Development of porous magnets with electron donor/acceptor metal–organic frameworks
| Project/Area Number |
17J02497
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| Research Category |
Grant-in-Aid for JSPS Fellows
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| Allocation Type | Single-year Grants |
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| Section | 国内 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Tohoku University |
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Principal Investigator |
張 俊 東北大学, 理学研究科, 特別研究員(PD)
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| Project Period (FY) |
2017-04-26 – 2020-03-31
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| Project Status |
Completed (Fiscal Year 2019)
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| Budget Amount *help |
¥2,500,000 (Direct Cost: ¥2,500,000)
Fiscal Year 2019: ¥800,000 (Direct Cost: ¥800,000)
Fiscal Year 2018: ¥800,000 (Direct Cost: ¥800,000)
Fiscal Year 2017: ¥900,000 (Direct Cost: ¥900,000)
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| Keywords | Molecular Magnet / Gas Sorption / Electronic State / magnetic sponge / hydrogen bonding / electron transfer / host-guest interaction / theoretical calculation / Curie temperature (Tc) / electronic state |
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| Outline of Annual Research Achievements |
Nowadays, the control of spontaneous magnetization in the molecular magnets has been mainly actualized by photo-irradiation, solvent accommodation, or electrochemical approach. Here, we demonstrate for the first time CO2 can be adsorbed to generate the long-range magnetic order in an electronic-state-flexible layered compound, [{Ru2(2,4-F2PhCO2)4}2TCNQ(OEt)2] (1). The adsorption of CO2 into compound 1 is accompanied by a structural transformation with the bending deflection of TCNQ(OEt)2, which plays an extremely important role in controlling the electronic states. Owing to the reversible change of electronic states by the CO2 adsorption/desorption processes, magnetic phase is switched between antiferromagnetic phase (CO2-adsorbed phase) and paramagnetic phase (CO2-free phase).
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| Research Progress Status |
令和元年度が最終年度であるため、記入しない。
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| Strategy for Future Research Activity |
令和元年度が最終年度であるため、記入しない。
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Report
(3 results)
Research Products
(22 results)
