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Lead-free piezoelectric device development by sol-gel composite

Research Project

Project/Area Number 17H06965
Research Category

Grant-in-Aid for Research Activity Start-up

Allocation TypeSingle-year Grants
Research Field Measurement engineering
Research InstitutionKumamoto University

Principal Investigator

Kobayashi Makiko  熊本大学, 大学院先端科学研究部(工), 准教授 (90629651)

Project Period (FY) 2017-08-25 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2018: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2017: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Keywords非鉛 / 圧電 / 超音波 / 複合材料 / 薄膜 / 圧電材料 / 高温 / 分極 / 電子・電気材料 / セラミックス / 複合材料・物性 / モニタリング / パルス電源
Outline of Final Research Achievements

New lead-free piezoelectric materials have been developed by combination of lead-free , low dielectric constant, and high piezoelectric constant powder phase and lead-free and high dielectric constant sol-gel phase. As a result, lead-free ultrasonic devices with superior ultrasonic properties and high temperature durability have been successfully developed. Since spontaneous polarization directions of powder phase in sol-gel composite films are random, the devices cannot present piezoelectric performance without poling process. During poling process, high electrical field is applied to piezoelectric film so that polarization directions will be aligned. In this research, poling conditions have been also optimized and LiNbO3 based material with very high coercive field and poling difficulty has been poled efficiently and ultrasonic performance at 1000 degreeC was successfully demonstrated.

Academic Significance and Societal Importance of the Research Achievements

圧電粉体相、ゾルゲル相、空孔相の3つの相から構成される複合材料により、非鉛で高性能な超音波デバイスの開発に成功しました。また、分極困難とされていたニオブ酸リチウムの効率的な分極に成功しました。今後よりいっそう研究を進めることにより、圧電材料の非鉛化を推進させ、作製中の環境汚染や作製者への健康被害の可能性を低減させることはもとより、開発に成功した非鉛高温超音波デバイスは長期における使用においても測定物を加速酸化による劣化を生じさせないため、実用化に近づいたといえます。

Report

(3 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Annual Research Report
  • Research Products

    (14 results)

All 2018 2017

All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (11 results) (of which Int'l Joint Research: 10 results,  Invited: 1 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] CaBi4Ti4O15-based lead-free sol-gel composites for high-temperature application2018

    • Author(s)
      Yamamoto Tomoya、Kobayashi Makiko
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 57 Issue: 7S1 Pages: 07LB16-07LB16

    • DOI

      10.7567/jjap.57.07lb16

    • NAID

      210000149283

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Presentation] High temperature properties of LiNbO3/Bi4Ti3O122018

    • Author(s)
      M. Yugawa, T. Yamamoto and M. Kobayashi
    • Organizer
      Symposium on Ultrasonic Electronics
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Low temperature fabrication of Bi4Ti3O12/TiO22018

    • Author(s)
      S. Nozawa, T. Yamamoto, M. Furukawa and M. Kobayashi
    • Organizer
      Symposium on Ultrasonic Electronics
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] High temperature properties of CaBi2Ta2O9/Bi4Ti3O122018

    • Author(s)
      T. Yamamoto, S. Nozawa, M. Furukawa and M. Kobayashi
    • Organizer
      Symposium on Ultrasonic Electronics
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Bi4Ti3O12/Al2O3 sol-gel composite ultrasonic transducer2018

    • Author(s)
      K. Okada, T. Yamamoto, M. Yugawa, M. Furukawa and M. Kobayashi
    • Organizer
      Symposium on Ultrasonic Electronics
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] New Lead-Free Bi4Ti3O12 Based Sol-Gel Composites for Ultrasonic Transducers2018

    • Author(s)
      S. Nozawa, T. Yamamoto and M. Kobayashi
    • Organizer
      IEEE International Ultrasonics Symposium
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Bi4Ti3O12/SrTiO3 sol-gel composite for ultrasonic transducers2018

    • Author(s)
      S. Nozawa, T. Yamamoto and M. Kobayashi
    • Organizer
      2018 IEEE ISAF-FMA-AMF-AMEC-PFM Joint Conference
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] High temperature properties of CaBi4Ti4O15/Ba0.7Sr0.3TiO32017

    • Author(s)
      T. Yamamoto, K. Kiyofuji, M. Yugawa, and M. Kobayashi
    • Organizer
      Symposium on Ultrasonic Electronics
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] High temperature properties of CaBi4Ti4O15/Bi4Ti3O122017

    • Author(s)
      K. Okada, T. Yamamoto, M. Yugawa and M. Kobayashi
    • Organizer
      Symposium on Ultrasonic Electronics
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Bi4Ti3O12 based lead-free sol-gel composite ultrasonic transducers2017

    • Author(s)
      M. Yugawa, T. Yamamoto, and M. Kobayashi
    • Organizer
      Symposium on Ultrasonic Electronics
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Poling condition optimization for CaBi4Ti4O15/Pb(Zr, Ti)O3 sol-gel composite2017

    • Author(s)
      M. Hurukawa, M. Yugawa, T. Yamamoto, H. Kouyama, T. Namihira, and M. Kobayashi
    • Organizer
      Symposium on Ultrasonic Electronics
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 広帯域超音波トランスデューサ応用ゾルゲル複合体厚膜材料2017

    • Author(s)
      小林牧子,清藤和穂,山本智也,湯川雅己
    • Organizer
      日本音響学会2017年秋季研究発表会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Patent(Industrial Property Rights)] 基板及び膜基板生産方法2018

    • Inventor(s)
      小林牧子 中妻啓 田邉将之
    • Industrial Property Rights Holder
      小林牧子 中妻啓 田邉将之
    • Industrial Property Rights Type
      特許
    • Filing Date
      2018
    • Related Report
      2018 Annual Research Report
  • [Patent(Industrial Property Rights)] 膜基板生産方法2017

    • Inventor(s)
      小林 牧子,中妻 啓,田邉 将之
    • Industrial Property Rights Holder
      小林 牧子,中妻 啓,田邉 将之
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2017-114694
    • Filing Date
      2017
    • Related Report
      2017 Annual Research Report

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Published: 2017-08-25   Modified: 2020-03-30  

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