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Development of Carbon Dioxide Fixation Reactions

Research Project

Project/Area Number 17H06143
Research Category

Grant-in-Aid for Scientific Research (S)

Allocation TypeSingle-year Grants
Research Field Synthetic chemistry
Research InstitutionTokyo Institute of Technology

Principal Investigator

Iwasawa Nobuharu  東京工業大学, 理学院, 教授 (40168563)

Project Period (FY) 2017-05-31 – 2022-03-31
Project Status Completed (Fiscal Year 2021)
Budget Amount *help
¥209,690,000 (Direct Cost: ¥161,300,000、Indirect Cost: ¥48,390,000)
Fiscal Year 2021: ¥28,340,000 (Direct Cost: ¥21,800,000、Indirect Cost: ¥6,540,000)
Fiscal Year 2020: ¥27,300,000 (Direct Cost: ¥21,000,000、Indirect Cost: ¥6,300,000)
Fiscal Year 2019: ¥28,990,000 (Direct Cost: ¥22,300,000、Indirect Cost: ¥6,690,000)
Fiscal Year 2018: ¥34,710,000 (Direct Cost: ¥26,700,000、Indirect Cost: ¥8,010,000)
Fiscal Year 2017: ¥90,350,000 (Direct Cost: ¥69,500,000、Indirect Cost: ¥20,850,000)
Keywords二酸化炭素固定化 / 光反応化学 / 有機合成化学 / 二酸化炭素 / 合成化学 / 可視光エネルギー
Outline of Final Research Achievements

To utilize carbon dioxide as a one-carbon source, we have designed and constructed new transition metal complexes or complex systems. Using these systems, we succeeded in developing various catalytic reactions to give useful carboxylic acid derivatives from various organic compounds and carbon dioxide. Among them, the reaction of various hydrocarbons such as ethylene and styrenes with carbon dioxide to give carboxylic acids and the development of a method to regenerate catalytically active species using visible light energy are leading achievements in this research field.

Academic Significance and Societal Importance of the Research Achievements

本研究の学術的な意義は、遷移金属触媒を用いて不活性な分子である二酸化炭素をさまざまな有機化合物と直接反応させる手法の開発に成功したことである。また社会的な意義としては、化石資源の枯渇が大きな課題となっている現在、二酸化炭素を炭素資源として利用することで今後の物質生産に新たな可能性を提供したことである。さらに、従来必要とされていた金属還元剤に代え可視光エネルギーを利用する還元手法の開発は、太陽エネルギーを利用する物質生産として重要性が極めて高いものである。

Assessment Rating
Verification Result (Rating)

A

Assessment Rating
Result (Rating)

A: Progress in the research is steadily towards the initial goal. Expected research results are expected.

Report

(11 results)
  • 2022 Research Progress Assessment (Verification Result) ( PDF )
  • 2021 Annual Research Report   Final Research Report ( PDF )
  • 2020 Annual Research Report   Abstract(Research Progress Assessment) ( PDF )   Research Progress Assessment (Result) ( PDF )
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • 2017 Abstract ( PDF )   Comments on the Screening Results ( PDF )   Annual Research Report
  • Research Products

    (72 results)

All 2022 2021 2020 2019 2018 2017 Other

All Int'l Joint Research (3 results) Journal Article (18 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 18 results,  Open Access: 1 results,  Acknowledgement Compliant: 1 results) Presentation (49 results) (of which Int'l Joint Research: 6 results,  Invited: 7 results) Book (1 results) Patent(Industrial Property Rights) (1 results)

  • [Int'l Joint Research] ICIQ(スペイン)

    • Related Report
      2021 Annual Research Report
  • [Int'l Joint Research] ICIQ(スペイン)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] ICIQ(Spain)

    • Related Report
      2017 Annual Research Report
  • [Journal Article] Visible‐Light‐Enabled Carboxylation of Benzyl Alcohol Derivatives with CO2 Using a Palladium/Iridium Dual Catalyst2022

    • Author(s)
      Jin Yushu、Toriumi Naoyuki、Iwasawa Nobuharu
    • Journal Title

      ChemSusChem

      Volume: 15 Issue: 3

    • DOI

      10.1002/cssc.202200021

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Catalytic Synthesis of a Methylmalonate Salt from Ethylene and Carbon Dioxide through Photoinduced Activation and Photoredox-Catalyzed Reduction of Nickelalactones2022

    • Author(s)
      Takahashi Kohei、Sakurazawa Yuji、Iwai Asaki、Iwasawa Nobuharu
    • Journal Title

      ACS Catalysis

      Volume: 12 Issue: 7 Pages: 3776-3781

    • DOI

      10.1021/acscatal.2c01053

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mechanistic Studies into Visible Light-Driven Carboxylation of Aryl Halides/Triflates by the Combined Use of Palladium and Photoredox Catalysts2021

    • Author(s)
      Toriumi Naoyuki、Shimomaki Katsuya、Caner Joaquim、Murata Kei、Martin Ruben、Iwasawa Nobuharu
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 94 Issue: 7 Pages: 1846-1853

    • DOI

      10.1246/bcsj.20210151

    • NAID

      130008076891

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Metal‐Free Photoredox‐Catalyzed Hydrodefluorination of Fluoroarenes Utilizing Amide Solvent as Reductant2021

    • Author(s)
      Toriumi Naoyuki、Yamashita Kazuya、Iwasawa Nobuharu
    • Journal Title

      Chemistry - A European Journal

      Volume: 27 Issue: 49 Pages: 12635-12641

    • DOI

      10.1002/chem.202101813

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rhodium‐Catalyzed meta‐Selective C-H Carboxylation Reaction of 1,1‐Diarylethylenes via Hydrorhodation‐Rhodium Migration2021

    • Author(s)
      Saito Takanobu、Caner Joaquim、Toriumi Naoyuki、Iwasawa Nobuharu
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 60 Issue: 43 Pages: 23349-23356

    • DOI

      10.1002/anie.202109470

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mechanistic Investigations of the Ruthenium-Catalyzed Synthesis of Acrylate Salt from Ethylene and CO22020

    • Author(s)
      Takahashi Kohei、Hirataka Yo、Ito Tatsuyoshi、Iwasawa Nobuharu
    • Journal Title

      Organometallics

      Volume: 39 Issue: 9 Pages: 1561-1572

    • DOI

      10.1021/acs.organomet.9b00659

    • Related Report
      2020 Annual Research Report 2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rh‐Catalyzed Direct Carboxylation of Alkenyl C-H Bonds of Alkenylpyrazoles2020

    • Author(s)
      Saitou Takanobu、Jin Yushu、Isobe Kotaro、Suga Takuya、Takaya Jun、Iwasawa Nobuharu
    • Journal Title

      Chemistry - An Asian Journal

      Volume: 15 Issue: 13 Pages: 1941-1944

    • DOI

      10.1002/asia.202000476

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rhodium-Catalyzed Chemoselective Hydrosilylation of Nitriles to an Imine Oxidation Level Enabled by a Pincer-type Group 13 Metallylene Ligand2020

    • Author(s)
      Takaya Jun、Ogawa Koki、Nakaya Ryota、Iwasawa Nobuharu
    • Journal Title

      ACS Catalysis

      Volume: 10 Issue: 20 Pages: 12223-12228

    • DOI

      10.1021/acscatal.0c02779

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis, structure, and reactivity of pincer-type iridium complexes having gallyl- and indyl-metalloligands utilizing 2,5-bis(6-phosphino-2-pyridyl)pyrrolide as a new scaffold for metal-metal bonds2019

    • Author(s)
      Takaya Jun、Hoshino Mayuko、Ueki Kanako、Saito Narumasa、Iwasawa Nobuharu
    • Journal Title

      Dalton Transactions

      Volume: 48 Issue: 39 Pages: 14606-14610

    • DOI

      10.1039/c9dt03443a

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Palladium-Catalyzed Visible-Light-Driven Carboxylation of Aryl and Alkenyl Triflates by Using Photoredox Catalysts2019

    • Author(s)
      Shimomaki Katsuya、Nakajima Tomoya、Caner Joaquim、Toriumi Naoyuki、Iwasawa Nobuharu
    • Journal Title

      Organic Letters

      Volume: 21 Issue: 12 Pages: 4486-4489

    • DOI

      10.1021/acs.orglett.9b01340

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Development of N‐Phosphinomethyl‐Substituted NHC‐Nickel(0) Complexes as Robust Catalysts for Acrylate Salt Synthesis from Ethylene and CO22019

    • Author(s)
      Takahashi Kohei、Cho Kinryo、Iwai Asaki、Ito Tatsuyoshi、Iwasawa Nobuharu
    • Journal Title

      Chemistry - A European Journal

      Volume: 25 Issue: 59 Pages: 13504-13508

    • DOI

      10.1002/chem.201903625

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Improved Conditions for the Visible-Light Driven Hydrocarboxylation by Rh(I) and Photoredox Dual Catalysts Based on the Mechanistic Analyses2019

    • Author(s)
      Murata Kei、Numasawa Nobutsugu、Shimomaki Katsuya、Takaya Jun、Iwasawa Nobuharu
    • Journal Title

      Frontiers in Chemistry

      Volume: 7 Pages: 371-371

    • DOI

      10.3389/fchem.2019.00371

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Stabilized Gallylene in a Pincer‐Type Ligand: Synthesis, Structure, and Reactivity of PGaIP‐Ir Complexes2019

    • Author(s)
      Saito Narumasa、Takaya Jun、Iwasawa Nobuharu
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 58 Issue: 29 Pages: 9998-10002

    • DOI

      10.1002/anie.201904968

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reactivity of Ruthenium(0) Complex Bearing a Tetradentate Phosphine Ligand: Applications to Catalytic Acrylate Salt Synthesis from Ethylene and CO22019

    • Author(s)
      T. Ito, K. Takahashi, N. Iwasawa
    • Journal Title

      Organometallics

      Volume: 38 Issue: 2 Pages: 205-209

    • DOI

      10.1021/acs.organomet.8b00789

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis, Structure, and Reactivity of a Mononuclear η2-(Ge-H)palladium(0) Complex Bearing a PGeP-Pincer Type Ligand: Reactivity Differences Between Silicon and Germanium2018

    • Author(s)
      J. Takaya, N. Iwasawa
    • Journal Title

      Eur. J. Inorg. Chem.

      Volume: 2018 Issue: 46 Pages: 5012-5018

    • DOI

      10.1002/ejic.201801257

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Metallic Reductant-Free Synthesis of α-Substituted Propionic Acid Derivatives through Hydrocarboxylation of Alkenes with Formate Salt2017

    • Author(s)
      Takaya, J.; Miyama, K.; Zhu, C.; Iwasawa, N.
    • Journal Title

      Chem. Commun.

      Volume: 53 Issue: 28 Pages: 3982-3985

    • DOI

      10.1039/c7cc01377a

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Synthesis, Structure, and Catalysis of Palladium Complexes Bearing a Group 13 Metalloligand: Remarkable Effect of an Aluminum-Metalloligand in Hydrosilylation of CO22017

    • Author(s)
      Takaya Jun、Iwasawa Nobuharu
    • Journal Title

      Journal of the American Chemical Society

      Volume: 139 Issue: 17 Pages: 6074-6077

    • DOI

      10.1021/jacs.7b02553

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Visible Light-Driven Carboxylation of Aryl Halides by the Combined Use of Palladium and Photoredox Catalysts2017

    • Author(s)
      K. Shimomaki, K. Murata, R. Martin, N. Iwasawa
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 139 Issue: 28 Pages: 9467-9470

    • DOI

      10.1021/jacs.7b04838

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] Hemilabileな四座配位子を有するルテニウム錯体の開発とその触媒活性2022

    • Author(s)
      廖 宇萌、平高 遥、高橋 講平、岩澤 伸治
    • Organizer
      日本化学会第102春季年会
    • Related Report
      2021 Annual Research Report
  • [Presentation] ニッケララクトンの光活性化を利用したエチレンと二酸化炭素からの触媒的メチルマロン酸塩合成2022

    • Author(s)
      櫻澤 裕二、岩井 朝希、高橋 講平、岩澤 伸治
    • Organizer
      日本化学会第102春季年会
    • Related Report
      2021 Annual Research Report
  • [Presentation] Visible Light Induced C-H Bond Activation of Arenes by PSP-Pincer Rhodium Hydride Complexes2022

    • Author(s)
      Yanzong Lyu, Naoyuki Toriumi, Nobuharu Iwasawa
    • Organizer
      日本化学会第102春季年会
    • Related Report
      2021 Annual Research Report
  • [Presentation] 水素と二酸化炭素を用いたロジウム/ルテニウム二元触媒系によるスチレン類のヒドロカルボキシル化反応の開発2022

    • Author(s)
      鳥海 尚之、 Yushu Jin、 Joaquim Caner、西川 真太郎、岩澤 伸治
    • Organizer
      日本化学会第102春季年会
    • Related Report
      2021 Annual Research Report
  • [Presentation] 水素と二酸化炭素を用いたスチレン類の光ヒドロカルボキシル化反応の機構解析2022

    • Author(s)
      西川 真太郎、Yushu Jin、 Joaquim Caner、鳥海 尚之、 岩澤 伸治
    • Organizer
      日本化学会第102春季年会
    • Related Report
      2021 Annual Research Report
  • [Presentation] ルテニウム-パラジウム二核錯体を光触媒とする二酸化炭素還元反応2021

    • Author(s)
      楊 斯騰・小川 功喜 ・鷹谷 絢・岩澤 伸治
    • Organizer
      第67回有機金属化学討論会
    • Related Report
      2021 Annual Research Report
  • [Presentation] ニッケララクトンの光活性化を利用したエチレンと二酸化炭素からの触媒的メチルマロン酸塩の合成2021

    • Author(s)
      櫻澤 裕二・岩井 朝希・高橋 講平・岩澤 伸治
    • Organizer
      第67回有機金属化学討論会
    • Related Report
      2021 Annual Research Report
  • [Presentation] Rhodium-catalyzed meta-Selective Carboxylation Reaction of 1,1-Diarylethylenes via Hydrorhodation-Rhodium Migration2020

    • Author(s)
      T. Saitou, N. Toriumi, N. Iwasawa
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] ルテニウムを配位子とする後周期遷移金属錯体の合成と反応2020

    • Author(s)
      中村優太、斉藤成将、鷹谷 絢、岩澤伸治
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] ピンサー型ガリレン配位子を持つロジウム錯体によるニトリルの化学選択的ヒドロシリル化反応2020

    • Author(s)
      小川功喜、中屋良太、鷹谷 絢、岩澤伸治
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] ホスフィノメチル基の置換したNHC配位子を有するニッケララクトンの光反応性2020

    • Author(s)
      岩井朝希、高橋講平、岩澤伸治
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 四座ホスフィン配位子を有する 0価ルテニウム錯体を触媒とするアリルエーテルを用いた求電子的アリル化反応2020

    • Author(s)
      渡辺 雄太、平高 遥、高橋講平、岩澤伸治
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Clarification of the Nucleophilic Species in the Carboxylation of Aryl (Pseudo)Halides with CO2 using Pd/Photoredox Dual Catalysts2020

    • Author(s)
      J. Caner, K. Shimomaki, K. Murata, N. Toriumi, R. Martin, N. Iwasawa
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 可視光エネルギーを利用するカルボキシル化反応の開発2019

    • Author(s)
      岩澤伸治
    • Organizer
      近畿化学協会有機金属部会 2019年度第3回例会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] PSiP-ピンサー型白金錯体と銀塩によるベンゼンのC-H結合変換反応2019

    • Author(s)
      中屋 良太、鷹谷 絢、岩澤 伸治
    • Organizer
      第66回有機金属化学討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 13 族メタリレン含有ピンサー型ロジウム錯体によるニトリルのイミンへの選択的ヒドロシリル化反応2019

    • Author(s)
      小川 功喜、中屋 良太、鷹谷 絢、岩澤 伸治
    • Organizer
      第66回有機金属化学討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 高周期14族元素含有ピンサー型配位子を持つ鉄ー亜鉛複核錯体の合成と反応2019

    • Author(s)
      瀧澤開、三浦律男、伊藤龍好、鷹谷絢、岩澤伸治
    • Organizer
      第36回有機合成化学セミナー
    • Related Report
      2019 Annual Research Report
  • [Presentation] ホスフィノメチル基の置換したNHCーニッケル錯体を用いたエチレンと二酸化炭素からのアクリル酸塩の触媒的合成2019

    • Author(s)
      岩井朝希、張錦良、高橋講平、岩澤伸治
    • Organizer
      第36回有機合成化学セミナー
    • Related Report
      2019 Annual Research Report
  • [Presentation] Pd/Photoredox二元触媒系による二酸化炭素を用いたアリール及びアルケニルトリフラートの可視光駆動型触媒的カルボキシル化反応の開発2019

    • Author(s)
      中島知也、本田純、Joaquim Caner、鳥海尚之、岩澤伸治
    • Organizer
      第36回有機合成化学セミナー
    • Related Report
      2019 Annual Research Report
  • [Presentation] 6,6”-ビスホスフィノテルピリジンを多座配位子とするルテニウム-後周期遷移金属二核錯体の合成、構造、反応性2019

    • Author(s)
      中村 優太, 斉藤 成将, 鷹谷 絢, 岩澤 伸治
    • Organizer
      錯体化学会 第69回討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] ホスフィノメチル基の置換したNHC-ニッケル錯体を用いたエチレンと二酸化炭素からのアクリル酸塩の触媒的合成2019

    • Author(s)
      岩井朝希、張錦良、高橋講平、岩澤伸治
    • Organizer
      第115回有機合成シンポジウム
    • Related Report
      2019 Annual Research Report
  • [Presentation] Reductants for Carboxylation Reactions2018

    • Author(s)
      N. Iwasawa
    • Organizer
      The 8th International Forum on Homogeneous Catalysis
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Visible-light Driven Carboxylation Reactions2018

    • Author(s)
      N. Iwasawa
    • Organizer
      43rd International Conference on Coordination Chemistry
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Development of Visible Light-Driven Hydrocarboxylation of Alkenes by the Rh(I) and Photoredox Catalysts2018

    • Author(s)
      K. Murata, N. Numasawa, K. Shimomaki, J. Takaya, N. Iwasawa,
    • Organizer
      43rd International Conference on Coordination Chemistry
    • Related Report
      2018 Annual Research Report
  • [Presentation] PSiP-Platinum Complexes-Promoted C-H Bond Activation and Transformation of Benzene2018

    • Author(s)
      R. Nakaya, J. Takaya, N. Iwasawa,
    • Organizer
      43rd International Conference on Coordination Chemistry
    • Related Report
      2018 Annual Research Report
  • [Presentation] Ruthenium-catalyzed Synthesis of Acrylic Acid from Ethylene and CO22018

    • Author(s)
      T. Ito, K. Takahashi, N. Iwasawa,
    • Organizer
      The 4th International Symposium on C-H Activation
    • Related Report
      2018 Annual Research Report
  • [Presentation] Ruthenium-catalyzed Synthesis of Acrylic Acid from Ethylene and CO22018

    • Author(s)
      T. Ito, K. Takahashi, N. Iwasawa,
    • Organizer
      The 14th International Kyoto Conference on New Aspects of Organic Chemistry
    • Related Report
      2018 Annual Research Report
  • [Presentation] Al-Pd二核錯体を触媒とする高効率的ヒドロシリル化反応2018

    • Author(s)
      鷹谷絢、塩塚朗、斉藤成将、 岩澤伸治
    • Organizer
      第65回有機金属化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] N-ホスフィノメチル置換 NHC 配位子を有するニッケル触媒を用いたエチレンと二酸化炭素からのアクリル酸塩の効率的合成2018

    • Author(s)
      高橋講平、張錦良、岩井朝希、岩澤伸治
    • Organizer
      第65回有機金属化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 四座配位子を持つルテニウム錯体を用いたエチレンと二酸化炭素からのアクリル酸合成の効率化2018

    • Author(s)
      平高遥、伊藤龍好、高橋講平、岩澤伸治
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] ホスフィノメチル基の置換したNHC-ニッケル錯体を用いたエチレンと二酸化炭素からのアクリル酸塩の触媒的合成2018

    • Author(s)
      岩井朝希、張錦良、高橋講平、岩澤伸治
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Pd/Photoredox 二元触媒系による二酸化炭素を用いたアリール及びアルケニルトリフラートの可視光駆動型カルボキシル化反応の開発2018

    • Author(s)
      中島知也、本田純、Caner Joaquim、鳥海尚之、岩澤伸治
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 低原子価13族金属含有ピンサー型配位子を持つ9族金属ヒドリド錯体の合成と反応2018

    • Author(s)
      星野麻由子、植木加奈子、鷹谷絢、岩澤伸治
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 可視光エネルギーを利用した遷移金属種を用いない二酸化炭素固定化反応の開発2018

    • Author(s)
      本田純、下牧克也、鳥海尚之、岩澤伸治
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 高周期14族元素含有ピンサー型配位子を持つ鉄-亜鉛複核錯体の合成と反応2018

    • Author(s)
      瀧澤開,三浦律男、伊藤龍好、鷹谷絢、岩澤伸治
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Ruthenium-catalyzed Synthesis of Acrylic Acid from Ethylene and CO22018

    • Author(s)
      Tatsuyoshi Ito, Kohei Takahashi, Nobuharu Iwasawa
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 高周期14族元素含有ピンサー型配位子を持つ白金錯体の合成と反応2018

    • Author(s)
      中屋 良太、鷹谷 絢、岩澤 伸治
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Al-Pd二核錯体を触媒とするヒドロシリル化反応の開発2018

    • Author(s)
      塩塚 朗、斉藤 成将、鷹谷 絢、岩澤 伸治
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] PGeP-ピンサー型配位子を有するレニウム錯体によるアレンのヒドロホウ素化反応2018

    • Author(s)
      村上 桃香、杉本 忠大、鷹谷 絢、岩澤 伸治
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ロジウム (I) 及びレドックス光増感剤を触媒として用いる可視光駆動型ヒドロカルボキシル化反応の効率化2018

    • Author(s)
      沼澤 宣次、下牧 克也、村田 慧、岩澤 伸治
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Visible-light Driven Carboxylation Reactions2017

    • Author(s)
      Nobuharu Iwasawa
    • Organizer
      1st Singapore Japan Germany Trilateral Symposium on Precision Synthesis & Catalysis
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 遷移金属錯体触媒を用いるカルボキシル化反応の開発2017

    • Author(s)
      岩澤伸治
    • Organizer
      第28回グリーンケミストリーフォーラム
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] PSiP-ピンサー型パラジウム錯体を用いる有機合成反応の開発2017

    • Author(s)
      岩澤伸治
    • Organizer
      第21回ケイ素化学協会シンポジウム
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 可視光エネルギーを利用するカルボキシル化反応2017

    • Author(s)
      岩澤伸治
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Synthesis, Structure and Reactivity of Iridium Complexes Having a Gallium-Containing Pincer Type Ligand2017

    • Author(s)
      Narumasa Saito, Jun Takaya, Nobuharu Iwasawa
    • Organizer
      19th INTERNATIONAL SYMPOSIA ON ORGANOMETALLIC CHEMISTRY DIRECTED TOWARDS ORGANIC SYNTHESIS (OMCOS 19)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Visible Light-Driven Carboxylation of Aryl Halides by the Combined Use of Pd and Photoredox Catalysts2017

    • Author(s)
      Katsuya Shimomaki, Kei Murata, Nobuharu Iwasawa
    • Organizer
      19th INTERNATIONAL SYMPOSIA ON ORGANOMETALLIC CHEMISTRY DIRECTED TOWARDS ORGANIC SYNTHESIS (OMCOS 19)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis, Structure, and Catalysis of Palladium Complexes Bearing a Group 13 Metalloligand: Remarkable Effect of an Al-Metalloligand in Hydrosilylation of CO22017

    • Author(s)
      Jun Takaya, Nobuharu Iwasawa
    • Organizer
      19th INTERNATIONAL SYMPOSIA ON ORGANOMETALLIC CHEMISTRY DIRECTED TOWARDS ORGANIC SYNTHESIS (OMCOS 19)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] パラジウム及び光酸化還元触媒を用いるハロゲン化アリールの可視光駆動型カルボキシル化反応2017

    • Author(s)
      下牧 克也、村田 慧、マーティン ルーベン、岩澤 伸治
    • Organizer
      第64回有機金属化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 13族金属含有ピンサー型配位子を持つイリジウム 錯体の合成とその構造と反応性2017

    • Author(s)
      斉藤 成将、鷹谷 絢、岩澤 伸治
    • Organizer
      第64回有機金属化学討論会
    • Related Report
      2017 Annual Research Report
  • [Book] "Transition-Metal-Catalyzed C-H Carboxylation" in "CO2 as a Building Block in Organic Synthesis"2020

    • Author(s)
      Joaquim Caner, Nobuharu Iwasawa
    • Total Pages
      35
    • Publisher
      Wiley-VCH
    • Related Report
      2020 Annual Research Report
  • [Patent(Industrial Property Rights)] 二酸化炭素と芳香族ハロゲン化合物とから芳香族カルボン酸又はそのエステルを製造するための触媒組成物2018

    • Inventor(s)
      岩澤伸治、村田慧、下牧克也、真田有
    • Industrial Property Rights Holder
      岩澤伸治、村田慧、下牧克也、真田有
    • Industrial Property Rights Type
      特許
    • Patent Publication Number
      2019-042708
    • Filing Date
      2018
    • Acquisition Date
      2019
    • Related Report
      2019 Annual Research Report

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Published: 2017-06-01   Modified: 2023-10-16  

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