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Structure analysis of solid hydrogen III phase using high-pressure X-ray diffraction technique

Research Project

Project/Area Number 17K05550
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Condensed matter physics II
Research InstitutionUniversity of Hyogo

Principal Investigator

Akahama Yuichi  兵庫県立大学, 物質理学研究科, 特任教授・名誉教授 (90202522)

Project Period (FY) 2017-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2019: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2018: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2017: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywords水素 / 高圧固体相 / X線回折 / 金属化 / 超臨界流体相 / ラマン分光 / 放射光 / ダイヤモンドアンビル / 固体水素 / 高圧相 / X線回折実験 / 超臨界相 / 高圧構造 / X線構造解析 / ラマン散乱 / 超高圧 / 分子性固体 / 超高圧力 / 金属水素 / 高温超伝導
Outline of Final Research Achievements

For the first time in the world, we succeeded in observing a high-quality powder X-ray diffraction pattern from the solid hydrogen phase III up to 200 GPa. Based on the observed data, it was clarified that the phase III structure has hexagonal symmetry, and that the hydrogen molecule is still near the lattice point of the hcp structure even at 200 GPa. So far, a monoclinic lattice (C2/c) has been regarded as promising for the structure of phase III from theoretical studies, but this result overturned this prediction and prompted a reexamination of theoretical calculations. Our Raman spectroscopy also clarified that the phase III caused a low symmetry of the crystal structure at about 230 GPa. Furthermore, the correlation between density and molecular vibration for the hydrogen supercritical fluid phase was found from X-ray diffraction and Raman spectroscopy experiments, and the pressure-induced structural phase transitions of many elemental materials were clarified.

Academic Significance and Societal Importance of the Research Achievements

水素は、最も単純な元素で、科学研究における重要な対象物質である。400 GPa以上の超高圧力下で実現すると予言されている金属水素は、室温で超伝導を示すことが提案され固体物理学の分野の重要課題となっている。本研究で解明された固体水素Ⅲ相の結晶構造、密度そして分子振動に関する情報は、金属水素を実現し、金属相の物性を理解する上で貴重な基礎データであり、学術的に大きな意義がある。また、本研究により解明された水素超臨界流体相の光学的性質や凝集状態そして密度等の基礎物性は、水素社会実現のための高圧水素ガス応用の上で貴重なデータに成ることから社会的に意義があると確信している。

Report

(5 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Research-status Report
  • 2018 Research-status Report
  • 2017 Research-status Report
  • Research Products

    (35 results)

All 2021 2020 2019 2018 2017

All Journal Article (17 results) (of which Int'l Joint Research: 6 results,  Peer Reviewed: 17 results,  Open Access: 6 results) Presentation (18 results) (of which Int'l Joint Research: 3 results,  Invited: 1 results)

  • [Journal Article] Volume compression of period 4 elements: Zn, Ge, As, and Se above 200?GPa: Ordering of atomic volume by atomic number2021

    • Author(s)
      Akahama Y.、Kamiue K.、Okawa N.、Kawaguchi S.、Hirao N.、Ohishi Y.
    • Journal Title

      Journal of Applied Physics

      Volume: 129 Issue: 2 Pages: 025901-025901

    • DOI

      10.1063/5.0033721

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] High-pressure stability of bcc-vanadium and phase transition to a rhombohedral structure at 200?GPa2021

    • Author(s)
      Akahama Yuichi、Kawaguchi Saori、Hirao Naohisa、Ohishi Yasuo
    • Journal Title

      Journal of Applied Physics

      Volume: 129 Issue: 13 Pages: 135902-135902

    • DOI

      10.1063/5.0041208

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Pressure–Composition Phase Diagram of Fe–Ni Alloy2020

    • Author(s)
      Akahama Yuichi、Fujimoto Yuki、Terai Tomoyuki、Fukuda Takashi、Kawaguchi Saori、Hirao Naohisa、Ohishi Yasuo、Kakeshita Tomoyuki
    • Journal Title

      MATERIALS TRANSACTIONS

      Volume: 61 Issue: 6 Pages: 1058-1062

    • DOI

      10.2320/matertrans.MT-M2020047

    • NAID

      130007846151

    • ISSN
      1345-9678, 1347-5320
    • Year and Date
      2020-06-01
    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structure refinement of black phosphorus under high pressure2020

    • Author(s)
      Akahama Yuichi、Miyakawa Masashi、Taniguchi Takashi、Sano-Furukawa Asami、Machida Shinichi、Hattori Takanori
    • Journal Title

      The Journal of Chemical Physics

      Volume: 153 Issue: 1 Pages: 014704-014704

    • DOI

      10.1063/5.0012870

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Observation of high-pressure bcc phase of titanium at 243?GPa2020

    • Author(s)
      Akahama Yuichi、Kawaguchi Saori、Hirao Naohisa、Ohishi Yasuo
    • Journal Title

      Journal of Applied Physics

      Volume: 128 Issue: 3 Pages: 035901-035901

    • DOI

      10.1063/5.0014766

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Elastic softening of bulk modulus of monoclinic HfO2 under high pressure2020

    • Author(s)
      Akahama Yuichi、Kawaguchi Saori、Hirao Naohisa、Ohishi Yasuo
    • Journal Title

      Applied Physics Letters

      Volume: 117 Issue: 18 Pages: 182903-182903

    • DOI

      10.1063/5.0029148

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] High-pressure Raman scattering and x-ray diffraction studies of the supercritical fluid of hydrogen2020

    • Author(s)
      Y. Akahama, R. Miyamoto, S. Nakano, S. Kawaguchi, N. Hirao, Y. Ohishi
    • Journal Title

      Journal of Applied Physics

      Volume: 128 Issue: 13 Pages: 135901-135901

    • DOI

      10.1063/5.0022735

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Pressure-induced evolution of band structure in black phosphorus studied by P31 NMR2020

    • Author(s)
      Fujii T.、Nakai Y.、Akahama Y.、Ueda K.、Mito T.
    • Journal Title

      Physical Review B

      Volume: 101 Issue: 16

    • DOI

      10.1103/physrevb.101.161408

    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Relation between O8 cluster shape and vibrational spectra in the ε-phase of solid oxygen2019

    • Author(s)
      Akahama Yuichi、Fujihisa Hiroshi、Hirao Naohisa、Ohishi Yasuo
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 58 Issue: 9 Pages: 095502-095502

    • DOI

      10.7567/1347-4065/ab355a

    • NAID

      210000156809

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] Structure change of monoclinic ZrO2 baddeleyite involving softenings of bulk modulus and atom vibrations2019

    • Author(s)
      Fukui Hiroshi、Fujimoto Manato、Akahama Yuichi、Sano-Furukawa Asami、Hattori Takanori
    • Journal Title

      Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials

      Volume: 75 Issue: 4 Pages: 742-749

    • DOI

      10.1107/s2052520619007923

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] Pressure-induced reentrant structural transition and equation of state of indium2019

    • Author(s)
      Akahama Y.、Takahashi K.、Kamiue K.、Sugimoto T.、Hirao N.、Ohishi Y.
    • Journal Title

      Journal of Applied Physics

      Volume: 125 Issue: 7 Pages: 075901-075901

    • DOI

      10.1063/1.5086318

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Piezofluorochromism in Charge‐Transfer Inclusion Crystals: The Influence of High Pressure versus Mechanical Grinding2018

    • Author(s)
      Toshikazu Ono, Yoshifumi Tsukiyama, Ai Taema, Hiroyasu Sato, Hidetoshi Kiyooka, Yuma Yamaguchi, Ayumi Nagahashi, Manami Nishiyama, Yuichi Akahama, Yoshiki Ozawa, Masaaki Abe, Yoshio Hisaeda
    • Journal Title

      ChemPhotoChem

      Volume: 印刷中 Issue: 5 Pages: 416-420

    • DOI

      10.1002/cptc.201700227

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Observation of Poiseuille flow of phonons in black phosphorus2018

    • Author(s)
      Machida Yo、Subedi Alaska、Akiba Kazuto、Miyake Atsushi、Tokunaga Masashi、Akahama Yuichi、Izawa Koichi、Behnia Kamran
    • Journal Title

      Science Advances

      Volume: 4 Issue: 6 Pages: 3374-3374

    • DOI

      10.1126/sciadv.aat3374

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Prolonged photo-carriers generated in a massive-and-anisotropic Dirac material2018

    • Author(s)
      Nurmamat Munisa、Ishida Yukiaki、Yori Ryohei、Sumida Kazuki、Zhu Siyuan、Nakatake Masashi、Ueda Yoshifumi、Taniguchi Masaki、Shin Shik、Akahama Yuichi、Kimura Akio
    • Journal Title

      Scientific Reports

      Volume: 8 Issue: 1 Pages: 1-7

    • DOI

      10.1038/s41598-018-27133-6

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Observation of the negative pressure derivative of the bulk modulus in monoclinic ZrO22018

    • Author(s)
      M. Fujimoto, Y. Akahama, H. Fukui, N. Hirao, and Y. Ohishi
    • Journal Title

      AIP Advances

      Volume: 8 Issue: 1 Pages: 0153101-5

    • DOI

      10.1063/1.5017774

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Coexistence of a metastable double hcp phase in bcc-fcc structure transition of Te under high pressure2018

    • Author(s)
      Y. Akahama, N. Okawa, T. Sugimoto, N. Hirao, and Y. Ohishi
    • Journal Title

      Jpn. J. App. Phys.

      Volume: 57 Issue: 2 Pages: 0256011-4

    • DOI

      10.7567/jjap.57.025601

    • NAID

      210000148602

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Raman scattering and X-ray diffraction studies on phase III of solid hydrogen2017

    • Author(s)
      Akahama Y、Mizuki Y、Nakano S、Hirao N、Ohishi Y
    • Journal Title

      J. Phys.: Conf, Series

      Volume: 950 Pages: 042060-042060

    • DOI

      10.1088/1742-6596/950/4/042060

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Presentation] 3次元ディラック物質黒リンにおけるランダウ量子化の考察2020

    • Author(s)
      藤井拓斗, 中井祐介, 上田光一, 赤浜裕一, 平田倫啓, 水戸毅, 長谷川泰正
    • Organizer
      日本物理学会2020年秋季大会(オンライン開催2020年9月8日ー11日)
    • Related Report
      2020 Annual Research Report
  • [Presentation] 圧力誘起ディラック電子物質黒リンの高圧下構造パラメータを用いたバンド構造計算2020

    • Author(s)
      藤井拓斗, 中井祐介, 上田光一, 赤浜裕一, 水戸毅, 宮川仁, 谷口尚, 佐野亜沙美, 服部高典, 町田真一
    • Organizer
      日本物理学会2020年秋季大会(オンライン開催2020年9月8日ー11日)
    • Related Report
      2020 Annual Research Report
  • [Presentation] 金属チタンの圧力誘起によるbcc相への構造転移2020

    • Author(s)
      赤浜裕一,河口沙織, 平尾直久, 大石泰生
    • Organizer
      日本物理学会第75回年次大会(名古屋大学東山キャンパス2020年3月16日~19日)
    • Related Report
      2019 Research-status Report
  • [Presentation] Volume compression of period 4 elements: Zn, Ge, As, and Se up to multimegabar pressures2019

    • Author(s)
      Y. Akahama, K. Kamiue, N. Okawa, S. Kawaguchi, N. Hirao, and Y. Ohishi
    • Organizer
      The 57th European High Pressure Research Group Meeting on High Pressure Science and Technology: (EHPRG2019) September 1-6, 2019, Hotel Duo, Prague, Czech Republic
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] 固体酸素ε相のO8クラスターの変形と分子振動の相関2019

    • Author(s)
      赤浜 裕一,藤久 裕司,平尾 直久,大石 泰生
    • Organizer
      日本物理学会2019秋季大会(岐阜大学 2019年9月10-13日)
    • Related Report
      2019 Research-status Report
  • [Presentation] 水素超臨界流体相の高圧X線回折研究II2019

    • Author(s)
      赤浜 裕一・中野 智志・河口 沙織・平尾 直久・大石 泰生
    • Organizer
      日本高圧力学会第60回高圧討論会 北海道札幌市かでる2・7 北海道立道民活動センター2019.10.23-25
    • Related Report
      2019 Research-status Report
  • [Presentation] 単斜晶ハフニアの高圧下の弾性ソフト化2019

    • Author(s)
      赤浜 裕一・福井 宏之・河口 沙織・平尾 直久・大石 泰生
    • Organizer
      日本高圧力学会第60回高圧討論会 北海道札幌市かでる2・7 北海道立道民活動センター2019.10.23-25
    • Related Report
      2019 Research-status Report
  • [Presentation] Reentrant structure transition of indium at 130 GPa2018

    • Author(s)
      Y. Akahama, K. Kamiue, K. Takahashi, N. Hirao, and Y. Ohishi
    • Organizer
      The 18th International Conference on High Pressure in Semiconductor Physics (HPSP-18) & The Workshop on High pressure Study on Superconducting (WHS), (Barcelona, Spain July 23-27, 2018)
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Pressure and Magnetic Field Angle Dependence of Magnetoresistance of Black Phosphorous under Pulsed Magnetic Fields2018

    • Author(s)
      A. Miyake, K. Akiba, M. Kano, Y. Akahama, K. Kindo and M. Tokunaga
    • Organizer
      The 12th International Conference on Research in High Magnetic Fields (RHMF 2018), (Santa Fe, NM USA June 24-28, 2018)
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] 水素の圧力誘起超臨界流体相-固相転移のラマン分光とX線回折研究2018

    • Author(s)
      1)宮本椋介、福井宏之、赤浜裕一、中野智志、 河口沙織、平尾直久、大石泰生
    • Organizer
      日本物理学会2018年秋季大会 同志社大学 2018年 9月 9日-12日
    • Related Report
      2018 Research-status Report
  • [Presentation] 水素超臨界流体相の高圧X線回折研究2018

    • Author(s)
      赤浜 裕一・中野 智志・河口 沙織・平尾 直久・大石 泰生
    • Organizer
      第59回高圧討論会 岡山理科大学2018年11月26日
    • Related Report
      2018 Research-status Report
  • [Presentation] 昔、今、そして明日の高圧研究-物質理学から-2018

    • Author(s)
      赤浜裕一
    • Organizer
      第59回高圧討論会 岡山理科大学2018年11月26日~28日
    • Related Report
      2018 Research-status Report
    • Invited
  • [Presentation] 超高圧X線回折によるSeとTeの構造相転移の研究2018

    • Author(s)
      大川 直樹・赤浜 裕一・河口 沙織・平尾 直久・大石 泰生
    • Organizer
      第59回高圧論会 岡山理科大学2018年11月26日~28日
    • Related Report
      2018 Research-status Report
  • [Presentation] 第四周期元素:Zn, Ge, Asの超高圧X線回折による原子体積の研究2018

    • Author(s)
      紙上 昂大・赤浜 裕一・河口 沙織・平尾 直久・大石 泰生
    • Organizer
      第59回高圧討論会 岡山理科大学2018年11月26日~28日
    • Related Report
      2018 Research-status Report
  • [Presentation] 固体水素III 相のX 線回折実験III2017

    • Author(s)
      赤浜裕一, 紙上昂大, 中野智志, 河口沙織, 平尾直久, 大石泰生
    • Organizer
      日本高圧力学会 第58回高圧討論会
    • Related Report
      2017 Research-status Report
  • [Presentation] Se とTe の圧力誘起構造相転移2017

    • Author(s)
      大川直樹, 赤浜裕一, 平尾直久, 大石泰生, 藤久裕司
    • Organizer
      日本高圧力学会 第58回高圧討論会
    • Related Report
      2017 Research-status Report
  • [Presentation] 高圧下におけるZrO2 単斜晶相の圧縮異常2017

    • Author(s)
      藤本真人, 福井宏之, 赤浜裕一, 平尾直久, 服部高典, 佐野 亜沙美
    • Organizer
      日本高圧力学会 第58回高圧討論会
    • Related Report
      2017 Research-status Report
  • [Presentation] ヒ素の超高圧X 線回折実験2017

    • Author(s)
      紙上昂大, 赤浜裕一, 平尾直久, 大石泰生
    • Organizer
      日本高圧力学会 第58回高圧討論会
    • Related Report
      2017 Research-status Report

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Published: 2017-04-28   Modified: 2022-01-27  

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