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Modeling and suppression of the striation formation arising during spincoating of photoresist films

Research Project

Project/Area Number 17H07158
Research Category

Grant-in-Aid for Research Activity Start-up

Allocation TypeSingle-year Grants
Research Field Fluid engineering
Research InstitutionTokyo City University

Principal Investigator

Shiratori Suguru  東京都市大学, 工学部, 講師 (10803447)

Project Period (FY) 2017-08-25 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2018: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2017: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Keywords液膜塗布 / 流れの安定性 / マランゴニ効果 / 膜厚測定 / 流体工学 / 製造プロセス / 薄膜流れ / 流れの不安定性
Outline of Final Research Achievements

This work is aimed at obtaining the guideline to avoid /suppress the so-called "striation" which is radial spoke-like thickness undulation generated during spin-coating of resist films, by elucidating the formation mechanism thereof. From the linear stability analysis, time evolution calculation, and real-time measurement of film thickness change during spin coating, the formation mechanism of striation is a derivative form of the well-known solutal Marangoni-Benard instability. As a guideline for the solvent selection, solvents of low vapor pressure and/or small surface-tension difference are preferable. In addition, it was found that adjusting an initial concentration could suppress the striation.

Academic Significance and Societal Importance of the Research Achievements

従来の研究では、流れの安定性解析は極めて単純な流れ場に対してしか行われてこなかった。本研究は、この理論・方法論を産業応用職の強い分野に適用した点に学術的特色がある。また、社会的には、膜厚ムラの回避・抑制指針として、専門分野の異なる技術者でも一般的に入手しやすい情報に基づいた指針を提供した点に意義がある。

Report

(3 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Annual Research Report
  • Research Products

    (5 results)

All 2018 2017

All Journal Article (1 results) Presentation (4 results) (of which Int'l Joint Research: 1 results)

  • [Journal Article] 遠心力場での液膜流れに関する線形安定性解析2017

    • Author(s)
      白鳥 英,島野 健仁郎,永野 秀明
    • Journal Title

      ながれ

      Volume: 36 Pages: 371-375

    • Related Report
      2017 Annual Research Report
  • [Presentation] Linear stability analysis on liquid film flow on the rotating disc2018

    • Author(s)
      Suguru Shiratori, Hideaki Nagano and Kenjiro Shimano
    • Organizer
      12th European Fluid Mechanics Conference
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 回転基板上の液膜流れにおけるマランゴニ数の過渡変化2018

    • Author(s)
      白鳥 英,永野 秀明,島野 健仁郎
    • Organizer
      日本流体力学会 年会2018
    • Related Report
      2018 Annual Research Report
  • [Presentation] 遠心力場での液膜流れに関する線形安定性解析2017

    • Author(s)
      白鳥 英,島野 健仁郎,永野 秀明
    • Organizer
      日本流体力学会年会2017
    • Related Report
      2017 Annual Research Report
  • [Presentation] 薄液膜の塗布時に発生する放射状スジムラの形成機構2017

    • Author(s)
      白鳥 英,永野 秀明,島野 健仁郎
    • Organizer
      日本マイクログラビティ応用学会第29回学術講演会
    • Related Report
      2017 Annual Research Report

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Published: 2017-08-25   Modified: 2020-03-30  

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