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Cross-border pollution from China to Chugoku district estimated by sulfur and oxygen isotopic ratios of rain sulfate

Research Project

Project/Area Number 17K05716
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Geochemistry/Cosmochemistry
Research InstitutionOkayama University

Principal Investigator

Chiba Hitoshi  岡山大学, 自然科学研究科, 特命教授 (30144736)

Project Period (FY) 2017-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2019: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2018: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2017: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Keywords降水硫酸 / 越境汚染 / 硫黄同位体比 / 酸素同位体比 / ストロンチウム同位体比 / 鉛同位体比 / 酸性降下物 / 硫酸イオン
Outline of Final Research Achievements

Monthly precipitations are collected for 4 years at 5 sampling stations which are located north-south from Tottori Prefecture at The Sea of Japan side to Okayama Prefecture at The Seto Inland Sea side. Their major chemistry and sulfur and oxygen isotopic composition of sulfate ion are analyzed. Seasonal variation of sulfur isotopic ratio of non-seasalt sulfate is high at winter season and low at summer season and is the same as the results obtained in other area in Japan. Seasonal variation of oxygen isotope ratio of non-seasalt sulfate, which is first analyzed in this study, is high at spring season and low in autumn season and is clearly different from the seasonal variation of sulfur isotope ratio. These two different seasonal variations indicate that yellow sand carried to Japan mainly at spring season is one of the source material of rain sulfate, which is not considered as a source material of rain sulfate before this study.

Academic Significance and Societal Importance of the Research Achievements

降水硫酸の酸素同位体比を初めて測定した。結果は硫黄同位体比と異なる春期に高く秋期に低い季節変動を示した。硫黄同位体比の冬期に高く夏期に低い季節変動と合わせて考察することにより,降水中の硫酸イオンには,これまで硫黄同位体比のみを用いた研究では考慮されていなかった黄砂が降水硫酸の重要な起源物質の一つであることが明らかになった。本研究の成果は,降水硫酸の起源物質の研究のみならず,浮遊粒子状物質(PM2.5やSPM)の水溶性物質に含まれている硫酸イオンの起源推定にも酸素同位体比が重要な指標となることを示している。

Report

(5 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Research-status Report
  • 2018 Research-status Report
  • 2017 Research-status Report
  • Research Products

    (8 results)

All 2020 2019 2018 2017

All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (7 results) (of which Int'l Joint Research: 1 results,  Invited: 1 results)

  • [Journal Article] Geochemical and isotopic imprints of groundwater evolution in mountainous areas of Maniwa City, Okayama Prefecture, Japan2020

    • Author(s)
      Konishi Ayumi、Fujiike Tatsuya、Okano Osamu、Chiba Hitoshi、Ueda Akira
    • Journal Title

      Groundwater for Sustainable Development

      Volume: 11 Pages: 100412-100412

    • DOI

      10.1016/j.gsd.2020.100412

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Presentation] 鳥取-岡山の降水硫酸と岡山市の浮遊粒子状物質中の水溶性硫酸イオンの 硫黄・酸素同位体比2020

    • Author(s)
      千葉 仁、藤池 竜也、山本 翼
    • Organizer
      日本地球惑星科学連合2020年大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 中国地方における降水硫酸と岡山市の浮遊粒子状物質の水溶性硫酸イオンの硫黄・酸素同位体比2020

    • Author(s)
      千葉 仁、藤池 竜也、山本 翼
    • Organizer
      第10回同位体環境学シンポジウム
    • Related Report
      2020 Annual Research Report
  • [Presentation] Chemistry and sulfur and oxygen isotope ratios of sulfate ion of water soluble component of suspended particulate matter at Okayama city2019

    • Author(s)
      Hitoshi CHIBA, Tsubasa YAMAMOTO
    • Organizer
      日本地球惑星科学連合2019年大会(幕張メッセ)
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] 岡山市における浮遊粒子状物質(SPM,PM2.5)の可溶性成分の化学組成と硫酸イオンの硫黄・酸素同位体比2018

    • Author(s)
      山本翼,千葉仁
    • Organizer
      日本地球化学会第65回年会(琉球大学)
    • Related Report
      2018 Research-status Report
  • [Presentation] 中国地方の降水硫酸および中国沙漠砂中の硫酸イオンの硫黄・酸素同位体比2018

    • Author(s)
      千葉仁,藤池竜也,毛惠星,三上莉奈
    • Organizer
      日本地球惑星科学連合2018年大会(幕張メッセ)
    • Related Report
      2018 Research-status Report
  • [Presentation] 硫黄同位体比と酸素同位体比を用いた中国地方の降水中の硫酸イオンの起源の推定 -予察-2017

    • Author(s)
      藤池竜也,毛恵星,千葉 仁
    • Organizer
      日本地球惑星科学連合2017年会
    • Related Report
      2017 Research-status Report
    • Invited
  • [Presentation] 硫黄同位体比と酸素同位体比を用いた中国地方の降水中の硫酸イオンの起源の推定2017

    • Author(s)
      藤池竜也,毛恵星,千葉 仁
    • Organizer
      日本地球化学会第64会年会
    • Related Report
      2017 Research-status Report

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Published: 2017-04-28   Modified: 2022-01-27  

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