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A study on intermolecular energy potential in a polar molecule by multi-spectroscopy using acoustic and electromagnetic waves

Research Project

Project/Area Number 17H04908
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Thermal engineering
Research InstitutionNational Institute of Advanced Industrial Science and Technology

Principal Investigator

Kano Yuya  国立研究開発法人産業技術総合研究所, 計量標準総合センター, 主任研究員 (90510040)

Project Period (FY) 2017-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥24,180,000 (Direct Cost: ¥18,600,000、Indirect Cost: ¥5,580,000)
Fiscal Year 2020: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2019: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2018: ¥6,630,000 (Direct Cost: ¥5,100,000、Indirect Cost: ¥1,530,000)
Fiscal Year 2017: ¥12,870,000 (Direct Cost: ¥9,900,000、Indirect Cost: ¥2,970,000)
Keywords音波 / 電磁波 / 音速 / 誘電率 / 分子間ポテンシャル / 双極子モーメント / 分極率 / ビリアル係数 / 有極性分子 / スペクトロスコピー / 極性分子 / スペクトロメータ / 粘性 / 粘度 / 熱伝導率
Outline of Final Research Achievements

For the aim of the study on the intermolecular potential energy of a polar molecule, a new multi-spectrometer with a cylindrical acoustic-microwave cavity resonator was developed in this study. Using the developed multi-spectrometer, speed-of-sound and dielectric relative permittivity were simultaneously and accurately measured for a polar molecule gas in wide ranges of temperature and pressure. The electrical polarity of the polar molecule was evaluated by using the measured data, and the virial coefficients were calculated on the basis of Stockmayer potential model in combination with the corresponding state principle. Density was successfully derived from the present virial coefficients in wide ranges of temperature and pressure. The developed multi-spectrometer with the proposed data analysis method enables a precise multi-property evaluation for polar molecules.

Academic Significance and Societal Importance of the Research Achievements

本研究で開発したマルチスペクトロメータを用いることで,音速および誘電率を同時に高精度計測することができ,得られたデータの解析から理想気体状態の定圧比熱,エンタルピー,双極子モーメント,分子分極率などを求めることができる.さらに,本研究で提案する分子間ポテンシャルを対応状態原理により表現したビリアル係数算出モデルを用いることで,密度も正確に導出することができる.これらの計測技術やデータ解析手法を応用することで,冷媒など作動流体について迅速かつ高精度な多重物性評価を実現することができ,熱エネルギー機器の省エネ化や温室効果ガス削減などの波及効果が期待できる.

Report

(5 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (11 results)

All 2021 2020 2019 2018 2017 Other

All Journal Article (6 results) (of which Peer Reviewed: 6 results,  Open Access: 2 results) Presentation (4 results) (of which Int'l Joint Research: 4 results) Remarks (1 results)

  • [Journal Article] Multi-property evaluation for a gas sample based on the acoustic and electromagnetic resonances measurement in a cylindrical cavity2021

    • Author(s)
      Kano Yuya
    • Journal Title

      The Journal of Chemical Thermodynamics

      Volume: 159 Pages: 106448-106448

    • DOI

      10.1016/j.jct.2021.106448

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thermophysical Properties of 1,1,1,3,3,3-hexafluoro-2-methoxypropane (HFE-356mmz) in the Vapor Phase Measured by Using an Acoustic-Microwave Resonance Technique2020

    • Author(s)
      Kano Yuya
    • Journal Title

      Energies

      Volume: 13 Issue: 20 Pages: 5525-5525

    • DOI

      10.3390/en13205525

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Dipole moment and heat capacity in the ideal gas state derived from relative permittivity and speed of sound measurements for HFO-1123 and HCFO-1224yd(Z)2020

    • Author(s)
      Kano Yuya、Kayukawa Yohei、Fujita Yoshitaka
    • Journal Title

      International Journal of Refrigeration

      Volume: 118 Pages: 354-364

    • DOI

      10.1016/j.ijrefrig.2020.06.027

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Speed of sound and dielectric constant measurements for HFO-1336mzz(E) in the gas phase2019

    • Author(s)
      Yuya Kano, Yohei Kayukawa, Yoshitaka Fujita
    • Journal Title

      Proc. of the 2nd Pacific Rim Thermal Engineering Conference

      Volume: 24041 Pages: 1-5

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Speed of Sound and Dielectric Constant Measurements for a Mixture of HFO-1123 and R-32 in the Gas Phase2018

    • Author(s)
      Yuya Kano, Yohei Kayukawa, Yoshitaka Fujita
    • Journal Title

      Proceedings of 1st IIR Conference on the Application of HFO Refrigerants

      Volume: - Pages: 1145-1145

    • DOI

      10.18462/IIR.HFO.2018.1145

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Progress Report on NMIJ Acoustic Gas Thermometry at the Triple Point of Water2018

    • Author(s)
      T. Misawa, J. Widiatmo, Y. Kano, T. Sasagawa, K. Yamazawa
    • Journal Title

      International Journal of Thermophysics

      Volume: 39 Issue: 1 Pages: 4-25

    • DOI

      10.1007/s10765-017-2317-4

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Presentation] Speed of sound and dielectric constant measurements for HFO-1336mzz(E) in the gas phase2019

    • Author(s)
      Yuya Kano, Yohei Kayukawa, Yoshitaka Fujita
    • Organizer
      The 2nd Pacific Rim Thermal Engineering Conference
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Simultaneous Measurement of Speed of Sound and Dielectric Constant for A Gas Sample2018

    • Author(s)
      Yuya Kano
    • Organizer
      20th Symposium on Thermophysical Properties
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Speed of Sound and Dielectric Constant Measurements for a Mixture of HFO-1123 and R-32 in the Gas Phase2018

    • Author(s)
      Yuya Kano, Yohei Kayukawa, Yoshitaka Fujita
    • Organizer
      1st IIR Conference on the Application of HFO Refrigerants
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] SPEED OF SOUND AND DIELECTRIC CONSTANT MEASUREMENTS FOR LOW-GWP REFRIGERANTS IN THE GAS PHASE2017

    • Author(s)
      Y. Kano, Y. Kayukawa, Y. Fujita
    • Organizer
      21st European Conference on Thermophysical Properties
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Remarks] 地球温暖化への影響が小さい次世代冷媒の熱物性評価

    • URL

      https://advanceseng.com/thermophysical-properties-evaluation-next-generation-refrigerants-low-global-warming-impact/

    • Related Report
      2020 Annual Research Report

URL: 

Published: 2017-04-28   Modified: 2022-01-27  

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