| Budget Amount *help |
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2019: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2018: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2017: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Outline of Final Research Achievements |
(1) A dimer molecule in which two biphenyls were linked by alkyl chains was synthesized in a higher yield than previously reported. While reducing this molecule, electronic absorption measurements and resonance Raman spectroscopy were performed to clarify the mechanism of anion species formation. (2) Near-infrared resonance Raman measurements on radical cation of benzene dimer were performed to elucidate the interaction between a delocalized electron and large-amplitude molecular vibrations. (3) We manufactured a motor-integrated infrared transmission liquid rotary cell to which various commercially available solution cells can be attached. (4) Raman measurements and analyses based on density functional theory calculations on various isotope-substituted benzenes, and ultrafast infrared spectroscopic measurements of photoresponsive metal complexes and high-speed photochromic molecules were also performed.
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