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Precious Measurement of Thermoelectric Performances of single crystals using AC Harman Method

Research Project

Project/Area Number 17H07399
Research Category

Grant-in-Aid for Research Activity Start-up

Allocation TypeSingle-year Grants
Research Field Inorganic materials/Physical properties
Research InstitutionNational Institute of Advanced Industrial Science and Technology

Principal Investigator

Okawa Kenjiro  国立研究開発法人産業技術総合研究所, 計量標準総合センター, 研究員 (80805119)

Research Collaborator AMAGAI Yasutaka  
Project Period (FY) 2017-08-25 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2018: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2017: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Keywords熱電発電 / 精密計測 / 交流ハーマン法 / 熱電材料 / 熱電効果 / 単結晶 / 電気標準
Outline of Final Research Achievements

A method to obtain the zT is the Harman method, which can directly estimate zT through AC and DC voltage measurements using zT = (VDC -VAC / VAC). In the actual experiment, the estimated value of zT deviates from the ideal value because this formula is based on the assumption of an adiabatic condition. There have been only a few studies on the quantitative correction.
Here, in order to accurately determine zT using the Harman method, we performed thermal analysis using the heat conduction equation, which is based on the Fourier law. We developed the thermal correction using the one-dimensional heat conduction model, considered as heat losses of convection, Joule heating, Thomson heating, and conduction through lead wires. From this analysis, the temperature distribution in the sample was investigated. Our results indicate that a correction factor for each heat loss should be added to the original formula for highly accurate Harman measurement.

Academic Significance and Societal Importance of the Research Achievements

未利用熱のうち300℃以下の低温域の未利用熱は膨大であり、産業分野のみで日本の年間総発電量を上回ると言われ、その積極的な利用が求められている。熱電発電技術は廃熱を直接電気エネルギーに変換する技術であり、産業界での潜在的なニーズは高く、省エネのため自動車部品やloT 用のセンサ電源への普及が進めば大きな波及効果が期待される。その一方で、熱電材料の評価には様々な測定手法が使われており統一された規格がない。本研究では、簡便な電気的評価法として有望な交流ハーマン法の高精度化に取り組んだ。正確な評価法の確立は、将来的な新材料の効率的な探索、信頼性評価、デバイスの効率評価応用へと繋がることが期待される。

Report

(3 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Annual Research Report
  • Research Products

    (18 results)

All 2019 2018 2017

All Journal Article (8 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 8 results,  Open Access: 1 results) Presentation (10 results) (of which Int'l Joint Research: 6 results)

  • [Journal Article] A general route to form topologically-protected surface and bulk Dirac fermions along high-symmetry lines2019

    • Author(s)
      Clark O J、Mazzola F、Markovic I、Riley J M、Feng J、Yang B-J、Sumida K、Okuda T、Fujii J、Vobornik I、Kim T K、Okawa K、Sasagawa T、Bahramy M S、King P D C
    • Journal Title

      Electronic Structure

      Volume: 1 Issue: 1 Pages: 014002-014002

    • DOI

      10.1088/2516-1075/ab09b7

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Establishment of High-Voltage AC-DC Voltage Transfer Standards in 1-100-kHz Range at NMIJ2019

    • Author(s)
      Fujiki Hiroyuki、Amagai Yasutaka、Okawa Kenjiro
    • Journal Title

      IEEE Transactions on Instrumentation and Measurement

      Volume: 68 Issue: 6 Pages: 1921-1926

    • DOI

      10.1109/tim.2018.2877858

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Low-Frequency AC-DC Differences of a Series-Parallel Circuit of Thermal Converters2019

    • Author(s)
      Amagai Yasutaka、Fujiki Hiroyuki、Okawa Kenjiro、Kaneko Nobu-Hisa
    • Journal Title

      IEEE Transactions on Instrumentation and Measurement

      Volume: 68 Issue: 6 Pages: 1907-1912

    • DOI

      10.1109/tim.2018.2882929

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] フレキシブルプリント回路基板上にビスマス・テルル焼結体を高密度実装したフレキシブル熱電モジュール2019

    • Author(s)
      天谷 康孝、大川 顕次郎 金子 普久
    • Journal Title

      ファインセラミックスレポート(FCレポート)

      Volume: 37 Pages: 51-55

    • NAID

      40021890098

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Extremely Large Magnetoresistance induced by Hidden Three-dimentional Dirac Bands in Non-magnetic Semimetal InBi2018

    • Author(s)
      K. Okawa, M. Kanou, H. Namiki, and T. Sasagawa
    • Journal Title

      Phys. Rev. Mater.

      Volume: 2 Issue: 12

    • DOI

      10.1103/physrevmaterials.2.124201

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Development of Thin-Film Resistors Fabricated on an A1N Substrate for High-Voltage AC-DC Transfer Standards2018

    • Author(s)
      Fujiki H.、Amagai Y.、Okawa K.
    • Journal Title

      2018 Conference on Precision Electromagnetic Measurements (CPEM 2018)

      Volume: - Pages: 1-6

    • DOI

      10.1109/cpem.2018.8500961

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Improved Power Coefficient of Sensitivity in a Series-Parallel Circuit of Thermal Converters2018

    • Author(s)
      Amagai Yasutaka、Fujiki Hiroyuki、Okawa Kenjiro
    • Journal Title

      2018 Conference on Precision Electromagnetic Measurements (CPEM 2018)

      Volume: - Pages: 1-6

    • DOI

      10.1109/cpem.2018.8500874

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fermiology and Superconductivity of Topological Surface States in PdTe22018

    • Author(s)
      O.J. Clark, M.J. Neat, K. Okawa, L. Bawden, I. Markovic, F. Mazzola, J. Feng, V. Sunko, J.M. Riley, W. Meevasana, J. Fujii, I. Vobornik, T.K. Kim, M. Hoesch, T. Sasagawa, P. Wahl, M.S. Bahramy, and P.D.C. King
    • Journal Title

      Phys. Rev. Lett.

      Volume: 120 Issue: 15

    • DOI

      10.1103/physrevlett.120.156401

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] Comparison of Three Accurate Measurement Methods for Measuring the Efficiency in Thermoelectric Modules2018

    • Author(s)
      K. Okawa, Y. Amagai, H. Fujiki
    • Organizer
      37th/16th Internatuinal and European Conference on Themoelectrics (ICT2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Heat Transfer Analysis on the Measurement of Thermoelectric Performances using the Harman Method2018

    • Author(s)
      K. Okawa, Y. Amagai, H. Fujiki
    • Organizer
      37th/16th Internatuinal and European Conference on Themoelectrics (ICT2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Apparatus for Measurement of the Output Power and Efficiency of Flexible Thermoelectric Power Generators2018

    • Author(s)
      Yasutaka Amagai, Hiroyuki Fujiki, Kenjiro Okawa, Yuzo. Tasaki, Keiichi. Ohata, Michio Okajima, and Shutaro. Nambu
    • Organizer
      37th/16th Internatuinal and European Conference on Themoelectrics (ICT2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Direct Current Polarity-Reversal Technique to Measure the Thomson Coefficient to Determine the Absolute Seebeck Coefficient2018

    • Author(s)
      Yasutaka Amagai, Takeshi. Shimazaki, Kenjiro Okawa, and Hiroyuki Fujiki
    • Organizer
      37th/16th Internatuinal and European Conference on Themoelectrics (ICT2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Development of Thin-film Resistors Fabricated on an AlN Substrate for High-Voltage AC-DC Transfer Standards2018

    • Author(s)
      Fujiki H.、Amagai Y.、Okawa K.
    • Organizer
      2018 Conference on Precision Electromagnetic Measurements
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Improved Power Coefficient of Sensitivity in a Series-Parallel Circuit of Thermal Converter2018

    • Author(s)
      Yasutaka Amagai, Hiroyuki Fujiki, Kenjiro Okawa, and Nobu-Hisa Kaneko
    • Organizer
      2018 Conference on Precision Electromagnetic Measurements
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] フレキシブル基板上にビスマス-テルル素子を実装した熱電モジュールの発電性能および耐久性の評価2018

    • Author(s)
      大川顕次郎, 天谷康孝, 藤木弘之, 金子晋久, 土嶺信男, 金子博, 田﨑雄三, 大畑惠一, 岡嶋道生, 南部修太郎
    • Organizer
      第15回日本熱電学会学術講演会(TSJ2018)
    • Related Report
      2018 Annual Research Report
  • [Presentation] 交流ハーマン法を用いた熱電材料評価における熱損失の影響の実証2018

    • Author(s)
      大川顕次郎, 天谷康孝, 藤木弘之, 金子晋久
    • Organizer
      第15回日本熱電学会学術講演会(TSJ2018)
    • Related Report
      2018 Annual Research Report
  • [Presentation] 熱電モジュール性能評価方法の比較2018

    • Author(s)
      大川顕次郎,天谷康孝,藤木弘之
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 交流ハーマン法の熱伝達解析2017

    • Author(s)
      大川顕次郎,天谷康孝,藤木弘之
    • Organizer
      第78回応用物理学会秋季学術講演会
    • Related Report
      2017 Annual Research Report

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Published: 2017-08-25   Modified: 2020-03-30  

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