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Development of highly durable hydrogen separation membranes for the construction of a new hydrogen purification process

Research Project

Project/Area Number 17K00634
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Environmental conscious materials and recycle
Research InstitutionResearch Institute of Innovative Technology for the Earth

Principal Investigator

Ito Fuminori  公益財団法人地球環境産業技術研究機構, その他部局等, 研究員 (10366429)

Co-Investigator(Kenkyū-buntansha) 山田 秀尚  金沢大学, 先端科学・社会共創推進機構, 准教授 (60446408)
Project Period (FY) 2017-04-01 – 2022-03-31
Project Status Completed (Fiscal Year 2021)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2019: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2018: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2017: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywords高分子膜 / 水素分離膜 / 水素精製プロセス / 分離膜 / 吸水剤 / ガスバリア性 / PVA / 吸水性樹脂 / 水素精製 / 分離性能 / 耐久性 / ガス分離膜の開発 / 高圧での性能試験 / 膜内の配合比 / 環境材料
Outline of Final Research Achievements

In order to transition to a hydrogen-based clean energy society in the future, it is necessary to develop new hydrogen refining technologies. This study addressed this issue. In other words, unlike conventional hydrogen purification methods using hydrogen separation membranes, we have developed a new hydrogen purification technology and process that utilizes the gas permeation characteristics of the fabricated polymer membrane.
First, separation membranes made of two types of polymers were fabricated. That is, (1) a membrane capable of preferentially permeating diffusion gas such as H2 and He and (2) a membrane capable of preferentially permeating CO2 were prepared. We proposed a separation technology and process that successfully combines the features of these membranes, and conducted a basic evaluation study. As a result, a new hydrogen purification process with high efficiency was developed.

Academic Significance and Societal Importance of the Research Achievements

水素を中心としたクリーンなエネルギー社会へ移行するためには、新たな水素精製に対する技術開発が必要である。
この課題に対し、本研究では、①安価で高性能、そして高圧領域で耐性を有する高分子系の膜を開発した。次に、②水素精製に向けた新たなプロセスを提案した。そして、③①で開発した高分子系の膜を、②で提案したプロセスに組み込むことで、従来の水素精製プロセスには無かった、新たなアプローチによるプロセスを開発することが出来た。

Report

(6 results)
  • 2021 Annual Research Report   Final Research Report ( PDF )
  • 2020 Research-status Report
  • 2019 Research-status Report
  • 2018 Research-status Report
  • 2017 Research-status Report
  • Research Products

    (26 results)

All 2022 2021 2020 2019 2018 2017

All Journal Article (12 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 10 results) Presentation (13 results) (of which Int'l Joint Research: 5 results,  Invited: 5 results) Book (1 results)

  • [Journal Article] Development of a polyvinyl alcohol/sodium polyacrylate composite polymer membrane with cesium carbonate as a mobile carrier for high-performance CO2 capture2022

    • Author(s)
      Fuminori Ito, Rie Sugimoto, Misato Mori, Hidetaka Yamada
    • Journal Title

      Polymers for Advanced Technologies

      Volume: 33 Issue: 5 Pages: 1677-1684

    • DOI

      10.1002/pat.5630

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] High performance CO2-facilitated transport membrane fabricated by compounding amine-terminated dendrimer in composite of polyvinyl alcohol and water-absorbing agent2021

    • Author(s)
      Fuminori Ito, Yuriko Nishiyama, Rie Sugimoto, Misato Mori, Hidetaka Yamada
    • Journal Title

      Journal of Macromolecular Science, Part A: Pure and Applied Chemistry

      Volume: 58 Issue: 12 Pages: 849-859

    • DOI

      10.1080/10601325.2021.1961589

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effects of the polymer composite composition and amine-based additives on the performance of a polymer composite CO2 separation membrane2021

    • Author(s)
      Fuminori Ito, Yuriko Nishiyama, Shuhong Duan, and Hidetaka Yamada
    • Journal Title

      Polymer Bulletin

      Volume: 78 Issue: 1 Pages: 513-528

    • DOI

      10.1007/s00289-020-03122-6

    • Related Report
      2020 Research-status Report
    • Peer Reviewed
  • [Journal Article] CO2-facilitated transport membranes prepared by blending polyvinyl alcohol (PVA) and various water-absorbing agents2021

    • Author(s)
      Fuminori Ito, Yuriko Nishiyama, Rie Sugimoto, Misato Mori, Hidetaka Yamada
    • Journal Title

      J. Applied polymer science

      Volume: 138 Issue: 15 Pages: 50191-50191

    • DOI

      10.1002/app.50191

    • Related Report
      2020 Research-status Report
    • Peer Reviewed
  • [Journal Article] Factors for improving the performance of the separation membranes prepared by the blending of polyvinyl alcohol and a water absorbing agent2021

    • Author(s)
      Fuminori Ito, Yuriko Nishiyama, Rie Sugimoto, Misato Mori, Hidetaka Yamada
    • Journal Title

      Polymer-Plastic Technology and Materials

      Volume: 60 Issue: 6 Pages: 659-669

    • DOI

      10.1080/25740881.2020.1826521

    • Related Report
      2020 Research-status Report
    • Peer Reviewed
  • [Journal Article] Examination of selection and combination of water-absorbing agent to blend with polyvinyl alcohol (PVA) in preparing CO2 separation membrane with high performance2020

    • Author(s)
      Fuminori Ito*, Yuriko Nishiyama, Shuhong Duan, Hidetaka Yamada
    • Journal Title

      Macromolecular Research

      Volume: 28(4) Issue: 4 Pages: 365-372

    • DOI

      10.1007/s13233-020-8043-y

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] CO2固定化・有効利用技術の概要2020

    • Author(s)
      山田秀尚
    • Journal Title

      環境浄化技術

      Volume: 19 Pages: 17-20

    • Related Report
      2019 Research-status Report
  • [Journal Article] Bottom-Up Synthesis of Defect-Free Mixed-Matrix Membranes by Using Polymer-Grafted Metal-Organic Polyhedra2019

    • Author(s)
      Nobuhiko Hosono, Wenbo Guo, Kenichiro Omoto, Hidetaka Yamada, Susumu Kitagawa
    • Journal Title

      Chem. Lett.

      Volume: 48 Issue: 6 Pages: 597-600

    • DOI

      10.1246/cl.190131

    • NAID

      130007659781

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] CO2回収用アミン溶液の反応とその圧力依存性2019

    • Author(s)
      山田秀尚
    • Journal Title

      高圧力の科学と技術

      Volume: 29 Pages: 199-205

    • NAID

      130007723999

    • Related Report
      2019 Research-status Report
  • [Journal Article] Preparation of Biodegradable Polymer Nanospheres Containing Manganese Porphyrin (Mn-Porphyrin)2019

    • Author(s)
      Fuminori Ito, Hidetaka Yamada, Kiyoshi Kanamura, Hiroyoshi Kawakami
    • Journal Title

      Journal of Inorganic and Organometallic Polymers and Materials

      Volume: 29 Issue: 3 Pages: 1010-1018

    • DOI

      10.1007/s10904-018-0991-8

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Development of high-performance polymer membranes for CO2 separation by combining functionalities of polyvinyl alcohol (PVA) and sodium polyacrylate (PAANa)2019

    • Author(s)
      Fuminori Ito, Yuriko Nishiyama, Shuhong Duan, Hidetaka Yamada
    • Journal Title

      Journal of Polymer Research

      Volume: 26 Issue: 5 Pages: 1061-9

    • DOI

      10.1007/s10965-019-1769-6

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Development of CO2 Molecular Gate Membranes for IGCC Process with CO2 Capture2017

    • Author(s)
      Teruhiko Kai, Shuhong Duan, Fuminori Ito, Satoshi Mikami, Yoshinobu Sato, Shin-ichi Nakao
    • Journal Title

      Energy Procedia

      Volume: 114 Pages: 613-620

    • DOI

      10.1016/j.egypro.2017.03.1203

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] Preparation and mnuplation of silver nanostructure with plasmon activity by a simple method2020

    • Author(s)
      A. Hyono, R. Yoshitani, M. Takase, K. Suzuki, F. Ito, and M. Chiba
    • Organizer
      PRiME 2020
    • Related Report
      2020 Research-status Report
    • Int'l Joint Research
  • [Presentation] 銀で修飾したポリスチレン粒子の光学特性2020

    • Author(s)
      吉谷立, 鈴木啓太, 高瀬舞, 伊藤史典, 千葉誠, 兵野篤
    • Organizer
      化学系学協会北海道支部2020年冬季研究発表会
    • Related Report
      2019 Research-status Report
  • [Presentation] 二酸化炭素分離回収用新規材料の開発と実用化展開2020

    • Author(s)
      山田秀尚
    • Organizer
      第32回CES21(Chemical Engineering & Science 21)講演会
    • Related Report
      2019 Research-status Report
    • Invited
  • [Presentation] Simulation of Amine-Based CO2 Capture Using Transition State Theory2019

    • Author(s)
      H. Yamada
    • Organizer
      17th International Conference on Carbon Dioxide Utilization
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] 地球温暖化対策技術開発におけるミクロとマクロの分子科学2019

    • Author(s)
      山田秀尚
    • Organizer
      分離技術会年会2019
    • Related Report
      2019 Research-status Report
    • Invited
  • [Presentation] CO2回収技術の最新動向2019

    • Author(s)
      山田秀尚
    • Organizer
      新化学技術推進協会エネルギー・資源技術部会エネルギー分科会講演会
    • Related Report
      2018 Research-status Report
    • Invited
  • [Presentation] MDシミュレーションによるモノエタノールアミン、ブチルエタノールアミン水溶液の液体構造の解析2018

    • Author(s)
      岡田真紀、藤田拳人、保科貴亮、山田秀尚、辻智也、日秋俊彦
    • Organizer
      第51回日本大学生産工学部学術講演会
    • Related Report
      2018 Research-status Report
  • [Presentation] 量子化学計算と反応速度論によるpH及び基質濃度の追跡シミュレーション2018

    • Author(s)
      山口徹、山田秀尚、眞田昭平、藤原崇幸、堀憲次
    • Organizer
      化学工学会第50回秋季大会
    • Related Report
      2018 Research-status Report
  • [Presentation] 313Kにおけるブチルエタノールアミンおよびメチルジエタノールアミン水溶液のCO2吸収に伴う電気伝導度の変化2018

    • Author(s)
      藤田拳人、岡田真紀、保科貴亮、山田秀尚、辻智也、日秋俊彦
    • Organizer
      化学工学会第50回秋季大会
    • Related Report
      2018 Research-status Report
  • [Presentation] Calculation of Physical Properties of Materials with QM and MD Simulations2018

    • Author(s)
      T. Yamaguchi, H. Yamada, T. Fujiwara, K. Hori
    • Organizer
      8th International Symposium on Molecular Thermodynamics and Molecular Simulation
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] 313Kにおけるブチルエタノールアミン水溶液のCO2吸収に伴う溶液物性の変化2018

    • Author(s)
      藤田拳人, 岡田真紀, 保科貴亮, 山田秀尚, 辻智也, 日秋俊彦
    • Organizer
      化学工学会第83年会
    • Related Report
      2017 Research-status Report
  • [Presentation] The Chemistry of Amine-Based CO2 Capture2017

    • Author(s)
      H. Yamada
    • Organizer
      International Conference on Chemical Science and Technology for Sustainable Development
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] アミン系材料を用いたCO2分離回収技術の研究開発2017

    • Author(s)
      山田秀尚
    • Organizer
      化学工学会第49回秋季大会
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research / Invited
  • [Book] CO2削減、省エネに関する新技術、採用事例、規制対応2017

    • Author(s)
      山田秀尚 (を含めた全75名)
    • Total Pages
      565
    • Publisher
      技術情報協会
    • Related Report
      2017 Research-status Report

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Published: 2017-04-28   Modified: 2023-01-30  

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