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Mechanics of chemical reaction induced by stress field in multilayered nano-films

Research Project

Project/Area Number 17H06209
Research Category

Grant-in-Aid for Challenging Research (Pioneering)

Allocation TypeSingle-year Grants
Research Field Mechanics of materials, Production engineering, Design engineering, and related fields
Research InstitutionKyoto University

Principal Investigator

Hirakata Hiroyuki  京都大学, 工学研究科, 教授 (40362454)

Co-Investigator(Kenkyū-buntansha) 近藤 俊之  大阪大学, 工学研究科, 助教 (70735042)
Project Period (FY) 2017-06-30 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥26,000,000 (Direct Cost: ¥20,000,000、Indirect Cost: ¥6,000,000)
Fiscal Year 2019: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2018: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2017: ¥18,980,000 (Direct Cost: ¥14,600,000、Indirect Cost: ¥4,380,000)
Keywordsナノ・マイクロ材料力学 / 応力誘起化学反応 / ナノ薄膜 / 材料力学
Outline of Final Research Achievements

When a force is locally applied to multilayered nanofilms in which two types of materials with a thickness of 10 nm order are alternately laminated, a chemical reaction occurs, and a compound is generated. However, the detailed mechanism of the stress-induced chemical reaction has not been elucidated. In this study, we have developed in-situ electron microscopy loading methods for Ti/Si multilayered nanofilms in which the ratio of normal to shear stresses can be precisely controlled. The experimental results determined the microscopic mechanisms of stress-induced chemical reactions and their dependence on deformation modes. This shows the possibility of controlling local chemical reactions by mechanical loading.

Academic Significance and Societal Importance of the Research Achievements

本研究成果は,多層ナノ構造から化合物が生成される化学反応に対する応力の役割を解明したことにより,変形や破壊のみを対象とした従来の材料力学の枠組みを越えた新しい学術分野を切り拓くものである.また,局所の応力場を制御することにより,化学反応の生じる領域形態や寸法,および反応の程度を制御できることから,ナノマイクロデバイスの構造作製と機能創製に進歩をもたらすものである.

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (8 results)

All 2019 2018 2017

All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (7 results) (of which Int'l Joint Research: 2 results)

  • [Journal Article] Plastic deformation dominates chemical reactions in Ti/Si multilayered nanofilms2018

    • Author(s)
      Hirakata Hiroyuki、Kawai Takashi、Kondo Toshiyuki、Minoshima Kohji
    • Journal Title

      Materials Science and Engineering: A

      Volume: 737 Pages: 105-114

    • DOI

      10.1016/j.msea.2018.09.031

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Presentation] Ti/Si多層ナノ薄膜のせん断負荷による化学反応メカニズム2019

    • Author(s)
      濵口高征, 白石貴裕, 嶋田隆広, 平方寛之
    • Organizer
      日本機械学会M&M2019材料力学カンファレンス, 九州大学
    • Related Report
      2019 Annual Research Report
  • [Presentation] Stress-induced chemical reaction of Ti/Si multilayered nano-films2018

    • Author(s)
      Hiroyuki HIRAKATA, Takashi KAWAI, Toshiyuki KONDO and Kohji MINOSHIMA
    • Organizer
      2018 MRS Fall Meeting and Exhibits
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Shear deformation induces localized chemical reaction of Ti/Si multilayered nanofilms2018

    • Author(s)
      Takahiro SHIRAISHI, Kazumasa TOKUNAKA, Takahiro SHIMADA and Hiroyuki HIRAKATA
    • Organizer
      15th Asia-Pacific Conference on Fracture and Strength (APCFS2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Ti/Si多層ナノ薄膜の応力誘起化合物生成反応の力学的評価2018

    • Author(s)
      徳中一将, 白石貴裕, 嶋田隆広, 平方寛之
    • Organizer
      日本材料学会第4回材料WEEK材料シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] Ti/Si 多層ナノ薄膜の変形誘起化学反応2018

    • Author(s)
      白石貴裕,徳中一将,嶋田隆広,平方寛之
    • Organizer
      日本機械学会2018年度年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Ti/Si多層ナノ薄膜における応力誘起化学反応条件の検討2018

    • Author(s)
      河合貴志, 近藤俊之, 平方寛之, 箕島弘二
    • Organizer
      日本機械学会関西支部第93期定時総会講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Ti/Si 多層ナノ薄膜の応力誘起化学反応開始の力学条件2017

    • Author(s)
      河合貴志, 近藤俊之, 平方寛之, 箕島弘二
    • Organizer
      日本機械学会M&M2017材料力学シンポジウム
    • Related Report
      2017 Annual Research Report

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Published: 2017-07-21   Modified: 2021-02-19  

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