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Near infrared plasmon-induced hole transfer in the heterostructured semiconductor nanocrystals

Research Project

Project/Area Number 17J09073
Research Category

Grant-in-Aid for JSPS Fellows

Allocation TypeSingle-year Grants
Section国内
Research Field Nanomaterials chemistry
Research InstitutionKyoto University

Principal Investigator

廉 孜超  京都大学, 化学研究所, 特別研究員(PD)

Project Period (FY) 2017-04-26 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥1,900,000 (Direct Cost: ¥1,900,000)
Fiscal Year 2018: ¥900,000 (Direct Cost: ¥900,000)
Fiscal Year 2017: ¥1,000,000 (Direct Cost: ¥1,000,000)
KeywordsHot hole transfer / LSPR / Near infrared light / Laser spectroscopy / Carrier dynamics / H2 evolution / Plasmonic hole transfer / Near-infrared light / Hydrogen evolution
Outline of Annual Research Achievements

The progress of this project has gone well with our expectation. Direct observation of near-infrared (NIR) light-induced plasmonic hot hole transfer was successfully made at a heterointerface in CdS/CuS heterostructured nanocrystals (HNCs). This part was published in the top journal (Z. Lian et al., Nature Commun. 2018, 9, 2314). The CdS/Cu7S4 HNCs with the morphology of heterodimers were successfully synthesized. They formed a novel plasmonic p-n junction, which overcame the ultrafast electron relaxation through hot electron injection and achieved extraordinarily long-lived charge separation (> 273 μs). The CdS/Cu7S4 HNCs exhibited high photocatalytic activity in hydrogen evolution under near- or short-wave infrared light irradiation. This part was published in the top journal (Z. Lian et al., J. Am. Chem. Soc. 2019, 141, 2446-2450). In addition, this article was selected as a Journal Cover Picture.
Next, durian-shaped CdS/ZnSe heterostructured semiconductor nanocrystals (d-CdS/ZnSe NCs) were successfully synthesized and the mechanism of formation processes were well explored. The d-CdS/ZnSe NCs exhibited high activity for H2 evolution due to the ultra-long lived charge separation (> 6.2 ms) and efficient hole transfer to the mesoporous shell. This part was published in a specific journal (Z. Lian et al., J. Phys. Chem. Lett. 2018, 9, 2212-2217).

Research Progress Status

平成30年度が最終年度であるため、記入しない。

Strategy for Future Research Activity

平成30年度が最終年度であるため、記入しない。

Report

(2 results)
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (11 results)

All 2018 2017

All Journal Article (3 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 3 results,  Open Access: 2 results) Presentation (8 results) (of which Int'l Joint Research: 3 results,  Invited: 1 results)

  • [Journal Article] Plasmonic p-n Junction for Infrared Light to Chemical Energy Conversion2018

    • Author(s)
      Lian Zichao, Sakamoto Masanori, Vequizo Junie J. M., Ranasinghe C. S. Kumara, Yamakata Akira, Nagai Takuro, Kimoto Koji, Kobayashi Yoichi, Tamai Naoto, Teranishi Toshiharu
    • Journal Title

      Journal of the American Chemical Society

      Volume: 141 Issue: 6 Pages: 2446-2450

    • DOI

      10.1021/jacs.8b11544

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Near Infrared Light Induced Plasmonic Hot Hole Transfer at a Nano-Heterointerface2018

    • Author(s)
      Z. Lian M. Sakamoto H. Matsunaga J. J. M. Vequizo A. Yamakata M. Haruta H. Kurata W. Ota T. Sato T. Teranishi
    • Journal Title

      Nat. Commun.

      Volume: 9 Issue: 1 Pages: 23141-7

    • DOI

      10.1038/s41467-018-04630-w

    • NAID

      120006488580

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Durian-Shaped CdS@ZnSe Core@Mesoporous-Shell Nanoparticles for Enhanced and Sustainable Photocatalytic Hydrogen Evolution2018

    • Author(s)
      Lian Zichao、Sakamoto Masanori、Kobayashi Yoichi、Tamai Naoto、Ma Jun、Sakurai Tsuneaki、Seki Shu、Nakagawa Tatsuo、Lai Mingwei、Haruta Mitsutaka、Kurata Hiroki、Teranishi Toshiharu
    • Journal Title

      The Journal of Physical Chemistry Letters

      Volume: 9 Issue: 9 Pages: 2212-2217

    • DOI

      10.1021/acs.jpclett.8b00789

    • Related Report
      2018 Annual Research Report 2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Presentation] Lattice Strain Induced Transformation of Interfacial Band Offsets in PbS/CdS Heterodimers2018

    • Author(s)
      Zichao Lian
    • Organizer
      The 98th Annual Meeting of the Chemical Society of Japan
    • Related Report
      2018 Annual Research Report
  • [Presentation] Observation of Near Infrared Light-Induced Plasmonic Hot Hole Transfer in CdS/CuS Heterostructured Nanocrystals2018

    • Author(s)
      Zichao Lian
    • Organizer
      Asian Symposium on Nanoscience & Nanotechnology 2018 (ASNANO2018)
    • Related Report
      2018 Annual Research Report
  • [Presentation] Control of Carrier Dynamics in Durian-Shaped CdS/ZnSe Nanocrystals for Enhanced and Sustainable Photocatalytic H2 Evolution under Visible Light2018

    • Author(s)
      Zichao Lian
    • Organizer
      2018 Spring Meeting of Materials Research Society
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Spectroscopic Observation of Near-Infrared Light Induced Plasmonic Hot Hole Transfer2018

    • Author(s)
      Zichao Lian
    • Organizer
      2018 International Seminar on Advanced Materials Research
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Plasmonic CuS Nanocrystals: Application for Surface Enhanced Raman Scattering Probes2018

    • Author(s)
      Zichao Lian
    • Organizer
      The 26th International Conference on Raman Spectroscopy (ICORS 2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Lattice Strain Induced Transformation of Interfacial Band Offsets in PbS/CdS Heterodimers2018

    • Author(s)
      Zichao Lian, Masanori Sakamoto, Toshiharu Teranishi
    • Organizer
      The 98th CSJ Annual Meeting of the Chemical Society of Japan
    • Related Report
      2017 Annual Research Report
  • [Presentation] Direct Observation of Interfacial Carrier Transfer in Size-Controllable PbS Quantum Dots/CdS Nanorods Heterostructures2017

    • Author(s)
      Zichao Lian, Masanori Sakamoto, Toshiharu Teranishi
    • Organizer
      The 15th Annual Meeting of Society of Nano Science and Technology
    • Related Report
      2017 Annual Research Report
  • [Presentation] Photo-induced carriers transfer in durian-shaped CdS/ZnSe nanocrystals2017

    • Author(s)
      Zichao Lian, Masanori Sakamoto, Toshiharu Teranishi
    • Organizer
      The 5th CMS International Symposium on Photofunctional Chemistry and Molecular Systems
    • Related Report
      2017 Annual Research Report

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Published: 2017-05-25   Modified: 2024-03-26  

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