• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Characterization of interracial pH using surface forces apparatus fluorescence spectroscopy

Research Project

Project/Area Number 17K05740
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Physical chemistry
Research InstitutionTohoku University

Principal Investigator

Kasuya Motohiro  東北大学, 多元物質科学研究所, 助教 (00582040)

Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2019: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2018: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2017: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywords表面・界面 / 表面力装置 / pH / 電気二重層 / 固-液界面 / 蛍光プローブ法 / 表面力測定 / 表面・界面物性
Outline of Final Research Achievements

We evaluated the interfacial pH values in aqueous electrolyte solutions between solid surfaces from fluorescence spectrum of a pH probe measured using surface forces apparatus (SFA) fluorescence spectroscopy, which we developed. We evaluated them with varying concentrations and ion species of the electrolytes and solid surfaces such as mica, silica and aluminium. We also performed measured the electric double layer (EDL) force using the same SFA, which provided the surface potentials and charge densities at the interfaces. From the results, we studied how much these factors affects the interfacial pH values.

Academic Significance and Societal Importance of the Research Achievements

本研究で明らかになった界面pHを変化させる要素の解明は,固-液界面におけるイオン挙動の理解に重要な基礎的な知見である.生体界面におけるたんぱく質等の生体分子の挙動や電極や触媒界面におけるpHの影響する化学反応の理解に貢献すると期待される.

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Research-status Report
  • 2017 Research-status Report
  • Research Products

    (22 results)

All 2019 2018 2017 Other

All Int'l Joint Research (1 results) Journal Article (9 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 9 results,  Open Access: 2 results) Presentation (11 results) (of which Int'l Joint Research: 8 results,  Invited: 1 results) Patent(Industrial Property Rights) (1 results) (of which Overseas: 1 results)

  • [Int'l Joint Research] Ecole centrale de Lyon/CNRS(フランス)

    • Related Report
      2019 Annual Research Report
  • [Journal Article] Ice Premelting Layer Studied by Resonance Shear Measurement (RSM)2019

    • Author(s)
      Lecadre Florian、Kasuya Motohiro、Kanno Yuji、Kurihara Kazue
    • Journal Title

      Langmuir

      Volume: 35 Issue: 48 Pages: 15729-15733

    • DOI

      10.1021/acs.langmuir.9b02451

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Selection of Polymerizable Functional Group of Adhesive Monolayer to Control Monomer Viscosity under Confinement in Silica Nano-gaps2019

    • Author(s)
      Ito Shunya、Kasuya Motohiro、Kurihara Kazue、Nakagawa Masaru
    • Journal Title

      Chemistry Letters

      Volume: 48 Issue: 8 Pages: 943-946

    • DOI

      10.1246/cl.190273

    • NAID

      130007687716

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Viscoelasticity of Rubber?Ice Interfaces Under Shear Studied Using Low-Temperature Surface Forces Apparatus2019

    • Author(s)
      Hemmette Sylvain、Kasuya Motohiro、Lecadre Florian、Kanno Yuji、Mazuyer Denis、Cayer-Barrioz Juliette、Kurihara Kazue
    • Journal Title

      Tribology Letters

      Volume: 67 Issue: 3 Pages: 67-74

    • DOI

      10.1007/s11249-019-1187-2

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Low-Temperature Surface Force Apparatus to Determine Interactions between Ice and Silica Surface2018

    • Author(s)
      Florian Lecadre, Motohiro Kasuya, Aya Harano, Yuji Kanno, Kazue Kurihara
    • Journal Title

      Langmuir

      Volume: 34 Issue: 38 Pages: 11311-11315

    • DOI

      10.1021/acs.langmuir.8b01902

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Selection of diacrylate monomers for sub-15 nm ultraviolet nanoimprinting by resonance shear measurement2018

    • Author(s)
      Ito Shunya、Kasuya Motohiro、Kurihara Kazue、Nakagawa Masaru
    • Journal Title

      Langmuir

      Volume: 34 Issue: 32 Pages: 9366-9375

    • DOI

      10.1021/acs.langmuir.8b01881

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Surface forces between hydrophilic silica surfaces in a moisture-sensitive oleophilic diacrylate monomer liquid2018

    • Author(s)
      Ito Shunya、Kasuya Motohiro、Kurihara Kazue、Nakagawa Masaru
    • Journal Title

      AIP Advances

      Volume: 8 Issue: 2 Pages: 025122-025122

    • DOI

      10.1063/1.4991630

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Nanotribological Characterization of Lubricants between Smooth Iron Surfaces2017

    • Author(s)
      Motohiro Kasuya, Kazuhito Tomita, Masaya Hino, Masashi Mizukami, Hiroyuki Mori, Seiji Kajita, Toshihide Ohmori, Atsushi Suzuki, and Kazue Kurihara
    • Journal Title

      Langmuir

      Volume: in print Issue: 16 Pages: 3941-3948

    • DOI

      10.1021/acs.langmuir.7b00148

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] 2.Nanometer-Resolved Fluidity of an Oleophilic Monomer between Silica Surfaces Modified with Fluorinated Monolayers for Nanoimprinting2017

    • Author(s)
      Shunya Ito, Motohiro Kasuya, Kazue Kurihara, Masaru Nakagawa
    • Journal Title

      ACS Appl. Mater. Interfaces

      Volume: 9 Issue: 7 Pages: 6591-6598

    • DOI

      10.1021/acsami.6b15139

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Characterization of Platinum Electrode Surfaces by Electrochemical Surface Forces Measurement2017

    • Author(s)
      Fujii Sho、Kasuya Motohiro、Kurihara Kazue
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 121 Issue: 47 Pages: 26406-26413

    • DOI

      10.1021/acs.jpcc.7b09301

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Presentation] Low-temperature Surface Forces Apparatus and Application2019

    • Author(s)
      Lecadre, Florian; Hemmette, Sylvain; Kasuya, Motohiro; Kanno, Yuji; Kurihara, Kazue
    • Organizer
      33rd of The European Colloid and Interface Society (ECIS2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Low-temperature Surface Forces Apparatus2019

    • Author(s)
      Kazue Kurihara, Florian Lecadre, Sylvain Hemmette, Motohiro Kasuya, Yuji Kanno
    • Organizer
      Okinawa Colloid 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Interaction among the Dissolving Species in Li Electrolyte/Metal Oxide Using Binary Solvent for Ionic Conduction2019

    • Author(s)
      Minoru Mizuhata, Nobuaki Kunikata, Yoshimasa Suzuki, Hideshi Maki, Masaki Matsui, Kazue Kurihara, Motohiro Kasuya
    • Organizer
      Okinawa Colloid 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Precise Characterization of Electric Double Layer of Electrode Using Electrochemical Surface Forces Apparatus2019

    • Author(s)
      Motohiro Kasuya, Kazue Kurihara
    • Organizer
      Okinawa Colloid 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 蛍光分光表面力装置を用いた閉じ込め液体中におけるピレンエキシマーの反応ダイナミクス評価2018

    • Author(s)
      粕谷素洋、栗原和枝
    • Organizer
      第69回コロイドおよび界面化学討論会
    • Related Report
      2018 Research-status Report
  • [Presentation] Evaluation of Interfacial pH Using Surface Forces Apparatus Fluorescence Spectroscopy2018

    • Author(s)
      佐野優花, 粕谷素洋, 栗原和枝
    • Organizer
      平成30年度化学系学協会東北大会
    • Related Report
      2018 Research-status Report
  • [Presentation] Surface Segregation of Fluorescent Dyes in Thin Films of Nanoimprintable UV-Cured Resins Studied by Evanescent Wave-Induced Fluorescence Microscopy and Spectroscopy2018

    • Author(s)
      Shunya Ito, Hamid Soleimaninejad, Motohiro Kasuya, Masaru Nakagawa, and Trevor A. Smith
    • Organizer
      International workshop on Mineral processing and Metallurgy 2018 (IMM2018)
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Evaluation of Interfacial pH Using Surface Forces Apparatus Fluorescence Spectroscopy2018

    • Author(s)
      Yuka Sano, Motohiro Kasuya, Kazue Kurihara
    • Organizer
      the 16th Conference of the International Association of Colloid and Interface Scientists (IACIS2018)
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Precise Characterization of Electric Double Layer of Electrode Using Electrochemical Surface Forces Apparatus2018

    • Author(s)
      M. Kasuya, K. Kurihara
    • Organizer
      Kick-off Symposium for World Leading Research Centers
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] 固-水界面におけるpHに対する電解質添加の効果の蛍光分光表面力装置による評価2017

    • Author(s)
      佐野優花、粕谷素洋、栗原和枝
    • Organizer
      第68回コロイド界面化学討論会
    • Related Report
      2017 Research-status Report
  • [Presentation] Characterization of ferrocene-modified electrode using electrochemical surface forces apparatus2017

    • Author(s)
      M. Kasuya, K. Kurihara
    • Organizer
      Kolloid-Tagung and FCS-Workshop Conference
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Patent(Industrial Property Rights)] 共振ずり測定装置2019

    • Inventor(s)
      粕谷素洋,水上雅史,栗原和枝
    • Industrial Property Rights Holder
      粕谷素洋,水上雅史,栗原和枝
    • Industrial Property Rights Type
      特許
    • Filing Date
      2019
    • Related Report
      2019 Annual Research Report
    • Overseas

URL: 

Published: 2017-04-28   Modified: 2021-02-19  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi