Extension of deuterium NMR spectroscopy of paramagnetic solids for analysis of molecular structure
| Project/Area Number |
17K05741
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Physical chemistry
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| Research Institution | Yamagata University |
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Principal Investigator |
IIJIMA Takahiro 山形大学, 学士課程基盤教育機構, 准教授 (20402761)
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| Project Period (FY) |
2017-04-01 – 2021-03-31
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| Project Status |
Completed (Fiscal Year 2020)
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| Budget Amount *help |
¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2019: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2018: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2017: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
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| Keywords | 核磁気共鳴 / 固体 / 重水素 / 常磁性 / NMR |
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| Outline of Final Research Achievements |
Solid state NMR spectroscopy of deuterium nuclei is an indispensable tool for investigating static and dynamic molecular structures of solid materials. Most of deuterium NMR, however, has been applied for diamagnetic solids, because in paramagnetic solids the magnetization suffers from the paramagnetic interaction that affects the measurement and analysis of spectra.
In the present work, we developed two solid-state deuterium NMR methods for paramagnetic solids. One is a method for separating chemically different sites by utilizing molecular dynamics, and the other is a separation method of nuclear interactions in two-dimensional NMR. Using these methods, we can investigate static and dynamic local structures about deuterium nuclei with increased accuracy.
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| Academic Significance and Societal Importance of the Research Achievements |
本研究では常磁性化合物に対する新規な固体重水素NMR法として化学サイト分離法と相互作用分離法を開発した．測定及び解析の困難さから常磁性固体の重水素NMRによる研究例はこれまで少なかった．本研究で開発した手法は配位高分子や金属タンパク質等の興味ある系における静的・動的局所構造の解析に資する．
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Report
(5 results)
Research Products
(12 results)
