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Development of new emissive species containing d10 metal in the excited states

Research Project

Project/Area Number 17K05816
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Inorganic chemistry
Research InstitutionSeikei University

Principal Investigator

Tsubomura Taro  成蹊大学, 理工学部, 教授 (70188621)

Co-Investigator(Kenkyū-buntansha) 西川 道弘  成蹊大学, 理工学部, 助教 (60711885)
Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2019: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2018: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2017: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Keywords金属錯体 / 発光 / 銅錯体 / パラジウム錯体 / リン光 / 発光材料 / 銀錯体
Outline of Final Research Achievements

In this study, novel luminescent metal complexes with various d10 electron configurations were synthesized. Many types of monovalent copper complexes have been studied; they include stable three-coordinated copper complexes bearing a bulky ligand, some copper complexes having an extended π-conjugated system which should capture the long-wavelength light. We have also succeeded in synthesizing many novel luminescent complexes such as copper complex containing chalcogenide elements, i.e. oxygen, sulfur and selenium as donor atoms to the metal, and a series of copper complexes containing carbene ligand.
In addition to the copper complexes, a series of zero-valent palladium complexes has been successfully prepared. Emissive palladium complexes are extremely rare, but it has been found that our complexes emit light of various colors.
Furthermore, we were able to clarify the luminescence mechanism of these complexes by quantum chemical calculations.

Academic Significance and Societal Importance of the Research Achievements

薄型ディスプレイ用の材料として、また各種センサや光触媒・光アップコンバージョンの材料として、発光性の金属化合物が求められており、多数の金属錯体が研究されてきた。その中にあって私は最も早い時期から銅錯体の発光に注目してきた一人として、これまでさまざまなタイプの錯体を提案することを本研究の目的とし、それを達成することができたと考えている。銅のみならず、パラジウム化合物を含めて、今後の発光材料になり得る化合物を多数提供でき、量子化学計算の結果もあわせて発光性錯体のデザイン上の指針を得ることができたと考えている。さらに、円偏光発光や光触媒の増感剤など当初予定していなかった応用面も見いだすことができた。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Research-status Report
  • 2017 Research-status Report
  • Research Products

    (13 results)

All 2019 2018 2017

All Journal Article (4 results) (of which Peer Reviewed: 4 results,  Open Access: 1 results) Presentation (9 results) (of which Int'l Joint Research: 6 results,  Invited: 1 results)

  • [Journal Article] Photocatalytic CO2 Reduction Using Various Heteroleptic Diimine-Diphosphine Cu(I) Complexes as Photosensitizers2019

    • Author(s)
      Yamazaki Yasuomi、Onoda Takayuki、Ishikawa Jun、Furukawa Shota、Tanaka Chinatsu、Utsugi Tomoya、Tsubomura Taro
    • Journal Title

      Frontiers in Chemistry

      Volume: 7 Pages: 288-288

    • DOI

      10.3389/fchem.2019.00288

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Water-soluble copper(i) complexes bearing 2,2′-bicinchoninic acid dipotassium salt with red-light absorption and repeatable colour change upon freezing operation2019

    • Author(s)
      Saito Yuma、Nishikawa Michihiro、Tsubomura Taro
    • Journal Title

      New Journal of Chemistry

      Volume: 43 Issue: 1 Pages: 277-283

    • DOI

      10.1039/c8nj05147j

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] A Blue Luminescent Dinuclear Copper(I) Complex Bearing a Diphosphine Dioxide Ligand2018

    • Author(s)
      Tatsuya Nishi and Taro Tsubomura
    • Journal Title

      Chemistry Letters

      Volume: 47 Issue: 3 Pages: 269-271

    • DOI

      10.1246/cl.171062

    • NAID

      130006434024

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Photophysical properties of three coordinated copper(i) complexes bearing 1,10-phenanthroline and a monodentate phosphine ligand2017

    • Author(s)
      Kakizoe Daichi、Nishikawa Michihiro、Fujii Yasuo、Tsubomura Taro
    • Journal Title

      Dalton Transactions

      Volume: 46 Issue: 43 Pages: 14804-14811

    • DOI

      10.1039/c7dt02938a

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Presentation] CPL spectra of copper complexes and related issues for the measurements2019

    • Author(s)
      T. Tsubomura
    • Organizer
      International Symposium on Circularly Polarized Luminescence and the Related Phenomena
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Spin-polarization in the charge transfer excited state of Copper (i) complexes2019

    • Author(s)
      M. Asano, Y. Yasuda, S. Hashimoto, M. Nishikawa, T. Tsubomura, T. Kodama, H. Takeda, and O. Ishitani
    • Organizer
      Spin Chemistry Meeting
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Photophysics of palladium(0) phosphine complexes2018

    • Author(s)
      Taro Tsubomura
    • Organizer
      International Conference on Coordination Chemistry 2018
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Synthesis of emissive heteroleptic copper(I) complexes with extended piconjugate diimine ligands2018

    • Author(s)
      N. Kotake, T. Tsubomura
    • Organizer
      International Conference on Coordination Chemistry 2018
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Synthesis, luminescence and structure of copper(I) complexes bearing bis(N-heterocyclic)carbene2018

    • Author(s)
      J. Watanabe, S. Yabuhara, T. Tsubomura
    • Organizer
      International Conference on Coordination Chemistry 2018
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Synthesis and photophysical properties of water-stable copper(I) complexes2018

    • Author(s)
      Y. Yasue, M. Nishikawa, T. Tsubomura
    • Organizer
      International Conference on Coordination Chemistry 2018
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] 水溶性ジイミン銅(I)錯体の合成と凍結による色変化2018

    • Author(s)
      西川道弘・齋藤悠馬・坪村太郎
    • Organizer
      第30回配位化合物の光化学討論会
    • Related Report
      2018 Research-status Report
  • [Presentation] N-複素環カルベン配位子を用いた発光性銅(I)二核錯体の合成2017

    • Author(s)
      渡辺純一、薮原修平、西川道広、坪村太郎
    • Organizer
      第29回配位化合物の光化学討論会
    • Related Report
      2017 Research-status Report
  • [Presentation] キレートホスフィン配位子を用いたPd(0)錯体のフォトルミネッセンス2017

    • Author(s)
      垣添大地、西川道広、坪村太郎
    • Organizer
      錯体化学会第67回討論会
    • Related Report
      2017 Research-status Report

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Published: 2017-04-28   Modified: 2021-02-19  

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