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Iron titanium oxyhydroxide as a water transporter into the Earths deep mantle

Research Project

Project/Area Number 17K05713
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Petrology/Mineralogy/Economic geology
Research InstitutionTeikyo University of Science & Technology

Principal Investigator

MATSUKAGE Kyoko N.  帝京科学大学, 総合教育センター/自然環境学科, 教授 (80343078)

Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2019: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2018: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2017: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywords水 / 鉄チタン水酸化物 / 地球内部 / 海洋プレート / 高圧含水相 / 沈み込み帯 / マントル / 高温高圧実験
Outline of Final Research Achievements

We experimentally discovered new hydrous phases, FeTi oxyhydroxides (FeOOH-TiO2). To determine the phase relation of these phases in subducting basaltic system, we performed experiments of basalt + H2O system by using multi-anvil apparatus at 10-23 GPa and 750-1200°C. We found that the phase with α-PbO2 type crystal structure was stable at wide pressure range at deep upper mantle and mantle transition zone at slab temperatures. In this system, lawsonite is a major hydrous mineral in the upper mantle, although it dehydrates at ~10 GPa. Our study indicates that the FeTi oxyhydroxide represents the main carrier of water at depths beneath the lawsonite stability field. After dehydration of FeTi oxyhydroxide at ~19 GPa, CaTi perovskite was formed as a Ti-bearing phase, and Al-bearing phase D was stable as a hydrous phase. Our findings suggest that water transport in the Earth’s deep interior by basaltic crust is probably much more efficient than had been previously thought.

Academic Significance and Societal Importance of the Research Achievements

本研究の結論として、鉄チタン水酸化物が地球の深さ300~600kmで安定に存在しうること、この領域での主要な水成分の運び手及びリザバーであること、が示された。海洋地殻物質は元来我々研究者が考えていたよりも、効率的に水成分を地球深部に運搬・保持し、地球内部の化学進化過程に影響を与えていると考えられる。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Research-status Report
  • 2017 Research-status Report
  • Research Products

    (10 results)

All 2020 2019 2018 2017 Other

All Int'l Joint Research (2 results) Journal Article (5 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 4 results,  Open Access: 2 results) Presentation (3 results) (of which Int'l Joint Research: 1 results)

  • [Int'l Joint Research] Guangzhou Institute of Geochemistry(中国)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] Guangzhou Institute of Geochemistry(中国)

    • Related Report
      2018 Research-status Report
  • [Journal Article] 沈み込む海洋地殻の液滴による上部マントル深部からマントル遷移層への水輸送2020

    • Author(s)
      松影香子
    • Journal Title

      新地球(印刷中)

      Volume: 1 Pages: 27-32

    • Related Report
      2019 Annual Research Report
    • Open Access
  • [Journal Article] Stability of hydrous phases of Al-rich phase D and Al-rich phase H in deep subducted oceanic crust2019

    • Author(s)
      Xingcheng Liu, Kyoko N. Matsukage, Yu Nishihara, Toshihiro Suzuki, and Eiichi Takahashi
    • Journal Title

      American Mineralogist

      Volume: 104 Issue: 1 Pages: 64-72

    • DOI

      10.2138/am-2019-6559

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Stability of hydrous minerals of Al-phase D and Al-phase H in deep subducted oceanic crust2019

    • Author(s)
      Liu, X., K.N. Matsukage, Y. Nishihara, T. Suzuki and E. Takahashi
    • Journal Title

      American Mineralogists

      Volume: 104 Issue: 8 Pages: 64-72

    • DOI

      10.1029/2018jb015973

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Aqueous fluid connectivity in subducting oceanic crust at the mantle transition zone conditions2018

    • Author(s)
      Liu, X., K.N. Matsukage, Y. Li, E. Takahashi, T. Suzuki, X. Xiong
    • Journal Title

      Journal of Geophysical Research

      Volume: 123 Pages: 1-12

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Morphological stability of hydrous liquid droplets at grain boundaries of eclogite minerals in the deep upper mantle2017

    • Author(s)
      Matsukage, K.N., M. Hashimoto and Y. Nishihara
    • Journal Title

      Journal of Mineralogical and Petrological Sciences

      Volume: 112 Issue: 6 Pages: 346-358

    • DOI

      10.2465/jmps.170309

    • NAID

      130006287887

    • ISSN
      1345-6296, 1349-3825
    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Open Access
  • [Presentation] 沈み込む海洋地殻による上部マントル下部の水輸送2019

    • Author(s)
      松影香子
    • Organizer
      マントル研究集会(東京大学大気海洋研究所シンポジウム)
    • Related Report
      2019 Annual Research Report
  • [Presentation] 上部マントル物質の高温高圧実験からの制約2019

    • Author(s)
      松影香子
    • Organizer
      マントルかんらん岩とオフィオライト研究会(金沢大学シンポジウム)
    • Related Report
      2019 Annual Research Report
  • [Presentation] Iron-titanium oxyhydroxide as a water transporter into the Earth’s mantle transition zone and lower mantle2018

    • Author(s)
      Matsukage, K.N., Y. Nishihara, X. Liu, Y. Seto, E. Takahashi
    • Organizer
      International Mineralogical Association (IMA) 2018
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research

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Published: 2017-04-28   Modified: 2021-02-19  

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