    • Author(s)
      T. Nakanishi
    • Organizer
      12th Pacific Rim Conference on Ceramic and Glass Technology (PACRIM12)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Luminescent Lanthanide Coordination Polymer Crystals with Temperature Sensitive Properties2017

    • Author(s)
      T. Nakanishi
    • Organizer
      International Workshops on Photoluminescence of Rare-Earth 2017 (Pre'17)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Book] 希土類「希土類配位構造体の光機能に関する研究」2018

    • Author(s)
      中西貴之
    • Total Pages
      5
    • Publisher
      日本希土類学会
    • Related Report
      2018 Annual Research Report
  • [Book] 光化学, 集積構造を持つ希土類配位化合物の光機能2018

    • Author(s)
      中西貴之、平井悠一、長谷川靖哉
    • Total Pages
      5
    • Publisher
      光化学協会
    • Related Report
      2018 Annual Research Report
  • [Book] 光化学2018

    • Author(s)
      中西貴之、平井悠一、長谷川靖哉
    • Total Pages
      4
    • Publisher
      光化学協会
    • Related Report
      2017 Annual Research Report
  • [Remarks] 所属機関HP

    • URL

      https://samurai.nims.go.jp/profiles/nakanishi_takayuki/publications#presentation

    • Related Report
      2019 Annual Research Report
  • [Patent(Industrial Property Rights)] 希土類錯体ポリマー及び発光体2018

    • Inventor(s)
      中西貴之, 松田賢司、沢登拓矢、長谷川靖哉
    • Industrial Property Rights Holder
      中西貴之, 松田賢司、沢登拓矢、長谷川靖哉
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2018-011508
    • Filing Date
      2018
    • Related Report
      2017 Annual Research Report
  • [Patent(Industrial Property Rights)] 希土類化合物、発光体、発光デバイス、波長変換材料及びセキュリティ材料2017

    • Inventor(s)
      中西貴之, 袴田翔, 北川裕一, 伏見公志 長谷川靖哉
    • Industrial Property Rights Holder
      中西貴之, 袴田翔, 北川裕一, 伏見公志 長谷川靖哉
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2017-221678
    • Filing Date
      2017
    • Related Report
      2017 Annual Research Report

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Published: 2017-04-28   Modified: 2022-01-27  

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