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Relation between the charge fluctuation and superconductivity in organic superconductors studied by STM/STS

Research Project

Project/Area Number 17K05526
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Condensed matter physics II
Research InstitutionHokkaido University

Principal Investigator

Ichimura Koichi  北海道大学, 工学研究院, 准教授 (50261277)

Co-Investigator(Kenkyū-buntansha) 松浦 徹  福井工業高等専門学校, 電気電子工学科, 准教授 (60534758)
Project Period (FY) 2017-04-01 – 2023-03-31
Project Status Completed (Fiscal Year 2022)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2019: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2018: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2017: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords超伝導 / 電荷秩序 / 走査トンネル顕微鏡 / 有機導体 / 強相関電子系 / 有機超伝導体
Outline of Final Research Achievements

An organic superconductor, which exhibits the charge ordering, was studied by low temperature scanning tunneling microscope (STM) to elucidate the role of the charge degrees of freedom in highly correlated electron systems. The charge disproportionation was observed by scanning tunneling spectroscopy (STS) in the charge ordering phase. We found that the charge disproportionation corresponds to the spatial modulation of the charge ordering gap. The charge disproportionation exists in the superconducting state, indicating that the superconductivity and the charge ordering coexist. It suggests that the charge fluctuation due to the long range (offsite) Coulomb interaction correlates to the superconductivity.

Academic Significance and Societal Importance of the Research Achievements

本研究により電荷秩序相での電子分布がナノメートルスケールで実空間観測できた。ここで確立したトンネルスペクトルから電子密度分布を得る方法は、強相関電子系を研究するうえで有用な手段である。
また、電荷ゆらぎが深く関与する新しい超伝導発現機構が示唆された。

Report

(7 results)
  • 2022 Annual Research Report   Final Research Report ( PDF )
  • 2021 Research-status Report
  • 2020 Research-status Report
  • 2019 Research-status Report
  • 2018 Research-status Report
  • 2017 Research-status Report
  • Research Products

    (40 results)

All 2022 2021 2020 2019 2018 2017 Other

All Int'l Joint Research (4 results) Journal Article (5 results) (of which Peer Reviewed: 5 results) Presentation (31 results) (of which Int'l Joint Research: 15 results,  Invited: 5 results)

  • [Int'l Joint Research] Universiti Sains Malaysia(マレーシア)

    • Related Report
      2022 Annual Research Report
  • [Int'l Joint Research] Universiti Sains Malaysia(マレーシア)

    • Related Report
      2021 Research-status Report
  • [Int'l Joint Research] Universiti Sains Malaysia(マレーシア)

    • Related Report
      2020 Research-status Report
  • [Int'l Joint Research] Universiti Sains Malaysia(マレーシア)

    • Related Report
      2019 Research-status Report
  • [Journal Article] Charge Ordering and Superconducting State in b”-(BEDT-TTF)4[(H3O)Ga(C2O4)3]・C6H5NO2 Studied by STM/STS2022

    • Author(s)
      Koichi Ichimura, Hiroki Kokubo, Satoshi Tanda, Tohru Kurosawa, Migaku Oda, Hiroki Honma, Noriaki Matsunaga, Kazuto Moribe, Yoshihiko Ihara, Atsushi Kawamoto
    • Journal Title

      JPS Conference Proceedings

      Volume: -

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Highly Isotropic In-plane Upper Critical Field in the Anisotropic s-Wave Superconductor 2H-NbSe22019

    • Author(s)
      S. Yasuzuka, S. Uji, T. Terashima, Y. Nogami, K. Ichimura, S. Tanda
    • Journal Title

      Journal of Superconductivity and Novel Magnetism

      Volume: 32 Issue: 4 Pages: 1-6

    • DOI

      10.1007/s10948-019-05333-z

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] Effect of Cu intercalation and pressure on excitonic interaction in 1T-TiSe22019

    • Author(s)
      Kitou S.、Nakano A.、Kobayashi S.、Sugawara K.、Katayama N.、Maejima N.、Machida A.、Watanuki T.、Ichimura K.、Tanda S.、Nakamura T.、Sawa H.
    • Journal Title

      Physical Review B

      Volume: 99 Issue: 10 Pages: 104109-104109

    • DOI

      10.1103/physrevb.99.104109

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Effect of Cu Doping on Superconductivity in TaSe3: Relationship between Superconductivity and Induced Charge Density Wave2018

    • Author(s)
      A. Nomura, K. Yamaya, S. Takayanagi, K. Ichimura, S. Tanda
    • Journal Title

      Europhysics Letters

      Volume: 124 Issue: 6 Pages: 67001-67001

    • DOI

      10.1209/0295-5075/124/67001

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Emergence of a Resistance Anomaly by Cu-doping in TaSe32017

    • Author(s)
      A. Nomura, K. Yamaya, S. Takayanagi, K. Ichimura, T. Matsuura, S. Tanda
    • Journal Title

      Europhysics Letters

      Volume: 119 Issue: 1 Pages: 17005-17005

    • DOI

      10.1209/0295-5075/119/17005

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Presentation] Charge Disproportionation in Organic Conductors a-(BEDT-TTF)2X2022

    • Author(s)
      Koichi Ichimura, Hikaru Takami, Kazuhiro Katono, Satoshi Tanda
    • Organizer
      6th International Conference on Functional Materials Science 2022 (6th ICFMS 2022) in conjunction with 2nd RIKEN Symposium
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Charge Ordering and Superconducting State in b”-(BEDT-TTF)4[(H3O)Ga(C2O4)3]・C6H5NO2 Studied by STM/STS2022

    • Author(s)
      Koichi Ichimura, Hiroki Kokubo, Satoshi Tanda, Tohru Kurosawa, Migaku Oda, Hiroki Honma, Noriaki Matsunaga, Kazuto Moribe, Yoshihiko Ihara, Atsushi Kawamoto
    • Organizer
      29th International conference on Low Temperature Physics (LT29)
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Progress of DFT Studies on Muon Hyperfine Interactions in DNA Molecules2022

    • Author(s)
      Ammaina Jamaludin, Shukri Sulaiman, Wan Nurfadhilah Zaharim, Harison Rozak, Katsuya Ishizaki, Koichi Ichimura, Isao Watanabe
    • Organizer
      6th International Conference on Functional Materials Science 2022 (6th ICFMS 2022) in conjunction with 2nd RIKEN Symposium
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Electron Transfer in DNA of Parkinson's Disease Model Studied by Scanning Tunneling Microscopy2022

    • Author(s)
      Muhammad Hanif Che Lah, Harison Rozak, Mohammed Faruque Reza, Shaharum Shamsuddin, Jafri Malin Abdullah, Koichi Ichimura, Isao Watanabe
    • Organizer
      6th International Conference on Functional Materials Science 2022 (6th ICFMS 2022) in conjunction with 2nd RIKEN Symposium
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research
  • [Presentation] STM Study of 12-mer Single Strand Guanine2022

    • Author(s)
      Katsuya Ishizaki, Issei Miyazaki, Harison Rozak, Wan Nurfadhilah Zaharim, Muhammad Hanif Che Lah, Isao Watanabe, Shukri Sulaiman, Satoshi Tanda, Koichi Ichimura
    • Organizer
      29th International conference on Low Temperature Physics (LT29)
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Scanning Tunneling Microscopy Studies of Electron Transfer in DNA - A Parkinson’s Disease Model2022

    • Author(s)
      Muhammad Hanif Che Lah, Harison Rozak, Mohammed Faruque Reza, Shaharum Shamsuddin, Jafri Malin Abdullah, Koichi Ichimura, Isao Watanabe
    • Organizer
      29th International conference on Low Temperature Physics (LT29)
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Voltage Response of STM Tunneling Currents on Microtubules: Proposal of a New Neural Model by Quantum Reduction with Entanglement2022

    • Author(s)
      Yutaro Teranishi, Keiji Nakatsugawa, Yukinori Nishigami, Toshiyuki Nakagaki, Koichi Ichimura, Yuta Fukuda, Satoshi Tanda
    • Organizer
      29th International conference on Low Temperature Physics (LT29)
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Precursor of New Field-Induced Phase Transition in NbSe3: by Measurement of Electromagnetic Response2022

    • Author(s)
      Kazu Urushihara, Yuta Fukuda, Akiya S. Ebana, Koichi Ichimura, Satoshi Tanda
    • Organizer
      29th International conference on Low Temperature Physics (LT29)
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 麻酔効果から考えた量子神経としての微小管2021

    • Author(s)
      寺西優太郎、中津川啓治、江花昭哉 ショーン、西上幸範、中垣俊之、市村 晃一、内田努、丹田聡
    • Organizer
      日本物理学会第76回年次大会
    • Related Report
      2021 Research-status Report
  • [Presentation] Fe1+xTeの誘電率測定II2020

    • Author(s)
      横井千熙、宮嵜一誠、金井恭介、市村晃一、丹田聡、松永悟明、黒澤徹
    • Organizer
      日本物理学会2020年秋季大会
    • Related Report
      2020 Research-status Report
  • [Presentation] Fe1+xTeの誘電率測定2020

    • Author(s)
      横井千熙、宮嵜一誠、金井恭介、市村晃一、丹田聡、松永悟明、黒澤徹
    • Organizer
      日本物理学会第75回年次大会
    • Related Report
      2019 Research-status Report
  • [Presentation] In-Plane Anisotropy of Upper Critical Field in Layered Transition Metal Dichalcogenide NbSe22018

    • Author(s)
      S. Yasuzuka, S. Uji, S. Sugiura, T. Terashima, Y. Nogami, K. Ichimura, S. Tanda
    • Organizer
      International Conference on Science and Technology of Synthetic Metals 2018 (ICSM2018)
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] STM/STS on beta”-(BEDT-TTF)4[(H3O)Ga(C2O4)3]・C6H5NO22018

    • Author(s)
      K. Ichimura, H. Kokubo, S. Tanda, T. Kurosawa, M. Oda, H. Honma, N. Matsunaga, K. Moribe, Y. Ihara, A. Kawamoto
    • Organizer
      4th International Conference on Functional Materials Science 2018 (4th ICFMS 2018) in conjunction with 2nd RIKEN Symposium
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] The Study of the Structure of 12-Mer Single-Stranded Polyadenine and Its Relationship with Electrical Conductivity2018

    • Author(s)
      Harison Rozak, Wan Nurfadhilah Zaharim, Issei Miyazaki, Nur Eliana Ismail, Siti Nuramira Abu Bakar, Daruliza Kernain, Razip Samian, Koichi Ichimura, Mohamed Ismail Mohamed-Ibrahim, Shukri Sulaiman, Isao Watanabe
    • Organizer
      4th International Conference on Functional Materials Science 2018 (4th ICFMS 2018) in conjunction with 2nd RIKEN Symposium
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] 2H-NbSe2における上部臨界磁場の面内異方性2018

    • Author(s)
      安塚周磨、宇治進也、杉浦栞理、寺嶋太一、野上由夫、市村晃一、丹田聡
    • Organizer
      日本物理学会2018年秋季大会
    • Related Report
      2018 Research-status Report
  • [Presentation] CuドープしたTaSe3における電荷密度波(CDW)の出現2018

    • Author(s)
      野村温、山谷和彦、高柳滋、市村晃一、松浦徹、丹田聡
    • Organizer
      日本物理学会2018年秋季大会
    • Related Report
      2018 Research-status Report
  • [Presentation] CuドープしたTaSe3における超伝導2018

    • Author(s)
      野村温、山谷和彦、高柳滋、市村晃一、丹田聡
    • Organizer
      日本物理学会2018年秋季大会
    • Related Report
      2018 Research-status Report
  • [Presentation] beta”-(BEDT-TTF)4[(H3O)Ga(C2O4)3]・C6H5NO2のSTM/STS2018

    • Author(s)
      市村晃一、小久保宏樹、丹田聡、黒澤徹、小田研、本間弘樹、松永悟明、森部一斗、井原慶彦、河本充司
    • Organizer
      日本物理学会2018年秋季大会
    • Related Report
      2018 Research-status Report
  • [Presentation] FeTeのSTM/STS2018

    • Author(s)
      宮嵜一誠、市村晃一、丹田聡、黒澤徹、小田研
    • Organizer
      日本物理学会2018年秋季大会
    • Related Report
      2018 Research-status Report
  • [Presentation] 1T-TaS2薄膜試料の磁気抵抗とホール抵抗測定II2018

    • Author(s)
      近藤広康、髙品博光、延兼啓純、中村一、中津川啓治、市村晃一、黒澤徹、丹田聡
    • Organizer
      日本物理学会2018年秋季大会
    • Related Report
      2018 Research-status Report
  • [Presentation] muSR Studies on Electron Motion in DNA2018

    • Author(s)
      Harison Rozak, Fadhilah Zaharim, Fahmi Astuti, Eliana Ismail, Amira Abu Bakar, Issei Miyazaki, Shukri Sulaiman, Mohamed Ismail Mohamed-Ibrahim, Koichi Ichimura, Isao Watanabe
    • Organizer
      日本物理学会2018年秋季大会
    • Related Report
      2018 Research-status Report
  • [Presentation] へき開薄膜化した層状銅酸化物絶縁体の輸送現象2018

    • Author(s)
      中村一、延兼啓純、近藤広康、市村晃一、丹田聡
    • Organizer
      日本物理学会第73回年次大会
    • Related Report
      2017 Research-status Report
  • [Presentation] STM/STSからみた1T-TaS2の電子状態II2018

    • Author(s)
      黒澤徹、高品博光、近藤広康、市村晃一、桃野直樹、吉田紘行、小田研、伊土政幸、丹田聡
    • Organizer
      日本物理学会第73回年次大会
    • Related Report
      2017 Research-status Report
  • [Presentation] 1T-TaS2薄膜試料の磁気抵抗とホール抵抗測定2018

    • Author(s)
      近藤広康、中村一、延兼啓純、中津川啓治、市村晃一、黒澤徹、丹田聡
    • Organizer
      日本物理学会第73回年次大会
    • Related Report
      2017 Research-status Report
  • [Presentation] 擬一次元有機導体(TMTTF)2XのSTM分光2018

    • Author(s)
      本間弘樹、延兼啓純、市村晃一、河本充司、松永悟明
    • Organizer
      日本物理学会第73回年次大会
    • Related Report
      2017 Research-status Report
  • [Presentation] STM/STS on the Charge Ordering State in beta"-(BEDT-TTF)4[(H3O)Ga(C2O4)3]C6H5NO22018

    • Author(s)
      K. Ichimura, H. Kokubo, S. Tanda, T. Kurosawa, H. Yoshida, M. Oda, M. Ido, H. Honma, N. Matsunaga, K. Moribe, Y. Ihara, A. Kawamoto
    • Organizer
      The International Conference on Science and Technology of Synthetic Metals 2018 (ICSM 2018)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Charge Disproportionation in Two Dimensional Organic Conductors2017

    • Author(s)
      K. Ichimura, H. Kokubo, I. Miyazaki, K. Katono, T. Taniguchi, Y. Kawashima, S. Tanda, K. Yamamoto
    • Organizer
      International Workshop on Organic Molecular Systems
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Charge Disproportionation in alpha-(BEDT-TTF)2X2017

    • Author(s)
      K. Ichimura, K. Katono, T. Taniguchi, Y. Kawashima, S. Tanda, K. Yamamoto
    • Organizer
      12th International Symposium on Crystalline Organic Metals Superconductors and Magnets (ISCOM2017)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Charge Disproportionation in Organic Conductors2017

    • Author(s)
      K. Ichimura, K. Katono, T. Taniguchi, Y. Kawashima, S. Tanda, K. Yamamoto
    • Organizer
      International Workshop on NanoScience and NanoOptics 2017
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 有機超伝導体における異方的超伝導ギャップ2017

    • Author(s)
      市村晃一、野村一成
    • Organizer
      2017年真空・表面科学合同講演会、合同シンポジウム「低次元超伝導の新展開」
    • Related Report
      2017 Research-status Report
    • Invited
  • [Presentation] STM/STSからみた1T-TaS2の電子状態2017

    • Author(s)
      黒澤徹、高品博光、近藤広康、市村晃一、桃野直樹、吉田紘行、小田研、伊土政幸、丹田聡
    • Organizer
      日本物理学会2017年秋季大会
    • Related Report
      2017 Research-status Report

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Published: 2017-04-28   Modified: 2024-01-30  

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