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In-situ monitoring of NOM fouling caused in porous membrane with the use of solid-state excitation emission matrix analysis

Research Project

Project/Area Number 17H04941
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Civil and environmental engineering
Research InstitutionChuo University

Principal Investigator

Yamamura Hiroshi  中央大学, 理工学部, 教授 (40515334)

Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥24,440,000 (Direct Cost: ¥18,800,000、Indirect Cost: ¥5,640,000)
Fiscal Year 2019: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2018: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2017: ¥17,030,000 (Direct Cost: ¥13,100,000、Indirect Cost: ¥3,930,000)
Keywords膜ろ過 / 励起蛍光分光分析 / 固体測定 / In-situ分析 / 膜ファウリング / Natural organic matter / 蛍光分光分析 / 固体蛍光分析 / 膜分離 / 蛍光分光 / センサー / 非破壊分析 / フミン酸 / In-situ / 蛍光分光光度計 / MF/UF膜 / タンパク質 / ゲル化 / Natural Organic Matter / 光ファイバー / In-situモニタリング / In-situ観察 / ファウリング
Outline of Final Research Achievements

Excitation emission matrix (EEM) is a method for discriminating the type of organic matter by detecting fluorescences emitted when an organic substance is irradiated with excitation light.
In this study, with the aim of applying EEM to the analysis of membrane foulant, (1) a database for peak positions of solid EEM analysis was constructed for samples recovered from various waters, and (2) a continuous monitoring test of membrane fouling was carried out using solid EEM. Despite being the same material, it was revealed that the peak positions were different in the liquid and solid samples.
Solid-state EEM revealed organic matter properties related to the progress of irreversible membrane fouling.

Academic Significance and Societal Importance of the Research Achievements

本研究により、簡易かつ高感度に膜ファウリング(目詰まり)物質が定性できるようになった。これにより、これまで試行錯誤的に実施されてきた膜ろ過運転の最適化や薬品洗浄条件の選定などを実施できるようになるため、大幅に膜ろ過にかかる導入コストの低減に繋がるものと期待される。
また、本研究により構築したNOM(天然有機物)の固体EEMスペクトルデータベースにより、NOMの特性を簡単かつ非破壊で分析できるようになる。それにより、土壌の性質が簡単に分析できるようになる。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (13 results)

All 2019 2018 2017

All Journal Article (4 results) (of which Peer Reviewed: 4 results,  Open Access: 1 results) Presentation (9 results) (of which Int'l Joint Research: 3 results,  Invited: 2 results)

  • [Journal Article] Solid-phase fluorescence excitation emission matrix for in-situ monitoring of membrane fouling during microfiltration using a polyvinylidene fluoride hollow fiber membrane2019

    • Author(s)
      Yamamura Hiroshi、Ding Qing、Watanabe Yoshimasa
    • Journal Title

      Water Research

      Volume: 164 Pages: 114928-114928

    • DOI

      10.1016/j.watres.2019.114928

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Application of Graphene Oxide for Adsorption Removal of Geosmin and 2-Methylisoborneol in the Presence of Natural Organic Matter2019

    • Author(s)
      Hafuka Akira、Nagasato Takahiro、Yamamura Hiroshi
    • Journal Title

      International Journal of Environmental Research and Public Health

      Volume: 16 Issue: 11 Pages: 1907-1907

    • DOI

      10.3390/ijerph16111907

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Digestion performance and contributions of organic and inorganic fouling in an anaerobic membrane bioreactor treating waste activated sludge2019

    • Author(s)
      Hafuka Akira、Mashiko Riho、Odashima Ryuto、Yamamura Hiroshi、Satoh Hisashi、Watanabe Yoshimasa
    • Journal Title

      Bioresource Technology

      Volume: 272 Pages: 63-69

    • DOI

      10.1016/j.biortech.2018.09.147

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Differences in behaviour of three biopolymer constituents in coagulation with polyaluminium chloride: Implications for the optimisation of a coagulation?membrane filtration process2018

    • Author(s)
      Ding Qing、Yamamura Hiroshi、Yonekawa Hitoshi、Aoki Nobuhiro、Murata Naoki、Hafuka Akira、Watanabe Yoshimasa
    • Journal Title

      Water Research

      Volume: 133 Pages: 255-263

    • DOI

      10.1016/j.watres.2018.01.034

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Presentation] 水中天然有機物の固体・液体3次元励起蛍光スペクトルの差異2019

    • Author(s)
      丁青、山村寛
    • Organizer
      第94回 水道研究発表会
    • Related Report
      2019 Annual Research Report
  • [Presentation] In-situ固体三次元励起蛍光分光法を利用した薬品洗浄による膜ファウリング解消効果の可視化2019

    • Author(s)
      落合洸介、山村寛
    • Organizer
      第94回 水道研究発表会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Optimization of Inline-EEM analysis for validated PARAFAC decomposition of NOM2019

    • Author(s)
      Yuta Yamamoto, Hiroshi Yamamura
    • Organizer
      IWA specialist conference on Natural Organic Matter in Water 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Comparison Of Three-dimensional Fluorescence Excitation-emission Matrix Spectroscopy Determined For Aquatic NOMs In Solid-phase And Liquid-phase2019

    • Author(s)
      Ding Qing, Hiroshi Yamamura
    • Organizer
      IWA specialist conference on Natural Organic Matter in Water 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 人口減少社会に向けた”スマート”な上下水道インフラ2019

    • Author(s)
      山村 寛
    • Organizer
      中央大学技術士会 講演会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] Characterization and chemical cleaning of irreversible membrane fouling by in-situ SPF-EEM2019

    • Author(s)
      K. Ochiai, Q. Ding, H. Yamamura, Y.
    • Organizer
      9th International Water Association (IWA) Membrane Technology Conference & Exhibition for Water and Wastewater Treatment and Reuse
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] In‐situ固体3次元励起蛍光スペクトル分析法による膜ファウリング原因物質・メカニズムの推定2018

    • Author(s)
      丁青, 山村寛, 渡辺義公
    • Organizer
      全国会議(水道研究発表会)
    • Related Report
      2018 Annual Research Report
  • [Presentation] 固体3D‐EEMによる中空糸膜に蓄積した膜ファウリング物質の非破壊連続観察2017

    • Author(s)
      潘鵬, 山村寛, 貝谷吉英
    • Organizer
      水道研究発表会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 固体3次元励起スペクトル分析による非破壊膜ファウリング解析2017

    • Author(s)
      山村寛, PAN Peng, 渡辺義公
    • Organizer
      日本水環境学会シンポジウム
    • Related Report
      2017 Annual Research Report
    • Invited

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Published: 2017-04-28   Modified: 2021-02-19  

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