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Search of new strongly correlated quasicrystals

Research Project

Project/Area Number 17K05524
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Condensed matter physics II
Research InstitutionToyota Physical and Chemical Research Institute

Principal Investigator

Ishimasa Tsutomu  公益財団法人豊田理化学研究所, フェロー事業部門, フェロー (10135270)

Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2019: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2018: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2017: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords準結晶 / 価数揺動 / 量子臨界 / 希土類合金 / 近似結晶 / 新物質 / 正12角形準結晶 / 正20面体準結晶 / Yb合金 / 強相関系 / 金属物性 / 強相関電子系 / 結晶工学
Outline of Final Research Achievements

Quasicrystals are a group of materials with a special long-range order (quasiperiodicity) showing diffraction symmetry different from ordinal crystals such as icosahedral symmetry and 12-fold symmetry. In order to clarify the physical properties originated from such structural specificity, we have conducted research centered on new-substance search. Theoretically, the possibility of a new dodecagonal quasicrystal containing Yb was pointed out using "high-dimensional analysis", and experimentally the first superconductivity (Zn-Mg-Al alloy) in a quasicrystal as well as formation of a new quasicrystal in Zn-Au alloys were discovered. Furthermore, we found phase separation (Cu-Ga-Sc alloy) with a difference in cluster structure, and a difference in electronic state of Yb (Au-Ge-Yb alloy) due to similar difference in the approximant crystals.
It is thought that these have brought us one step closer to the goal of “clarifying the physical properties inherent in quasicrystals”.

Academic Significance and Societal Importance of the Research Achievements

歴史の区分として,しばしば石器時代,青銅時代,鉄器時代,シリコン時代などを用いますが,これらは全て”結晶の時代”と言うことができます.ところが最近,専門家の間では準結晶と呼ばれる物質群が注目されています.準結晶は,アルミニウム,銅,鉄など,金属の合金として形成しますが,結晶ともアモルファスとも異なる「特別の規則」に従って原子が並んでいるため,従来の金属材料とは異なる「未来材料になりうるような性質」を持っています.ここでは,新物質探索を軸として,そのような準結晶についての基礎研究を行いました.

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Research-status Report
  • 2017 Research-status Report
  • Research Products

    (39 results)

All 2020 2019 2018 2017 Other

All Int'l Joint Research (2 results) Journal Article (8 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 5 results,  Open Access: 5 results) Presentation (27 results) (of which Int'l Joint Research: 8 results,  Invited: 7 results) Remarks (2 results)

  • [Int'l Joint Research] University of Grenoble Alpes, CNRS(フランス)

    • Related Report
      2018 Research-status Report
  • [Int'l Joint Research] Slovak Academy of Sciences(スロバキア)

    • Related Report
      2018 Research-status Report
  • [Journal Article] 同型置換による準結晶及び近似結晶の探索: 新たな価数揺動系をめざして2020

    • Author(s)
      石政 勉
    • Journal Title

      豊田研究報告

      Volume: 73 Pages: 41-49

    • NAID

      40022268299

    • Related Report
      2019 Annual Research Report
    • Open Access
  • [Journal Article] Icosahedral quasicrystal, 1/1 and 2/1 approximants in Zn-based ternary alloys containing Au and Yb/Tb2019

    • Author(s)
      Tsutomu Ishimasa
    • Journal Title

      Philosophical Magazine Letters

      Volume: vol.99 Issue: 10 Pages: 351-359

    • DOI

      10.1080/09500839.2019.1695068

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Tsai型1/1近似結晶の構造と相変態:Cu-Ga-Sc合金の場合2019

    • Author(s)
      石政 勉
    • Journal Title

      豊田研究報告

      Volume: 72 Pages: 45-51

    • NAID

      40021933632

    • Related Report
      2019 Annual Research Report
    • Open Access
  • [Journal Article] Interpretation of some Yb-based valence-fluctuating crystals as approximants to a dodecagonal quasicrystal2018

    • Author(s)
      T. Ishimasa, M. Mihalkovic, K. Deguchi, N.K. Sato and M. de Boissieu
    • Journal Title

      Philosophical Magazine

      Volume: 98 Issue: 22 Pages: 2018-2034

    • DOI

      10.1080/14786435.2018.1470339

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] 希土類合金結晶からの正12角形準結晶構造モデルの構築2018

    • Author(s)
      石政 勉
    • Journal Title

      豊田研究報告

      Volume: 71 Pages: 73-79

    • Related Report
      2018 Research-status Report
    • Open Access
  • [Journal Article] Discovery of superconductivity in quasicrystals2018

    • Author(s)
      K. Kamiya, T. Takeuchi, N. Kabeya, N. Wada, T. Ishimasa, A. Ochiai, K. Deguchi, K. Imura, N.K. Sato
    • Journal Title

      Nature Communications

      Volume: 9 Issue: 1 Pages: 154-154

    • DOI

      10.1038/s41467-017-02667-x

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Quantum critical behavior in magnetic quasicrystals and approximant crystals2017

    • Author(s)
      N. K. Sato, S.Matsukawa, K. Nobe, K. Imura, K. Deguchi, T. Ishimasa
    • Journal Title

      J. Physics Conf. Series

      Volume: 868 Pages: 012005-012005

    • DOI

      10.1088/1742-6596/868/1/012005

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Direct observation of heterogeneous valence state in Yb-based quasicrystalline approximants2017

    • Author(s)
      M. Matsunami, M. Oura, K. Tamasaku, T. Ishikawa, S. Ideta, K. Tanaka, T. Takeuchi, T. Yamada, A.P. Tsai, K. Imura, K. Deguchi, N.K. Sato, T. Ishimasa
    • Journal Title

      Physical Review B

      Volume: 96 Issue: 24

    • DOI

      10.1103/physrevb.96.241102

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Presentation] Modulations in Tsai-type: the problems can be solved but could not be solved2020

    • Author(s)
      石政 勉
    • Organizer
      第24回準結晶研究会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 準結晶の電気抵抗と比熱の研究2020

    • Author(s)
      平野由真,林裕人,豊永詞,石政勉,蔡安邦,山田庸公,井村敬一郎,出口和彦,佐藤憲昭
    • Organizer
      日本物理学会第75回年次大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Zn-Au-Yb準結晶・近似結晶における価数揺動と磁性2020

    • Author(s)
      井村敬一郎,米山祐樹, 安藤秀行,出口和彦,山岡人志,平岡望,石井啓文,石政勉,佐藤憲昭
    • Organizer
      日本物理学会第75回年次大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Icosahedral quasicrystal, 1/1 and 2/1 approximants in Zn-Au-L (L=Yb, Tb) alloys2019

    • Author(s)
      T. Ishimasa
    • Organizer
      Interdisciplinary Symposium for Quasicrystals and Strongly Correlated Electron Systems
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Valence instability and quantum criticality in Yb-based quasicrystals and approximant crystals2019

    • Author(s)
      K. Imura, S. Yokota, K. Sakamoto, K. Namba, S. Hirokawa, K. Deguchi, H. Yamaoka, Y. Yamamoto, T. Kawai, J. Mizuki, N. Hiraoka, H. Ishii, T. Ishimasa, N.K. Sato
    • Organizer
      Interdisciplinary Symposium for Quasicrystals and Strongly Correlated Electron Systems
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Quasicrystals as a new platform of valence fluctuating systems2019

    • Author(s)
      T. Ishimasa, K. Deguchi, K. Imura, N.K. Sato
    • Organizer
      International Conference on Strongly Correlated Electron Systems 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Zn系準結晶及びCd-Mg-Yb準結晶の電気抵抗率の温度依存性の研究2019

    • Author(s)
      平野由真,林裕人, 石政勉, 蔡安邦,山田庸公、井村敬一郎, 出口和彦, 佐藤憲昭
    • Organizer
      日本物理学会2019年秋季大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] ランタノイドとAuを含むZn基合金における正20面体準結晶, 2/1, 1/1近似結晶の形成2019

    • Author(s)
      石政 勉
    • Organizer
      日本物理学会2019年秋季大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Tsai型クラスター構造を持つZn-Au-Yb準結晶及び近似結晶の磁性2019

    • Author(s)
      井村敬一郎, 米山祐樹, 出口和彦, 佐藤憲昭
    • Organizer
      日本物理学会2019年秋季大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] ランタノイドとAuを含むZn基合金における準結晶関連構造の形成2019

    • Author(s)
      石政 勉
    • Organizer
      電子顕微鏡学会北海道支部学術講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 準結晶の立場からみたボロン化合物2019

    • Author(s)
      石政勉
    • Organizer
      第13回日本ホウ素・ホウ化物研究会
    • Related Report
      2018 Research-status Report
    • Invited
  • [Presentation] Cu-Ga-Sc1/1近似結晶の相分離2019

    • Author(s)
      石政勉, 高倉洋礼、八木祐介
    • Organizer
      日本物理学会第74回年次大会
    • Related Report
      2018 Research-status Report
  • [Presentation] Search for Ga-based icosahedral quasicrystal2018

    • Author(s)
      T. Hiroto, K. Honda, K. Nishimoto, K. Kitahara, T. Ishimasa, K. Kimura
    • Organizer
      Aperiodic 2018
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Preparation of icosahedral high-entropy alloy2018

    • Author(s)
      P. Priputen, M. Mihalkovic, P. Noga, M. Widom, T. Ishimasa
    • Organizer
      Aperiodic 2018
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Superconductivity in Al-Zn-Mg quasicrystal2018

    • Author(s)
      N.K. Sato, K. Kamiya, T. Takeuchi, N. Kabeya, N. Wada, T. Ishimasa, A. Ochiai, K. Deguchi, K. Imura
    • Organizer
      Aperiodic 2018
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Cu-Ga-Sc1/1近似結晶の構造相転移2018

    • Author(s)
      石政勉, 谷口信, 高倉洋礼, M. de Boissieu, M. Mihalkovic
    • Organizer
      日本物理学会2018年秋季大会
    • Related Report
      2018 Research-status Report
  • [Presentation] Zn-T-Sc (T=Ag, Mg)及びCd-Mg-Yb準結晶の極低温電気抵抗測定2018

    • Author(s)
      林裕人, 石政勉, 蔡安邦,山田庸公、井村敬一郎, 出口和彦, 佐藤憲昭
    • Organizer
      日本物理学会2018年秋季大会
    • Related Report
      2018 Research-status Report
  • [Presentation] Cu-Ga-Sc 近似結晶の相分離2018

    • Author(s)
      石政勉, 高倉洋礼、八木祐介
    • Organizer
      電子顕微鏡学会北海道支部学術講演会
    • Related Report
      2018 Research-status Report
  • [Presentation] 合金系準結晶の未解決問題2018

    • Author(s)
      石政勉
    • Organizer
      第13回日本フラックス成長研究会
    • Related Report
      2018 Research-status Report
    • Invited
  • [Presentation] Zn-Ag-Sc準結晶・近似結晶の極低温電気抵抗及びトンネル効果測定2018

    • Author(s)
      林裕人, 本山岳, 石政勉, 井村敬一郎, 出口和彦, 佐藤憲昭
    • Organizer
      日本物理学会第73回年次大会
    • Related Report
      2017 Research-status Report
  • [Presentation] Approximants connecting quasicrystals to periodic crystals2017

    • Author(s)
      T. Ishimasa
    • Organizer
      Open space between aperiodic order and strong electronic correlations, Annecy France
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Zn-Ag-Sc準結晶の極低温電気抵抗率測定2017

    • Author(s)
      林裕人, 石政勉, 林実奈美, 井村敬一郎, 出口和彦, 佐藤憲昭
    • Organizer
      日本物理学会2017年秋季大会
    • Related Report
      2017 Research-status Report
  • [Presentation] Tsai型クラスターをもつYb系準結晶・近似結晶の磁性2017

    • Author(s)
      廣川慎之介, 出口和彦, 米山祐樹, 横田晋次郎, 井村敬一郎, 佐藤憲昭, 豊永詞, 石政勉, 山本義哉, 山岡人志, 平岡望, 石井啓
    • Organizer
      日本物理学会2017年秋季大会
    • Related Report
      2017 Research-status Report
  • [Presentation] Au-Al-Yb準結晶における置換可能な元素の探索と低温物性2017

    • Author(s)
      米山祐樹, 出口和彦, 松川周矢, 廣川慎之介, 難波慶介, 井村敬一郎, 石政勉、佐藤憲昭
    • Organizer
      日本物理学会2017年秋季大会
    • Related Report
      2017 Research-status Report
  • [Presentation] Yb系価数揺動近似結晶の構造解釈:正12角形準結晶の観点から2017

    • Author(s)
      石政勉, 出口和彦, 佐藤憲昭
    • Organizer
      日本物理学会2017年秋季大会
    • Related Report
      2017 Research-status Report
  • [Presentation] Approximant connecting some heavy fermion crystals to quasicrystals2017

    • Author(s)
      T. Ishimasa
    • Organizer
      C-MAC Days 2017, Athens, Greece
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 準結晶構造の数理:物質科学の視点から2017

    • Author(s)
      石政勉
    • Organizer
      第16回岡シンポジウム
    • Related Report
      2017 Research-status Report
    • Invited
  • [Remarks] 新物質探索による準結晶・関連結晶の構造・物性研究

    • URL

      https://www.toyotariken.jp/fellow/tsutomu-ishimasa

    • Related Report
      2019 Annual Research Report
  • [Remarks] 新物質探索による準結晶構造と物性の研究

    • URL

      https://www.toyotariken.jp/cms/wp-content/uploads/2018/09/ishimasa_syoukai-1.pdf

    • Related Report
      2018 Research-status Report

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Published: 2017-04-28   Modified: 2021-02-19  

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