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High efficiency water-splitted photoelectrode using metal nanopillars embedded in oxide thin films

Research Project

Project/Area Number 17H04895
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Device related chemistry
Research InstitutionNihon University (2019)
The University of Tokyo (2017-2018)

Principal Investigator

TAKAHASHI Ryota  日本大学, 工学部, 准教授 (80546573)

Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥24,830,000 (Direct Cost: ¥19,100,000、Indirect Cost: ¥5,730,000)
Fiscal Year 2019: ¥5,980,000 (Direct Cost: ¥4,600,000、Indirect Cost: ¥1,380,000)
Fiscal Year 2018: ¥5,980,000 (Direct Cost: ¥4,600,000、Indirect Cost: ¥1,380,000)
Fiscal Year 2017: ¥12,870,000 (Direct Cost: ¥9,900,000、Indirect Cost: ¥2,970,000)
Keywords水分解光電極 / 水素合成 / 酸化物エレクトロニクス / 光触媒 / 光電極 / ナノ構造 / パルスレーザー堆積法 / ナノ材料
Outline of Final Research Achievements

In this study, I aim to improve the efficiency of photoelectron by growing metal nano pillar structure in an oxide thin film by using a self-organizing method and applying it as a water splitting photoelectron material. In particular, a material with a Schottky junction at the interface between the metal and the oxide is selected, and the photo-excited photo carrier is made to function as a depletion layer for separating charges into holes and electrons, A number of photoelectrons with three-dimensional Schottky junctions dispersed in a photoelectron thin film by a self-assemble process are fabricated to realize high efficiency of hydrogen synthesis. Here, I particularly focus on SrTiO3 based visible light responsive photocatalysts, and aim at creating innovative photoelectrode material using chemically stable single crystal thin films.

Academic Significance and Societal Importance of the Research Achievements

再生可能なエネルギーの開発は地球全体のエネルギーを考える上で重要であるのは言うまでもなく、安全かつ地球の温暖化を防ぐエネルギー材料の開発が求められている。その一つの候補が水素エネルギーである。トヨタの水素自動車“ミライ”で知られているように、燃料電池や自動車において、すでに実用段階に入っている。このような水素エネルギーがより広く人間社会に普及していくには製造、輸送、貯蔵、供給をはじめとするインフラ関連の技術開発から、大学レベルでの基礎的な科学研究まで、それぞれの研究の重要性が増しつつある。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (20 results)

All 2019 2018 2017

All Journal Article (8 results) (of which Int'l Joint Research: 5 results,  Peer Reviewed: 8 results,  Open Access: 3 results) Presentation (12 results) (of which Int'l Joint Research: 6 results,  Invited: 8 results)

  • [Journal Article] Noble metal clustering and nanopillar formation in an oxide matrix2019

    • Author(s)
      Lippmaa Mikk、Kawasaki Seiji、Takahashi Ryota、Yamamoto Takahisa
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 59 Issue: 1 Pages: 010501-010501

    • DOI

      10.7567/1347-4065/ab57e2

    • NAID

      210000157581

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Gradient Carrier Doping as a Method for Maximizing the Photon-to-Current Efficiency of a SrTiO3 Water-Splitting Photoanode2019

    • Author(s)
      Kawasaki Seiji、Takahashi Ryota、Lippmaa Mikk
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 123 Issue: 25 Pages: 15551-15556

    • DOI

      10.1021/acs.jpcc.9b02546

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Pulsed laser deposition with rapid beam deflection by a galvanometer mirror scanner2019

    • Author(s)
      Maruyama S.、Sannodo N.、Harada R.、Anada Y.、Takahashi R.、Lippmaa M.、Matsumoto Y.
    • Journal Title

      Review of Scientific Instruments

      Volume: 90 Issue: 9 Pages: 093901-093901

    • DOI

      10.1063/1.5104291

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and characterization of (111)-oriented BaTiO3 thin films2019

    • Author(s)
      Bolstad T、Kjaernes K、Raa K、Takahashi R、Lippmaa M.、Tybell T
    • Journal Title

      Materials Research Express

      Volume: 6 Issue: 5 Pages: 056409-056409

    • DOI

      10.1088/2053-1591/ab0221

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Pyroelectric detection of ferroelectric polarization in magnetic thin films2018

    • Author(s)
      Takahashi Ryota、Lippmaa Mikk
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 57 Issue: 9 Pages: 0902A1-0902A1

    • DOI

      10.7567/jjap.57.0902a1

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Noble Metal Nanocluster Formation in Epitaxial Perovskite Thin Films2018

    • Author(s)
      Lee Mihee、Arras Remi、Takahashi Ryota、Warot-Fonrose Benedicte、Daimon Hiroshi、Casanove Marie-Jose、Lippmaa Mikk
    • Journal Title

      ACS Omega

      Volume: 3 Issue: 2 Pages: 2169-2173

    • DOI

      10.1021/acsomega.7b02071

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Thermally Stable Sr2RuO4 Electrode for Oxide Heterostructures2017

    • Author(s)
      Takahashi Ryota、Lippmaa Mikk
    • Journal Title

      ACS Applied Materials & Interfaces

      Volume: 9 Issue: 25 Pages: 21314-21321

    • DOI

      10.1021/acsami.7b03577

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Hole trap state analysis in SrTiO32017

    • Author(s)
      Osawa N.、Takahashi R.、Lippmaa M.
    • Journal Title

      Applied Physics Letters

      Volume: 110 Issue: 26 Pages: 263902-263902

    • DOI

      10.1063/1.4991015

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] A-site driven ferroelectricity in ferromagnetic double perovskite2019

    • Author(s)
      Ryota Takahashi
    • Organizer
      Asia-Pacific PFM 2019, August 12-14, 2019, Seoul, Korea
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Thermally stable Sr2RuO4 electrode for ferroelectric BaTiO3 and photocatalytic Rh:SrTiO3 films2018

    • Author(s)
      Ryota Takahashi, Mikk Lippmaa
    • Organizer
      Material Research Society Fall meeting
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] PLD 手法を用いた SrTiO3 薄膜の成長における He ガスの効果2018

    • Author(s)
      高橋竜太、李智蓮、リップマー ミック
    • Organizer
      応用物理学会:平成30年度春季
    • Related Report
      2018 Annual Research Report
  • [Presentation] 強誘電体薄膜の高温堆積とフレキシブル化2018

    • Author(s)
      高橋竜太
    • Organizer
      応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Self-assembled metal nanopillars embedded in oxide semiconductor photoelectrode for photoelectrochmical water splitting2018

    • Author(s)
      Ryota Takahashi
    • Organizer
      Conference on electronic and advanced materials
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Self-assemble metal nanopillars embedded in photoelectrochemical water splitting photoelectrodes2018

    • Author(s)
      Ryota Takahashi
    • Organizer
      International Symposium on Pure & Applied Chemistry 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 高効率水素製造光触媒を実現した新奇薄膜構造 ~高分解能STEM観察ではじめて判ったナノピラー構造~2017

    • Author(s)
      高橋竜太
    • Organizer
      平成29年度ナノテクノロジープラットフォーム総会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 焦電性測定による磁性強誘電体の開発2017

    • Author(s)
      高橋竜太
    • Organizer
      ポスト新機能物質開発のための戦略会議
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Ferroelectricity in ferromagnetic La2NiMnO6 thin films2017

    • Author(s)
      Ryota Takahashi
    • Organizer
      Korea Physics Society Spring meeting
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Ferroelectric properties in ferromagnetic La2NiMnO6 thin films2017

    • Author(s)
      Ryota Takahashi
    • Organizer
      Korea-China-Japan Symposium on Complex Oxide Thin Films and Applications
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] BaTiO3薄膜中の欠陥構造によって変化する自発分極の向き2017

    • Author(s)
      高橋竜太、Mikk Lippmaa
    • Organizer
      第78回応用物理学学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Rh:SrTiO3薄膜におけるRhの価数観測2017

    • Author(s)
      細川喜久、高橋竜太、組頭広志、Mikk Lippmaa
    • Organizer
      第78回応用物理学学術講演会
    • Related Report
      2017 Annual Research Report

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Published: 2017-04-28   Modified: 2021-02-19  

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