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Fabrication and shape contol of oxide semisonductor photoelectrodes for artificial photosynthesis by chemical bath deposition

Research Project

Project/Area Number 17K04989
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Nanomaterials chemistry
Research InstitutionEhime University

Principal Investigator

Terasako Tomoaki  愛媛大学, 理工学研究科(工学系), 准教授 (70294783)

Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2019: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2018: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2017: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Keywords酸化亜鉛 / 酸化銅 / CBD法 / ナノ構造 / シード層 / UV光検出器 / ヘテロ接合 / 光電流 / キャリア生成・消滅機構 / 酸化ニッケル / ナノロッド / 光触媒 / 表面モフォロジー / ナノ材料 / 人工光合成 / 酸化物半導体 / 化学溶液析出法
Outline of Final Research Achievements

The possibility of morphology-controlled growth of CuO and Cu2O films, and ZnO nanorods (NRs) by chemical bath deposition (CBD) based technique was examined for applying to semiconductor photoelectrodes for artificial photosynthesis. Both the average width of the ZnO NRs and the average length of the CuO nano-needles were determined by the grain size of the seed layer. Moreover, both the orientations of the ZnO NRs and the Cu2O film were governed by that of the seed layer. Optical and electrical characterizations of the PEDOT:PSS/ZnO NRs organic-inorganic hybrid Schottky junction UV detectors revealed that the adsorption and desorption processes of oxygen molecular ions on the surface of the NRs strongly contribute to the photo-generation and annihilation of electrons and holes in the NRs.

Academic Significance and Societal Importance of the Research Achievements

CBD法CuOおよびCu2O薄膜、ZnO NRsの表面形態や配向性制御において溶媒の純度が重要な因子であることはもちろんのこと、シード層の選択が非常に重要であることが明らかになった。これはシード層の表面形態制御による半導体光電極の表面形態制御の可能性を示している。またZnO NRs表面での酸素分子イオンの脱着反応とキャリアの光生成と消滅が強く関係していることは、光電変換効率の改善にNRs成長後の熱処理や異種半導体材料の量子ドット堆積による表面修飾が有効であることを示している。本研究の成果は、高分子のような耐熱性の乏しい基板材料上への半導体光電極の形成に有益な情報を提供するものと期待している。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Research-status Report
  • 2017 Research-status Report
  • Research Products

    (40 results)

All 2019 2018 2017

All Journal Article (7 results) (of which Peer Reviewed: 4 results) Presentation (33 results) (of which Int'l Joint Research: 13 results,  Invited: 3 results)

  • [Journal Article] 化学溶液析出法によるZnOナノロッドの成長とPEDOT:PSS/ZnOナノロッドヘテロ接合による紫外光検出2019

    • Author(s)
      寺迫智昭,小原翔平,難波優,橋国直人,矢木正和,古林寛,山本哲也
    • Journal Title

      信学技報

      Volume: Vol. 119, No.35 Pages: 57-62

    • Related Report
      2019 Annual Research Report
  • [Journal Article] 化学溶液析出法によって種々のTCOシード層に成長したZnOナノロッドの構造およびフォトルミネッセンス特性2019

    • Author(s)
      濱本昂大,寺迫智昭,矢木正和,古林寛,山本哲也
    • Journal Title

      信学技報

      Volume: Vol. 119, No. 303 Pages: 9-13

    • Related Report
      2019 Annual Research Report
  • [Journal Article] 化学溶液析出法による極薄GZO薄膜シード層上へのZnOナノロッドの成長と構造及び光学特性2019

    • Author(s)
      寺迫智昭,濱本昂大,山田健太,甲田真一朗,矢木正和,古林寛,山本哲也
    • Journal Title

      信学技報

      Volume: Vol. 119, No. 303 Pages: 15-20

    • Related Report
      2019 Annual Research Report
  • [Journal Article] Fe-assisted chemical bath deposition of highly oriented Cu2O films and formation of ZnO nanorods/Cu2O heterojunctions2019

    • Author(s)
      Terasako Tomoaki、Kitamoto Ryutaroh、Okada Hideyuki
    • Journal Title

      Materials Today: Proceedings

      Volume: 7 Pages: 784-791

    • DOI

      10.1016/j.matpr.2018.12.075

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Structural and photoluminescence properties of ZnO nanorods grown on ion-plated Ga-doped ZnO seed layers by chemical bath deposition and fabrication of poly(3,4-ethylenedioxythiophene) poly(styrenesulfonate)/ZnO nanorods heterostructures2019

    • Author(s)
      Terasako Tomoaki、Obara Shohei、Yagi Masakazu、Nomoto Junichi、Yamamoto Tetsuya
    • Journal Title

      Thin Solid Films

      Volume: 677 Pages: 109-118

    • DOI

      10.1016/j.tsf.2019.03.025

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Morphology-controlled growth of ZnO nanorods by chemical bath deposition and seed layer dependence on their structural and optical properties2019

    • Author(s)
      Terasako Tomoaki、Obara Shohei、Sakaya Shogo、Tanaka Mamoru、Fukuoka Ryota、Yagi Masakazu、Nomoto Junichi、Yamamoto Tetsuya
    • Journal Title

      Thin Solid Films

      Volume: 669 Pages: 141-150

    • DOI

      10.1016/j.tsf.2018.10.039

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Possibility of selective and morphology-controlled growth of CuO and Cu2O films2017

    • Author(s)
      Tomoaki Terasako, Kohki Ohnishi, Hideyuki Okada, Shohei Obara, Masakazu Yagi
    • Journal Title

      Thin Solid Films

      Volume: 644 Pages: 146-155

    • DOI

      10.1016/j.tsf.2017.08.054

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Presentation] 化学溶液析出法によるZnOナノロッドの成長とPEDOT:PSS/ZnOナノロッドヘテロ接合による紫外光検出2019

    • Author(s)
      寺迫智昭,小原翔平,難波優,橋国直人,矢木正和,古林寛,山本哲也
    • Organizer
      電子情報通信学会研究会(SDM、ED、CPM共催) ~機能性デバイス材料・作製・特性評価および関連技術 ~
    • Related Report
      2019 Annual Research Report
  • [Presentation] Vapor-liquid-solid growth of SnO2 nanowires by atmospheric-pressure CVD and their structural, optical and gas-sensing properties2019

    • Author(s)
      Tomoaki Terasako, Toshiki Kurashige, Hideyuki Marui, Gou Manabe, Masakazu Yagi, Masami Mori, Yoshihiko Sadaoka
    • Organizer
      EuroCVD 22 & Baltic ALD 16
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 化学溶液析出法によって成長したZnOナ ノロッドの構造およびフォトルミネッセ ンス特性のシード層依存性2019

    • Author(s)
      濱本昂大,寺迫智昭,矢木正和,古林寛,山本哲也
    • Organizer
      2019年度応用物理・物理系学会中国四国支部合同学術講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Chemical Bath Deposition of ZnO Nanorods on Ion-plated Ga doped ZnO Seed Layers and Formation of PEDOT:PSS/ZnO Nanorods Heterostructures for UV Light Detection2019

    • Author(s)
      Tomoaki Terasako, Shohei Obara, Suguru Namba, Naoto Hashikuni, Masakazu Yagi, Yutaka Furubayashi, Tetsuya Yamamoto
    • Organizer
      20th International Union of Materials Research Societies International Conference in Asia
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Structural and Electrical Properties of Undoped and Li Doped CuO Films Grown by Chemical Bath Deposition2019

    • Author(s)
      Tomoaki Terasako, Hideyuki Okada, Kenji Gochoh, Naoya Hayashimoto
    • Organizer
      20th International Union of Materials Research Societies International Conference in Asia
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 化学溶液析出法によって種々のTCOシード層に成長したZnOナノロッドの構造およびフォトルミネッセンス特性2019

    • Author(s)
      濱本昂大,寺迫智昭,矢木正和,古林寛,山本哲也
    • Organizer
      電子情報通信学会研究会(CPM LQE ED共催)~窒化物半導体光・電デバイス、材料、関連技術、及び一般~
    • Related Report
      2019 Annual Research Report
  • [Presentation] 化学溶液析出法による極薄GZO薄膜シード層上へのZnOナノロッドの成長と構造及び光学特性2019

    • Author(s)
      寺迫智昭,濱本昂大,山田健太,甲田真一朗,矢木正和,古林寛,山本哲也
    • Organizer
      電子情報通信学会研究会(CPM LQE ED共催)~窒化物半導体光・電デバイス、材料、関連技術、及び一般~
    • Related Report
      2019 Annual Research Report
  • [Presentation] UV Light Detecting Properties of ZnO Nanorods Grown on Ion-plated Ga Doped ZnO Seed Layers by Chemical Bath Deposition2019

    • Author(s)
      Tomoaki Terasako, Shohei Obara, Suguru Namba, Naoto Hashikuni, Masakazu Yagi, Yutaka Furubayashi, Tetsuya Yamamoto
    • Organizer
      Materials Research Meeting 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Influence of Seed Layers on Structural and Morphological Properties of Nickel Hydroxide Nanowalls Grown by Chemical Bath Deposition2019

    • Author(s)
      Tomoaki Terasako, Yutaka Furubayashi,Tetsuya Yamamoto
    • Organizer
      Materials Research Meeting 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 化学溶液析出法によるZnOナノロッドの成長及びPEDOT:PSSとの無機-有機ハイブリッドヘテロ接合(II)2019

    • Author(s)
      小原翔平、難波優、橋国直人、寺迫智昭、宮田晃、矢木正和、野本淳一、山本哲也
    • Organizer
      第66回応用物理学会春季学術講演会
    • Related Report
      2018 Research-status Report
  • [Presentation] Morphology-controlled growth of ZnO nanorods by chemical bath deposition and seed layer dependence on their structural and optical properties2018

    • Author(s)
      Tomoaki Terasako, Shohei Obara, Shogo Sakaya, Mamoru Tanaka, Ryota Fukuoka, Masakazu Yagi, Junichi Nomoto, Tetsuya Yamamoto
    • Organizer
      45th International Conference on Metallurgical Coatings & Thin Films
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Fe-assisted chemical bath deposition of highly oriented Cu2O films and formation of ZnO nanorods/Cu2O heterojunctions2018

    • Author(s)
      Tomoaki Terasako, Ryutaroh Kitamoto, Hideyuki Okada
    • Organizer
      Nanotech Malaysia 2018
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Structural and photoluminescence properties of ZnO nanorods grown by chemical bath deposition and formation of PEDOT:PSS/ZnO nanorods heterojunctions2018

    • Author(s)
      Tomoaki Terasako, Shohei Obara, Masakazu Yagi, Junichi Nomoto, Tetsuya Yamamoto
    • Organizer
      10th International Symposium on Organic Molecular Electronics
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] 化学溶液析出法によるZnOナノロッドの成長及びPEDOT:PSSとの無機-有機ハイブリッドヘテロ接合2018

    • Author(s)
      小原翔平、寺迫智昭、宮田晃、野本淳一、山本哲也
    • Organizer
      第79回応用物理学会秋季学術講演会
    • Related Report
      2018 Research-status Report
  • [Presentation] ZnOナノロッドのCBD成長と構造及びフォトルミネッセンス特性へのシード層の効果2018

    • Author(s)
      寺迫智昭、小原翔平、矢木正和、野本淳一、山本哲也
    • Organizer
      第79回応用物理学会秋季学術講演会
    • Related Report
      2018 Research-status Report
  • [Presentation] Structural and optical properties of ZnO nanorods grown on ion-plated GZO buffer layers by chemical bath deposition and fabrication of PEDOT:PSS/ZnO nanorods heterojunctions2018

    • Author(s)
      Tomoaki Terasako, Shohei Obara, Masakazu Yagi, Junichi Nomoto, Tetsuya Yamamoto
    • Organizer
      7th International Symposium on Transparent Conductive Materials & 4th E-MRS & MRS-j Bilateral Symposium on Advanced Oxides and Wide Bandgap Semiconductors
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 化学溶液析出法による無添加及びLi添加CuO薄膜の成長と構造および電気的特性2018

    • Author(s)
      岡田英之、寺迫智昭、五丁健治、林本直也
    • Organizer
      電子情報通信学会電子部品・材料(CPM)研究会
    • Related Report
      2018 Research-status Report
  • [Presentation] 化学溶液析出法によるGZOシード層上へのZnOナノロッドの成長とPEDOT:PSS/ZnOナノロッドヘテロ接合の形成2018

    • Author(s)
      小原翔平、難波優、橋国直人、寺迫智昭、矢木正和、野本淳一、山本哲也
    • Organizer
      電子情報通信学会電子部品・材料(CPM)研究会
    • Related Report
      2018 Research-status Report
  • [Presentation] Cu2O薄膜上へのZnOナノロッドの化学溶液析出法による堆積と構造及びフォトルミネッセンス特性2018

    • Author(s)
      寺迫智昭、松井健乃介、三島 健、矢木正和
    • Organizer
      第28回日本MRS年次大会
    • Related Report
      2018 Research-status Report
  • [Presentation] 化学溶液析出法によるLiドープCuO薄膜の作製と電気的特性2018

    • Author(s)
      岡田英之、五丁健治、林本直也、寺迫智昭
    • Organizer
      第28回日本MRS年次大会
    • Related Report
      2018 Research-status Report
  • [Presentation] Possibility of Selective and Morphology-Cotrolled Growth of CuO and Cu2O Films2017

    • Author(s)
      Tomoaki Terasako, Kohki Ohnishi, Hideyuki Okada, Shohei Obara
    • Organizer
      44th International Conference on Metallurgical Coatings & Thin Films
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Fe支援化学溶液析出法によるCu2O薄膜の成長と表面モフォロジー2017

    • Author(s)
      寺迫 智昭、 岡田 英之、 小原 翔平
    • Organizer
      電子情報通信学会電子部品・材料研究会
    • Related Report
      2017 Research-status Report
  • [Presentation] GZOバッファ層への化学溶液析出法による酸化亜鉛薄膜の堆積2017

    • Author(s)
      小原 翔平、 寺迫 智昭、 宮田 晃、 野本 淳一、 山本 哲也
    • Organizer
      2017年度応用物理・物理系学会中国四国支部合同学術講演会
    • Related Report
      2017 Research-status Report
  • [Presentation] 化学溶液析出法によるCuO薄膜の成長と結晶学的特性2017

    • Author(s)
      岡田 英之、 寺迫 智昭、 宮田 晃
    • Organizer
      2017年度応用物理・物理系学会中国四国支部合同学術講演会
    • Related Report
      2017 Research-status Report
  • [Presentation] 新奇な化学溶液析出法による酸化第一銅の成長2017

    • Author(s)
      寺迫 智昭
    • Organizer
      2017年度応用物理学会中国四国支部若手半導体研究会
    • Related Report
      2017 Research-status Report
  • [Presentation] Chemical Bath Deposition of CuO, Cu2O, ZnO and Their Heterojunctions2017

    • Author(s)
      Tomoaki Terasako, Hideyuki Okada, Shohei Obara
    • Organizer
      IUMRS ICAM 2017
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] 化学溶液析出法によるZnO薄膜成長におけるGZOバッファ層の効果2017

    • Author(s)
      小原 翔平,寺迫 智昭, 宮田 晃,野本 淳一,山本 哲也
    • Organizer
      第78回応用物理学会秋季学術講演会
    • Related Report
      2017 Research-status Report
  • [Presentation] Fe支援化学溶液析出法によるCu2O薄膜の成長と表面モフォロジー2017

    • Author(s)
      寺迫 智昭,岡田 英之,小原 翔平,宮田 晃
    • Organizer
      第78回応用物理学会秋季学術講演会
    • Related Report
      2017 Research-status Report
  • [Presentation] 化学溶液析出法によるCuO薄膜の成長と配向制御の可能性2017

    • Author(s)
      岡田 英之,寺迫 智昭,宮田 晃
    • Organizer
      第78回応用物理学会秋季学術講演会
    • Related Report
      2017 Research-status Report
  • [Presentation] Growth of Highly Oriented Cu2O Films by Fe-assisted Chemical Bath Deposition and Formation of Their Heterojunctions with ZnO Nanorods2017

    • Author(s)
      Tomoaki Terasako, Hideyuki Okada, Shohei Obara
    • Organizer
      TACT2017 International Thin Films Conference
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Chemical bath deposition of ZnO thin films on GZO buffer layer and their structural and photoluminescence properties2017

    • Author(s)
      Shohei Obara, Tomoaki Terasako, Junichi Nomoto, Tetsuya Yamamoto
    • Organizer
      TACT2017 International Thin Films Conference
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] イオンプレーティング法GZOシード層上へのZnOナノロッドのCBD成長とZnOナノロッド/PEDOT:PSSヘテロ構造の形成2017

    • Author(s)
      寺迫 智昭、 大西 航暉、 小原 翔平、 福岡 良太、 野本 淳一、 山本 哲也
    • Organizer
      電子情報通信学会有機エレクトロニクス研究会 (鳥栖)
    • Related Report
      2017 Research-status Report
    • Invited
  • [Presentation] 化学溶液析出法によって成長したZnO及びCu2O薄膜の構造特性におけるシード層の効果2017

    • Author(s)
      寺迫 智昭、 小原 翔平、 野本 淳一、 山本 哲也
    • Organizer
      第27回日本MRS年次大会 シンポジウムC
    • Related Report
      2017 Research-status Report

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Published: 2017-04-28   Modified: 2021-02-19  

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