| Budget Amount *help |
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2019: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2018: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2017: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
|
|---|
| Outline of Final Research Achievements |
Metal complexes containing hydride units play a key role in a range of chemical processes such as energy conversion and hydrogen storage applications. However, there have been critical issues including safety and environmental load because hydride sources such as H2 gas are used for the synthesis of conventional hydride complexes. In this study, novel strategies were established for selective synthesis of ruthenium complexes containing three types of metal- and/or organic-hydride units in the absence of H2 gas. Furthermore, it was confirmed that the organic-hydride was more excellent than the corresponding metal-hydride when hydrogen donating abilities to some substrates were examined using three kinds of the prepared hydride complexes.
|
