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Development of an additive-free heavy metal ion recovery method using solid catalyst and magnetic separation

Research Project

Project/Area Number 17K00598
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Environmental engineering and reduction of environmental burden
Research InstitutionOsaka University

Principal Investigator

Akiyama Yoko  大阪大学, 工学研究科, 准教授 (50452470)

Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2019: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2018: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2017: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Keywords汚染質除去技術 / 固体触媒 / 磁気分離 / 有価物回収 / 重金属イオン / マグネタイト / 再生利用 / 水酸化鉄 / 自己触媒反応 / 汚染物質除去
Outline of Final Research Achievements

The purpose of this study is to develop a technique to precipitate heavy metal ions in water as hydroxides or oxides by oxidation reaction by solid catalyst and to recover them for reuse.
Here, divalent iron ions contained in high concentrations in the mine water were removed by a solid catalyst which shows autocatalytic reaction. A maximum iron ion removal rate of more than 90% was obtained by using the solid catalyst derived from iron sulfate. Next, a combination of the gravitational sedimentation and magnetic separation methods was investigated as a separation method for the precipitates. Finally, a sustainable treatment system of mine water that does not rely on an external power source using solar power was proposed.

Academic Significance and Societal Importance of the Research Achievements

本研究の学術的意義は、固体触媒が表面に同じ物質を析出させる自触媒反応を利用した重金属除去手法において、出発物質の異なる固体触媒による触媒性能の違いの機構が明らかになったことである。このことにより、触媒性能を向上させるための触媒調製条件の化学的根拠が明らかになった。一方、社会的意義は、持続可能な重金属除去システムを考案したことである。本研究で最終的に設計した重金属除去システムは、自触媒反応により追加の添加剤が不要であり、ドラム型永久磁石の利用により単純な構造であり、さらに外部電源に頼らず自立した運転が可能なシステムであることから、廃鉱山の抗廃水処理や発展途上国への導入が可能であると考えられる。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Research-status Report
  • 2017 Research-status Report
  • Research Products

    (13 results)

All 2019 2018 2017 Other

All Journal Article (3 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 3 results,  Open Access: 3 results) Presentation (9 results) (of which Int'l Joint Research: 3 results,  Invited: 1 results) Remarks (1 results)

  • [Journal Article] Remediation of Groundwater Contaminated by Heavy Metals Using Magnetic Separation Technique2019

    • Author(s)
      Albino Jose Amosse, Yoko Akiyama
    • Journal Title

      Journal of Physics: Conference Series

      Volume: 1293 Issue: 1 Pages: 012080-012080

    • DOI

      10.1088/1742-6596/1293/1/012080

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Fundamental study on sustainable treatment system of mine water using magnetized solid catalyst2019

    • Author(s)
      Chisato Mukuta,Yoko Akiyama
    • Journal Title

      Progress in Superconductivity and Cryogenics

      Volume: 21 Pages: 15-21

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Remediation of groundwater contaminated by heavy metals using magnetic separation technique2019

    • Author(s)
      A.J.Amosse, Y.Akiyama
    • Journal Title

      Journal of Physics: Conference Series

      Volume: 印刷中

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Presentation] 泥水中における重金属イオンの 微視的動態に関する研究2019

    • Author(s)
      小西佑典,秋山庸子
    • Organizer
      第37回関西界面科学セミナー
    • Related Report
      2019 Annual Research Report
  • [Presentation] Adsorption Behavior of Heavy Metal Ions in Muddy Water -The Possibility of Magnetic Separation for Removal of Cd and As-2019

    • Author(s)
      Y.Akiyama,Y.Konishi
    • Organizer
      The 10th International Forum on Magnetic Force Control
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 泥水中における重金属イオンの微視的動態に関する研究2019

    • Author(s)
      神田香穂子,小西佑典,秋山庸子
    • Organizer
      第18回 2019年度 磁気力制御・磁場応用夏の学校
    • Related Report
      2019 Annual Research Report
  • [Presentation] 磁気分離を用いた重金属汚染土壌の 減容に関する基礎的研究2019

    • Author(s)
      小西佑典,秋山庸子
    • Organizer
      第5回 関西四国磁性研究会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Fundamental Study on Sustainable Treatment System of Mine Water2018

    • Author(s)
      C.Mukuta, Y.Akiyama
    • Organizer
      The 9th International Forum on Magnetic Force Control, Sep. 3-5, 2018 (Busan,Korea)
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Remediation of groundwater contaminated by heavy metals using magnetic separation technique2018

    • Author(s)
      A.J.Amosse, Y.Akiyama
    • Organizer
      The 31st International Symposium on Superconductivity (ISS2018), Dec.14, 2018(Tsukuba, Japan)
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] 持続可能な坑廃水処理システムの基礎的検討2018

    • Author(s)
      小西佑典、椋田千聖、秋山庸子
    • Organizer
      2018 磁気力制御・磁場応用 夏の学校 2018年9月15日(宇都宮大学)
    • Related Report
      2018 Research-status Report
  • [Presentation] 持続可能な坑廃水処理システムの検討2017

    • Author(s)
      椋田 千聖,秋山 庸子,西嶋 茂宏
    • Organizer
      日本原子力学会 2017秋の大会
    • Related Report
      2017 Research-status Report
  • [Presentation] Remediation of Mining Groundwater Contaminated By Heavy Metals Using Magnetic Separation Technique2017

    • Author(s)
      Albino Amosse, Yoko Akiyama
    • Organizer
      第12回日本磁気科学会年会
    • Related Report
      2017 Research-status Report
  • [Remarks] 量子線生体材料工学領域 重金属グループ

    • URL

      http://www.see.eng.osaka-u.ac.jp/seeqb/seeqb/study/hmr.html

    • Related Report
      2019 Annual Research Report

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Published: 2017-04-28   Modified: 2021-02-19  

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