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Creation of polycyclic aromatic compound type fused-azulenes aimed for the organic electronics

Research Project

Project/Area Number 17K05780
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Organic chemistry
Research InstitutionShinshu University

Principal Investigator

Shoji Taku  信州大学, 学術研究院理学系, 准教授 (60581014)

Project Period (FY) 2017-04-01 – 2022-03-31
Project Status Completed (Fiscal Year 2021)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2020: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2019: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2018: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2017: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywordsアズレン / 縮環アズレン / 多環式芳香族化合物 / 含窒素複素環 / 発光性色素 / エレクトロクロミズム / 有機電子材料 / 多環式芳香環 / チオフェン / 環化付加反応 / ドナー・アクセプターシステム / 芳香族求核置換反応 / 芳香族イミド / 環化縮合反応 / 有機合成化学
Outline of Final Research Achievements

We developed a method for the preparation of ring-fused azulene derivatives and evaluated their optical and electrochemical properties for application to organic electronics. As a result, the fused-azulene derivatives prepared in this project are found to exhibit unique fluorescent properties that are dependent on the pH of the solution. Furthermore, the the fused-azulene derivatives are also revealed to exhibit the electrochromism, which is a reversible and remarkable color change under the electrochemical redox conditions.

Academic Significance and Societal Importance of the Research Achievements

本課題で新たに合成した縮環アズレン類は電気的刺激によって顕著に色調が変化することからディスプレイ素子等の有機電子材料への応用が期待できる。また、一連の縮環アズレン類はpHに依存して発光を示すことが明らかとなったため、生体細胞の発光性染色色素等への応用にも期待がもたれる結果が得られた。

Report

(6 results)
  • 2021 Annual Research Report   Final Research Report ( PDF )
  • 2020 Research-status Report
  • 2019 Research-status Report
  • 2018 Research-status Report
  • 2017 Research-status Report
  • Research Products

    (74 results)

All 2022 2021 2020 2019 2018 2017 Other

All Journal Article (30 results) (of which Peer Reviewed: 30 results,  Open Access: 3 results) Presentation (34 results) (of which Int'l Joint Research: 1 results,  Invited: 1 results) Book (1 results) Remarks (9 results)

  • [Journal Article] Synthesis, Reactivity, and Properties of Benz[a]azulenes via the [8 + 2] Cycloaddition of 2-H-Cyclohepta[b]furan-2-ones with an Enamine2022

    • Author(s)
      Shoji Taku、Yamazaki Akari、Katoh Ryuzi、Shimamura Konomi、Sakai Rina、Yasunami Masafumi、Okujima Tetsuo、Ito Shunji
    • Journal Title

      The Journal of Organic Chemistry

      Volume: - Issue: 9 Pages: 5827-5845

    • DOI

      10.1021/acs.joc.2c00133

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of 8-Aryl-2-H-cyclohepta[b]furan-2-ones and Transformation into 4-Arylazulenes2022

    • Author(s)
      Shoji Taku、Ando Daich、Yamazaki Akari、Ariga Yukino、Hamasaki Atom、Mori Shigeki、Okujima Tetsuo、Ito Shunji
    • Journal Title

      Chemistry Letters

      Volume: - Issue: 5 Pages: 533-537

    • DOI

      10.1246/cl.220076

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Sensitive screening of methamphetamine stimulant using potential-modulated electrochemiluminescence2022

    • Author(s)
      Takahashi Fumiki、Nitta Saki、Shimizu Ryo、Shoji Taku、Tatsumi Hirosuke、Jin Jiye
    • Journal Title

      Analytica Chimica Acta

      Volume: 1191 Pages: 339229-339229

    • DOI

      10.1016/j.aca.2021.339229

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Azuleno[6,5-b]Indoles: Palladium-Catalyzed Oxidative Ring-Closing Reaction of 6-(Arylamino)Azulenes2022

    • Author(s)
      Taku Shoji, Yukino Ariga, Shunji Ito, and Masafumi Yasunami
    • Journal Title

      Heterocycles

      Volume: - Issue: 1 Pages: 383-383

    • DOI

      10.3987/com-21-s(r)5

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ion Transfer Voltammetry of Azulene Sulfonates at a Liquid|Liquid Interface2021

    • Author(s)
      YAJIMA Satoshi、SHOJI Taku、TATSUMI Hirosuke
    • Journal Title

      BUNSEKI KAGAKU

      Volume: 70 Issue: 9 Pages: 529-533

    • DOI

      10.2116/bunsekikagaku.70.529

    • NAID

      130008116861

    • ISSN
      0525-1931
    • Year and Date
      2021-09-05
    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Azulene Derivatives from 2H-Cyclohepta[b]furan-2-ones as Starting Materials: Their Reactivity and Properties2021

    • Author(s)
      Shoji Taku、Ito Shunji、Yasunami Masafumi
    • Journal Title

      International Journal of Molecular Sciences

      Volume: 22 Issue: 19 Pages: 10686-10686

    • DOI

      10.3390/ijms221910686

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis, Photophysical and Electrochemical Properties of 1-, 2-, and 6-(2-Benzofuryl)azulenes2021

    • Author(s)
      Shoji Taku、Ariga Yukino、Yamazaki Akari、Uda Mayumi、Nagasawa Takuya、Ito Shunji
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 94 Issue: 3 Pages: 1000-1009

    • DOI

      10.1246/bcsj.20200311

    • NAID

      130008021842

    • Related Report
      2020 Research-status Report
    • Peer Reviewed
  • [Journal Article] Azulene‐Substituted Donor‐Acceptor Polymethines and 1,6’‐Bi‐, 1,6′;3,6′′‐Ter‐, and Quinqueazulenes via Zincke Salts: Synthesis, and Structural, Optical, and Electrochemical Properties2021

    • Author(s)
      Shoji Taku、Yamazaki Akari、Ariga Yukino、Uda Mayumi、Ando Daichi、Sasahara Nichika、Kai Naohito、Ito Shunji
    • Journal Title

      ChemPlusChem

      Volume: 86 Issue: 6 Pages: 946-966

    • DOI

      10.1002/cplu.202100174

    • Related Report
      2020 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis of thiophene-fused heptalenes by cycloaddition of azulenothiophenes with dimethyl acetylenedicarboxylate2020

    • Author(s)
      Shoji Taku、Miura Kota、Ariga Yukino、Yamazaki Akari、Ito Shunji、Yasunami Masafumi
    • Journal Title

      Scientific Reports

      Volume: 10 Issue: 1 Pages: 12477-12477

    • DOI

      10.1038/s41598-020-69425-w

    • Related Report
      2020 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Development of Heterocycle-Substituted and Fused Azulenes in the Last Decade (2010-2020)2020

    • Author(s)
      Shoji Taku、Okujima Tetsuo、Ito Shunji
    • Journal Title

      International Journal of Molecular Sciences

      Volume: 21 Issue: 19 Pages: 7087-7087

    • DOI

      10.3390/ijms21197087

    • Related Report
      2020 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Molecular Transformation to Pyrroles, Pentafulvenes, and Pyrrolopyridines by [2+2] Cycloaddition of Propargylamines with Tetracyanoethylene2020

    • Author(s)
      Shoji Taku、Takagaki Sho、Ariga Yukino、Yamazaki Akari、Takeuchi Mutsumi、Ohta Akira、Sekiguchi Ryuta、Mori Shigeki、Okujima Tetsuo、Ito Shunji
    • Journal Title

      Chemistry - A European Journal

      Volume: 26 Issue: 9 Pages: 1931-1935

    • DOI

      10.1002/chem.201904926

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] Direct synthesis of 2-arylazulenes by [8+2] cycloaddition of 2H-cyclohepta[b]furan-2-ones with silyl enol ethers2020

    • Author(s)
      Shoji Taku、Sugiyama Shuhei、Kobayashi Yoshiaki、Yamazaki Akari、Ariga Yukino、Katoh Ryuzi、Wakui Hiroki、Yasunami Masafumi、Ito Shunji
    • Journal Title

      Chemical Communications

      Volume: 56 Issue: 10 Pages: 1485-1488

    • DOI

      10.1039/c9cc09376a

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis of phthalimides cross-conjugated with an azulene ring, and their structural, optical and electrochemical properties2020

    • Author(s)
      Shoji Taku、Iida Nanami、Yamazaki Akari、Ariga Yukino、Ohta Akira、Sekiguchi Ryuta、Nagahata Tatsuki、Nagasawa Takuya、Ito Shunji
    • Journal Title

      Organic & Biomolecular Chemistry

      Volume: 18 Issue: 12 Pages: 2274-2282

    • DOI

      10.1039/d0ob00164c

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis of azuleno[2,1-b]thiophenes by cycloaddition of azulenylalkynes with elemental sulfur and their structural, optical and electrochemical properties2019

    • Author(s)
      Shoji Taku、Miura Kota、Ohta Akira、Sekiguchi Ryuta、Ito Shunji、Endo Yuya、Nagahata Tatsuki、Mori Shigeki、Okujima Tetsuo
    • Journal Title

      Organic Chemistry Frontiers

      Volume: 6 Issue: 15 Pages: 2801-2811

    • DOI

      10.1039/c9qo00593e

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis of 6-Amino- and 6-Arylazoazulenes via Nucleophilic Aromatic Substitution and Their Reactivity and Properties2019

    • Author(s)
      Taku Shoji,* Shuhei Sugiyama, Mutsumi Takeuchi, Akira Ohta, Ryuta Sekiguchi, Shunji Ito, Tomoaki Yatsu, Tetsuo Okujima, and Masafumi Yasunami
    • Journal Title

      The Journal of Organic Chemistry

      Volume: 84 Issue: 3 Pages: 1257-1275

    • DOI

      10.1021/acs.joc.8b02648

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis of azulenophthalimides by phosphine-mediated annulation of 1,2-diformylazulenes with maleimides2019

    • Author(s)
      Taku Shoji,* Takanori Araki, Nanami Iida, Kota Miura, Akira Ohta, Ryuta Sekiguchi, Shunji Ito, and Tetsuo Okujima
    • Journal Title

      Organic Chemistry Frontiers

      Volume: 6 Issue: 2 Pages: 195-204

    • DOI

      10.1039/c8qo01121d

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis and photophysical properties of azuleno[1′,2′:4,5]pyrrolo[2,1-b]quinazoline-6,14-diones: Azulene analogs of tryptanthrin2018

    • Author(s)
      Chieko Kogawa, Asuka Fujiwara, Ryuta Sekiguchi, Taku Shoji, Jun Kawakami, Masaaki Okazaki, Shunji Ito*
    • Journal Title

      Tetrahedron

      Volume: 74 Issue: 49 Pages: 7018-7029

    • DOI

      10.1016/j.tet.2018.10.020

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] 2,2’-Biazulene diimide-based conjugate polymers for high-performance field-effect transistors2018

    • Author(s)
      Taku Shoji,* and Shunji Ito
    • Journal Title

      SCIENCE CHINA Chemistry

      Volume: 61 Issue: 8 Pages: 973-974

    • DOI

      10.1007/s11426-018-9323-2

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis of 2-Methyl-1-azulenyl Tetracyanobutadienes and Dicyanoquinodimethanes: Substituent Effect of 2-Methyl Moiety on Azulene Ring toward the Optical and Electrochemical Properties2018

    • Author(s)
      Taku Shoji,* Kota Miura, Takanori Araki, Akifumi Maruyama, Akira Ohta, Ryuta Sekiguchi, Shunji Ito, and Tetsuo Okujima
    • Journal Title

      The Journal of Organic Chemistry

      Volume: 83 Issue: 12 Pages: 6690-6705

    • DOI

      10.1021/acs.joc.8b01067

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis of 2-Amino-1-Cyanoazulenes: Substituent Effect on 2H-Cyclohepta[b]Furan-2-Ones Toward the Reaction with Malononitrile2018

    • Author(s)
      Taku Shoji,* Shuhei Sugiyama, Kota Miura, Akira Ohta, Ryuta Sekiguchi, Shunji Ito, Shigeki Mori, and Tetsuo Okujima
    • Journal Title

      Heterocycles

      Volume: 97 Issue: 2 Pages: 1068-1081

    • DOI

      10.3987/com-18-s(t)89

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Molecular Transformation of 2-Methylazulenes: An Efficient and Practical Synthesis of 2-Formyl- and 2-Ethynylazulenes2018

    • Author(s)
      Taku Shoji,* Takanori Araki, Nanami Iida, Yoshiaki Kobayashi, Akira Ohta, Ryuta Sekiguchi, Shunji Ito, Shigeki Mori, Tetsuo Okujima, and Masafumi Yasunami
    • Journal Title

      European Journal of Organic Chemistry

      Volume: 2018 Issue: 9 Pages: 1145-1157

    • DOI

      10.1002/ejoc.201701746

    • NAID

      120007100268

    • Related Report
      2018 Research-status Report 2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Tuning the Coverage of Self-assembled Monolayer by Introducing Bulky Substituents onto Rigid Adamantane Tripod2018

    • Author(s)
      Toshikazu Kitagawa, Shima Nakanishi, Aya Mizuno, Yohei Niwa, Hiroki Tabata, Katsuyuki Hirai, Takao Okazaki
    • Journal Title

      Archive for Org. Chem., ARKIVOC

      Volume: 2018 Issue: 2 Pages: 131-144

    • DOI

      10.24820/ark.5550190.p010.163

    • Related Report
      2018 Research-status Report 2017 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Synthesis of Azulene-substituted Benzofurans and Isocoumarins via Intramolecular Cyclization of 1-Ethynylazulenes, and their Structural and Optical Properties2018

    • Author(s)
      Taku Shoji,* Miwa Tanaka, Sho Takagaki, Kota Miura, Akira Ohta, Ryuta Sekiguchi, Shunji Ito, Shigeki Mori, and Tetsuo Okujima
    • Journal Title

      Organic & Biomolecular Chemistry

      Volume: 16 Issue: 3 Pages: 480-489

    • DOI

      10.1039/c7ob02861j

    • NAID

      120007100267

    • Related Report
      2018 Research-status Report 2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] The preparation and properties of heteroarylazulenes and hetero-fused azulenes2018

    • Author(s)
      Taku Shoji and Shunji Ito
    • Journal Title

      Advances in Heterocyclic Chemistry

      Volume: 126 Pages: 1-54

    • DOI

      10.1016/bs.aihch.2018.02.002

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Azulene-based Donor-Acceptor Systems: Synthesis, Optical and Electrochemical Properties2017

    • Author(s)
      Taku Shoji, and Shunji Ito
    • Journal Title

      Chemistry - A European Journal

      Volume: 23 Issue: 66 Pages: 16696-16709

    • DOI

      10.1002/chem.201702806

    • NAID

      120007100265

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Azulene-Substituted TetraarylPyrroles by Reaction of 1-Azulenyl Ketones with Benzoin and Ammonium Acetate2017

    • Author(s)
      Taku Shoji, Sho Takagaki, Miwa Tanaka, Takanori Araki, Shuhei Sugiyama, Ryuta Sekiguchi, Akira Ohta, Shunji Ito, and Tetsuo Okujima
    • Journal Title

      Heterocycles

      Volume: 94 Issue: 10 Pages: 1870-1883

    • DOI

      10.3987/com-17-13781

    • NAID

      120007100271

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis of 2-amino- and 2-arylazoazulenes via nucleophilic aromatic substitution of 2-chloroazulenes with amines and arylhydrazines2017

    • Author(s)
      Taku Shoji,* Shuhei Sugiyama, Takanori Araki, Akira Ohta, Ryuta Sekiguchi, Shunji Ito, Shigeki Mori, Tetsuo Okujima, and Masafumi Yasunami
    • Journal Title

      Organic & Biomolecular Chemistry

      Volume: 15 Issue: 18 Pages: 3917-3923

    • DOI

      10.1039/c7ob00691h

    • NAID

      120007100284

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis of 2-Aminofurans by Sequential [2 + 2] Cycloaddition-Nucleophilic Addition of 2-Propyn-1-ols with Tetracyanoethylene and Amine-Induced Transformation into 6-Aminopentafulvenes2017

    • Author(s)
      Taku Shoji,* Daichi Nagai, Miwa Tanaka, Takanori Araki, Akira Ohta, Ryuta Sekiguchi, Shunji Ito, Shigeki Mori, and Tetsuo Okujima
    • Journal Title

      Chemistry - A European Journal

      Volume: 23 Issue: 21 Pages: 5126-5136

    • DOI

      10.1002/chem.201700121

    • NAID

      120007100266

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis of 2-Azulenyltetrathiafulvalenes by Palladium-catalyzed Direct Arylation of 2-Chloroazulenes with Tetrathiafulvalene and Their Optical and Electrochemical Properties2017

    • Author(s)
      Taku Shoji,* Takanori Araki, Shuhei Sugiyama, Akira Ohta, Ryuta Sekiguchi, Shunji Ito, Tetsuo Okujima, and Kozo Toyota
    • Journal Title

      The Journal of Organic Chemistry

      Volume: 82 Issue: 3 Pages: 1657-1665

    • DOI

      10.1021/acs.joc.6b02818

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Electrochemical Properties of Azulene-Substituted Tetracyanobutadiene and Dicyanoquinodimethane Chromophores Connected with Naphthalene Cores2017

    • Author(s)
      Taku Shoji,* Mitsuhisa Maruyama, Akifumi Maruyama, Daichi Nagai, Miwa, Tanaka, Ryuta Sekiguchi, Shunji Ito, Tetsuo Okujima
    • Journal Title

      Heterocycles

      Volume: 95 Issue: 1 Pages: 353-369

    • DOI

      10.3987/com-16-s(s)25

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Presentation] Reactivity of Azulenylpropargylamines with Tetracyanoethylene: Synthesis of Pyrroles, Pentafulvenes, and Pyrropyridines via [2 + 2] Cycloaddition Reaction2020

    • Author(s)
      Taku Shoji, Yukino Ariga, Akari Yamazaki
    • Organizer
      第100回日本化学会春季年会
    • Related Report
      2019 Research-status Report
  • [Presentation] Synthesis and Photophysical Properties of Benzo and Naphthoazulenes2020

    • Author(s)
      Akari Yamazaki, Taku Shoji
    • Organizer
      第100回日本化学会春季年会
    • Related Report
      2019 Research-status Report
  • [Presentation] ベンゾアズレン類の合成と光学特性2020

    • Author(s)
      Yukino Ariga, Taku Shoji
    • Organizer
      第100回日本化学会春季年会
    • Related Report
      2019 Research-status Report
  • [Presentation] Effect on the 2-Heteroaryl Substituents as a Directing Group for the Palladium-catalyzed C-H Activation Arylation of Azulenes at the 1,3-Positions2020

    • Author(s)
      Yoshihiro Ogasawara, Takuya Nagasawa, Tomoaki Yatsu, Taku Shoji, Jun Kawakami, Shunji Ito
    • Organizer
      第100回日本化学会春季年会
    • Related Report
      2019 Research-status Report
  • [Presentation] Palladium-catalyzed Selective Arylation of Azulenes at the 1,3-Positions based on the C-H Activation by Utilizing 2-Pyridyl Substituent as a Directing group2020

    • Author(s)
      Takuya Nagasawa, Tomoaki Yatsu, Yoshihiro Ogasawara, Taku Shoji, Jun Kawakami, Shunji Ito
    • Organizer
      第100回日本化学会春季年会
    • Related Report
      2019 Research-status Report
  • [Presentation] Synthesis and Reactivity of Azulenophthalimides and Their Structural, Optical and Electrochemical Properties2019

    • Author(s)
      Taku Shoji, Takanori Araki, Akira Ohta, Ryuta Sekiguchi, Shunji Ito
    • Organizer
      18th International Symposium on Novel Aromatic Compounds [ISNA-18]
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Synthesis and Properties of Thiophene-fused Tryptanthrin Congeners2019

    • Author(s)
      阿部幹弥、太田哲、庄子卓、関口龍太
    • Organizer
      2019年度化学系学協会東北大会
    • Related Report
      2019 Research-status Report
  • [Presentation] Synthesis and Properties of Novel Tryptanthrin Congeners Containing Azulene Skeleton2019

    • Author(s)
      中澤悠平、鈴木紅音、太田哲、庄子卓、伊東俊司、関口龍太
    • Organizer
      2019年度化学系学協会東北大会
    • Related Report
      2019 Research-status Report
  • [Presentation] Synthesis of Azulene-substituted Phthalimides by [4 + 2] Cycloaddition of 2-Aminofurans with Maleimides2019

    • Author(s)
      庄子卓、飯田七海、太田哲、関口龍太、伊東俊司
    • Organizer
      2019年度化学系学協会東北大会
    • Related Report
      2019 Research-status Report
  • [Presentation] Synthesis and Photophysical Properties of 2-Phenylazulenes2019

    • Author(s)
      Taku Shoji, Shuhei Sugiyama, Hiroki Wakui, Ryuzi Kato, Masafumi Yasunami, Shunji Ito
    • Organizer
      2019年度化学系学協会東北大会
    • Related Report
      2019 Research-status Report
  • [Presentation] Synthetic Study of Azulene-fused BODIPY2019

    • Author(s)
      城島一暁、石野さくら、太田哲、庄子卓、関口龍太
    • Organizer
      2019年度化学系学協会東北大会
    • Related Report
      2019 Research-status Report
  • [Presentation] アズレン縮環フタルイミドの合成と光学特性2019

    • Author(s)
      庄子卓、荒木貴訓、飯田七海、三浦孝太、太田哲、関口龍太、伊東俊司
    • Organizer
      第30回基礎有機化学討論会
    • Related Report
      2019 Research-status Report
  • [Presentation] アズレノペンタフルベン誘導体の合成と光学特性2019

    • Author(s)
      三浦孝太、庄子卓、太田哲、関口龍太
    • Organizer
      第30回基礎有機化学討論会
    • Related Report
      2019 Research-status Report
  • [Presentation] アズレン骨格を有する新規トリプタンスリン類縁体の合成と物性2019

    • Author(s)
      中澤悠平、鈴木紅音、太田哲、庄子卓、伊東俊司、関口龍太
    • Organizer
      第50回中部化学関係学協会支部連合秋季大会
    • Related Report
      2019 Research-status Report
  • [Presentation] アズレン縮環BODIPYの合成研究2019

    • Author(s)
      城島一暁、石野さくら、太田哲、庄子卓、関口龍太
    • Organizer
      第50回中部化学関係学協会支部連合秋季大会
    • Related Report
      2019 Research-status Report
  • [Presentation] 縮環アズレンを基盤としたスクアライン誘導体の合成と光学特性2019

    • Author(s)
      三浦孝太、庄子卓、太田哲、関口龍太
    • Organizer
      第50回中部化学関係学協会支部連合秋季大会
    • Related Report
      2019 Research-status Report
  • [Presentation] 硫黄とアズレニルアルキン類の環化付加反応によるアズレノ[2,1-b]チオフェン誘導体の合成とそれらの構造、光学及び分光学的性質2019

    • Author(s)
      三浦孝太、庄子卓、太田哲、関口龍太
    • Organizer
      第50回中部化学関係学協会支部連合秋季大会
    • Related Report
      2019 Research-status Report
  • [Presentation] 非対称な1,6'-ビアズレンおよび1,6':3,6''-テルアズレン誘導体の合成研究2019

    • Author(s)
      飯田七海、庄子卓、太田哲、関口龍太
    • Organizer
      第50回中部化学関係学協会支部連合秋季大会
    • Related Report
      2019 Research-status Report
  • [Presentation] アズレン置換Zincke塩を経由した新規Donor-Acceptor型ポリメチン類の合成と反応性2019

    • Author(s)
      庄子卓、飯田七海、太田哲、関口龍太
    • Organizer
      第50回中部化学関係学協会支部連合秋季大会
    • Related Report
      2019 Research-status Report
  • [Presentation] アズレノピリミドンおよびピリミジン類の合成研究2019

    • Author(s)
      有賀雪乃、庄子卓、太田哲、関口龍太
    • Organizer
      第50回中部化学関係学協会支部連合秋季大会
    • Related Report
      2019 Research-status Report
  • [Presentation] ベンゾアズレン類の合成と光学特性2019

    • Author(s)
      山崎あかり、庄子卓、太田哲、関口龍太
    • Organizer
      第50回中部化学関係学協会支部連合秋季大会
    • Related Report
      2019 Research-status Report
  • [Presentation] 新規アズレノピロール誘導体の合成とその性質2019

    • Author(s)
      石野さくら、太田哲、庄子卓、関口龍太
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Research-status Report
  • [Presentation] アズレニルアルキンと硫黄との環化付加反応によるアズレノチオフェン類の合成とその反応性2018

    • Author(s)
      三浦孝太, 庄子卓, 太田哲, 関口龍太
    • Organizer
      第49回中部化学関係学協会支部連合秋季大会
    • Related Report
      2018 Research-status Report
  • [Presentation] 2-アミノフラン類とマレイミドとのDiels-Alder反応によるアズレン置換フタルイミド類の合成研究2018

    • Author(s)
      飯田七海, 庄子卓, 太田哲, 関口龍太
    • Organizer
      第49回中部化学関係学協会支部連合秋季大会
    • Related Report
      2018 Research-status Report
  • [Presentation] 2H-cyclohepta[b]-furan-2-oneとシリルエノールエーテルとの[8 + 2]環化付加反応による2-アリールアズレン類の合成研究2018

    • Author(s)
      杉山周平, 小林善明, 庄子卓, 太田晢, 関口龍太
    • Organizer
      第49回中部化学関係学協会支部連合秋季大会
    • Related Report
      2018 Research-status Report
  • [Presentation] アズレン置換プロパルギルアミン類とテトラシアノエチレンとの反応性2018

    • Author(s)
      高垣勝, 庄子卓, 太田哲, 関口龍太
    • Organizer
      第49回中部化学関係学協会支部連合秋季大会
    • Related Report
      2018 Research-status Report
  • [Presentation] Synthesis of Azulene-substituted Benzofurans and Isocoumarins by Intramolecular Cyclization of Azulenylalkynes2018

    • Author(s)
      Taku Shoji, Miwa Tanaka, Akira Ohta, Ryuta Sekiguchi, Shunji Ito, Tetsuo Okujima
    • Organizer
      平成30年度化学系学協会東北大会
    • Related Report
      2018 Research-status Report
  • [Presentation] Synthesis of 2-Amino-1-Cyanoazulenes by Reaction of 2H-Cyclohepta[b]furan-2-ones with Malononitrile2018

    • Author(s)
      Taku Shoji, Akira Ohta, Ryuta Sekiguchi, Shunji Ito, Tetsuo Okujima
    • Organizer
      平成30年度化学系学協会東北大会
    • Related Report
      2018 Research-status Report
  • [Presentation] Synthesis of 2-Formylazulenes and Conversion to 2-Ethynylazulenes2018

    • Author(s)
      Taku Shoji、Takanori Araki, Takanori Araki, Nanami Iida, Ryuta Sekiguchi, Shunji Ito, Tetsuo Okujima
    • Organizer
      平成30年度化学系学協会東北大会
    • Related Report
      2018 Research-status Report
  • [Presentation] アリールエチニルアズレン類と硫黄との環化反応による新規アズレノチオフェン誘導体の合成研究2018

    • Author(s)
      三浦孝太、庄子卓、太田哲、関口龍太
    • Organizer
      第29回基礎有機化学討論会
    • Related Report
      2018 Research-status Report
  • [Presentation] 2-メチル-1-アズレニルテトラシアノブタジエンおよびジシアノキノジメタン類の合成と性質2018

    • Author(s)
      庄子卓、丸山晃史、荒木貴訓、太田哲、関口龍太、伊東俊司、奥島鉄雄
    • Organizer
      第29回基礎有機化学討論会
    • Related Report
      2018 Research-status Report
  • [Presentation] Synthesis of azulene-substituted 6-aminopentaflvenes from 2-aminofurans2017

    • Author(s)
      Taku Shoji, Daichi Nagai, Akira Ohta, Ryuta Sekiguchi, Shunji Ito, Tetsuo Okujima
    • Organizer
      平成29年度化学系学協会東北大会
    • Related Report
      2017 Research-status Report
  • [Presentation] Synthesis of amino and azuazulenes by SNAr reaction of haloazulenes2017

    • Author(s)
      Taku Shoji, Shuhei Sugiyama, Akira Ohta, Ryuta Sekiguchi, Shunji Ito, Tetsuo Okujima, Masafumi Yasunami
    • Organizer
      平成29年度化学系学協会東北大会
    • Related Report
      2017 Research-status Report
  • [Presentation] アズレンを基盤とした共役π電子系化合物の合成2017

    • Author(s)
      庄子 卓
    • Organizer
      有機合成化学協会東海支部・若手研究者のためのセミナー
    • Related Report
      2017 Research-status Report
    • Invited
  • [Book] Advances in Heterocyclic Chemistry: The preparation and properties of heteroarylazulenes and hetero-fused azulenes2018

    • Author(s)
      Taku Shoji,* and Shunji Ito*
    • Publisher
      Elsevier
    • Related Report
      2018 Research-status Report
  • [Remarks] 信州大学理学部化学コース有機化学分野 庄子研究室

    • URL

      https://shinshuscienceorgc.wixsite.com/organicchemistrylab1

    • Related Report
      2021 Annual Research Report
  • [Remarks] publons

    • URL

      https://publons.com/researcher/1690334/taku-shoji/

    • Related Report
      2021 Annual Research Report
  • [Remarks] ORCiD

    • URL

      https://orcid.org/0000-0001-8176-2389

    • Related Report
      2021 Annual Research Report 2020 Research-status Report 2019 Research-status Report 2018 Research-status Report
  • [Remarks] researchmap

    • URL

      https://researchmap.jp/shoji-azulene

    • Related Report
      2021 Annual Research Report 2020 Research-status Report 2019 Research-status Report 2018 Research-status Report 2017 Research-status Report
  • [Remarks] 学術情報オンラインシステムSOAR

    • URL

      http://soar-rd.shinshu-u.ac.jp/profile/ja.gmShOakh.html

    • Related Report
      2020 Research-status Report 2019 Research-status Report
  • [Remarks] Publons

    • URL

      https://publons.com/researcher/1690334/taku-shoji/

    • Related Report
      2020 Research-status Report 2019 Research-status Report 2018 Research-status Report
  • [Remarks] 信州大学学術情報オンラインシステムSOAR

    • URL

      http://soar-rd.shinshu-u.ac.jp/profile/ja.gmShOakh.html

    • Related Report
      2018 Research-status Report 2017 Research-status Report
  • [Remarks] 信州大学理学部化学コース 有機化学第一研究室 (庄子研究室)

    • URL

      https://shinshuscienceorgc.wixsite.com/organicchemistrylab1

    • Related Report
      2018 Research-status Report
  • [Remarks] RESEARCHER ID

    • URL

      http://www..com/rid/J-5166-2013

    • Related Report
      2017 Research-status Report

URL: 

Published: 2017-04-28   Modified: 2023-01-30  

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