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Development of functional nano thin film by hydrogen ion beam

Research Project

Project/Area Number 17K05832
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Functional solid state chemistry
Research InstitutionKyoto University

Principal Investigator

Maesato Mitsuhiko  京都大学, 理学研究科, 准教授 (60324604)

Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2019: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2018: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2017: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywords水素イオンビーム / 薄膜 / ドーピング / 電気抵抗 / 酸化物 / 同位体効果 / ペロブスカイト型酸化物 / パラジウム / 超伝導 / 水素 / ナノ材料 / 低温物性
Outline of Final Research Achievements

Hydrogen ion beam irradiation is a powerful method for introducing a large amount of hydrogen into materials. Since the desorption of hydrogen can be suppressed at low temperature, extremely large amount of hydrogen can be doped by low temperature hydrogen ion beam irradiation. Importantly, this method is applicable to any material of interest. In addition, we can investigate hydrogen-induced exotic physical properties simultaneously by in situ physical property measurements. In this study, we succeeded in changing the physical properties of various nano thin films by utilizing low temperature hydrogen ion beam irradiation with in situ physical property measurements.

Academic Significance and Societal Importance of the Research Achievements

本研究では、水素イオンビーム照射装置を用いて、ナノ薄膜の機能を創発する新しい基盤技術を確立した。固体中に水素を自在に導入できる水素イオンビームを用いると、例えば、身近なありふれた材料を有用な高機能物質に変換することが期待できる。実際に、電気を流さない酸化物の絶縁体に水素を注入することにより、金属へと変換できることを示した。また、金属に水素を注入することによって超伝導に変換できることも示した。水素はクリーンなエネルギー源としても重要な物質であり、水素を利用したマテリアルイノベーションは今後ますます重要になる。本研究はその基盤を構築する成果をあげた。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Research-status Report
  • 2017 Research-status Report
  • Research Products

    (47 results)

All 2020 2019 2018 2017

All Journal Article (14 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 14 results,  Open Access: 5 results) Presentation (33 results) (of which Int'l Joint Research: 11 results,  Invited: 5 results)

  • [Journal Article] Canting Antiferromagnetic Spin-Order (TN = 102 K) in a Monomer Mott Insulator (ET)Ag4(CN)5 with a Diamond Spin-Lattice2020

    • Author(s)
      A. Otsuka, Y. Shimizu, G. Saito, M. Maesato, A. Kiswandhi, T. Hiramatsu, Y. Yoshida, H. Yamochi, M. Tsuchiizu, Y. Nakamura, H. Kishida, and H. Ito
    • Journal Title

      Bull. Chem. Soc. Jpn.

      Volume: 93 Issue: 2 Pages: 260-272

    • DOI

      10.1246/bcsj.20190279

    • NAID

      130007798348

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Molecular diamond lattice antiferromagnet as a Dirac semimetal candidate2019

    • Author(s)
      Y. Shimizu, A. Otsuka, M. Maesato, M. Tsuchiizu, A. Nakao, H. Yamochi, T. Hiramatsu, Y. Yoshida, and G. Saito
    • Journal Title

      Phys. Rev. B

      Volume: 99 Issue: 17 Pages: 174417-174417

    • DOI

      10.1103/physrevb.99.174417

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] High-pressure Effect on a Proton-conducting Metal-Organic Framework, LaCr(C2O4)3・10H2O2019

    • Author(s)
      Yamamoto Takayuki、Asakawa Yuta、Maesato Mitsuhiko、Hirao Naohisa、Kawaguchi Saori I.、Ohishi Yasuo、Kitagawa Hiroshi
    • Journal Title

      Chemistry Letters

      Volume: 48 Issue: 7 Pages: 746-748

    • DOI

      10.1246/cl.190240

    • NAID

      130007675088

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Conducting Coronene Cation Radical Salt Containing Magnetic Metal Ions2019

    • Author(s)
      Yoshida Yukihiro、Maesato Mitsuhiko、Saito Gunzi、Kitagawa Hiroshi
    • Journal Title

      Inorganic Chemistry

      Volume: 58 Issue: 20 Pages: 14068-14074

    • DOI

      10.1021/acs.inorgchem.9b02080

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Partial Substitution of Ag(I) for Cu(I) in Quantum Spin Liquid κ-(ET)2Cu2(CN)3, Where ET Is Bis(ethylenedithio)tetrathiafulvalene2019

    • Author(s)
      Yoshida Yukihiro、Maesato Mitsuhiko、Tomeno Shinya、Kimura Yojiro、Saito Gunzi、Nakamura Yuto、Kishida Hideo、Kitagawa Hiroshi
    • Journal Title

      Inorganic Chemistry

      Volume: 58 Issue: 8 Pages: 4820-4827

    • DOI

      10.1021/acs.inorgchem.8b03251

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] A Novel Platinum(III)?Platinum(III) Neutral Dimer Complex, Pt2(cdtb)4I2 (cdtb: 4-Cyanodithiobenzoate)2019

    • Author(s)
      Moriyama Hayato、Otsubo Kazuya、Aoki Kentaro、Maesato Mitsuhiko、Sugimoto Kunihisa、Kitagawa Hiroshi
    • Journal Title

      Chemistry Letters

      Volume: 48 Issue: 9 Pages: 1035-1037

    • DOI

      10.1246/cl.190355

    • NAID

      130007703014

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Bis(ethylenedithio)tetrathiafulvalene Cation Radical Salts Composed of Nonuniform Silver(I) Complex Polyanions2019

    • Author(s)
      Yoshida Yukihiro、Maesato Mitsuhiko、Nakamura Yuto、Ishikawa Manabu、Yamochi Hideki、Saito Gunzi、Kishida Hideo、Kitagawa Hiroshi
    • Journal Title

      Inorganic Chemistry

      Volume: 58 Issue: 24 Pages: 16703-16711

    • DOI

      10.1021/acs.inorgchem.9b02814

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Heavy interstitial hydrogen doping into SrTiO32018

    • Author(s)
      R. Nakayama, M. Maesato, T. Yamamoto, H. Kageyama, T. Terashima, H. Kitagawa
    • Journal Title

      Chem. Comm.

      Volume: 54 Issue: 88 Pages: 12439-12442

    • DOI

      10.1039/c8cc07021k

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] The electronic state of hydrogen in α phase of the hydrogen-storage material PdH(D)x: Does a chemical bond between palladium and hydrogen exist?2018

    • Author(s)
      S. Dekura, H. Kobayashi, R. Ikeda, M. Maesato, H. Yoshino, M. Ohba, T. Ishimoto, S. Kawaguchi, Y. Kubota, S. Yoshioka, S. Matsumura, T. Sugiyama, H. Kitagawa
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 57 Issue: 31 Pages: 9823-9827

    • DOI

      10.1002/anie.201805753

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Design of Spin-Frustrated Monomer-Type C60?? Mott Insulator2018

    • Author(s)
      Otsuka Akihiro、Konarev Dmitri、Lyubovskaya Rimma、Khasanov Salavat、Maesato Mitsuhiko、Yoshida Yukihiro、Saito Gunzi
    • Journal Title

      Crystals

      Volume: 8 Issue: 3 Pages: 115-115

    • DOI

      10.3390/cryst8030115

    • NAID

      120006502652

    • Related Report
      2018 Research-status Report 2017 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Synthesis and Physical Properties of New Organic Conductor with Triangular Lattice2018

    • Author(s)
      E. Matsubara, H. Miyazono, S. Tomeno, Y. Kimura, M. Maesato
    • Journal Title

      ELCAS Journal

      Volume: 3 Pages: 13-15

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] A compact low-temperature hydrogen ion beam apparatus for in situ physical property measurements2017

    • Author(s)
      Nakayama R.、Suzuki N.、Maesato M.、Nagaoka T.、Arita M.、Kitagawa H.
    • Journal Title

      Review of Scientific Instruments

      Volume: 88 Issue: 12 Pages: 123904-123904

    • DOI

      10.1063/1.5004517

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Discovery of Hexagonal Structured Pd-B Nanocrystals2017

    • Author(s)
      Kobayashi Keigo、Kobayashi Hirokazu、Maesato Mitsuhiko、Hayashi Mikihiro、Yamamoto Tomokazu、Yoshioka Satoru、Matsumura Syo、Sugiyama Takeharu、Kawaguchi Shogo、Kubota Yoshiki、Nakanishi Hiroshi、Kitagawa Hiroshi
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 56 Issue: 23 Pages: 6578-6582

    • DOI

      10.1002/anie.201703209

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Design and Preparation of a Quantum Spin Liquid Candidate κ-(ET)2Ag2(CN)3 having a nearby Superconductivity2017

    • Author(s)
      T. Hiramatsu, Y. Yoshida, G. Saito, A. Otsuka, H. Yamochi, M . Maesato, Y. Shimizu, H. Ito, Y. Nakamura, H. Kishida, M. Watanabe, R. Kumai
    • Journal Title

      Bull. Chem. Soc. Jpn.

      Volume: 90 Issue: 9 Pages: 1073-1082

    • DOI

      10.1246/bcsj.20170167

    • NAID

      130006077917

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Open Access
  • [Presentation] Low Temperature Hydrogen Ion Beam Irradiation for Exploring Exotic Physical Properties2020

    • Author(s)
      Mitsuhiko Maesato, Ryo Nakayama, GyeongCheol Lim, Takahito Terashima, Hiroshi Kitagawa
    • Organizer
      1st International Symposium “Hydrogenomics” combined with 14th International Symposium Hydrogen & Energy
    • Related Report
      2019 Annual Research Report
  • [Presentation] Artificial Control of Materials Properties2019

    • Author(s)
      Mitsuhiko Maesato
    • Organizer
      Zhou Huijiu Forum
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Artificial Control of Materials Properties2019

    • Author(s)
      Mitsuhiko Maesato
    • Organizer
      Nanjing University - Kyoto University Bilateral Workshop: Functional Molecular Materials
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] New Spin Liquid Candidates Based on BEDT-TTF2019

    • Author(s)
      M. Maesato, Y. Yoshida, S. Tomeno, Y. Kimura, A. Kiswandhi, Y. Nakamura, H. Kishida, Y. Shimizu, G. Saito, H. Kitagawa
    • Organizer
      13th International Symposium on Crystalline Organic Metals, Superconductors and Magnets (ISCOM)
    • Related Report
      2019 Annual Research Report
  • [Presentation] 低温水素イオンビーム照射による高濃度水素ドープとin situ物性測定2019

    • Author(s)
      前里 光彦, 中山 亮, GyeongCheol Lim, 寺嶋 孝仁, 北川 宏
    • Organizer
      第13回物性科学領域横断研究会 (領域合同研究会)
    • Related Report
      2019 Annual Research Report
  • [Presentation] High pressure infrared study of a monomer Mott insulator (ET)Ag4(CN)52019

    • Author(s)
      Andhika Kiswandhi, Mitsuhiko Maesato, Shinya Tomeno, Yukihiro Yoshida, Hidekazu Okamura, Yuka Ikemoto, Hideo Kishida, Gunzi Saito, Hiroshi Kitagawa
    • Organizer
      日本物理学会 第74回年次大会(2019年)
    • Related Report
      2018 Research-status Report
  • [Presentation] Quantum spin liquid in an organic triangular-lattice with disorder free anion2019

    • Author(s)
      Shinya Tomeno, Yukihiro Yoshida, Andhika Kiswandhi, Mitsuhiko Maesato, Shimizu Yasuhiro, Hiroshi Kitagawa
    • Organizer
      日本化学会 第99春季年会 (2019)
    • Related Report
      2018 Research-status Report
  • [Presentation] Proton conductivity of confined ammonia in metal-organic frameworks2019

    • Author(s)
      D.-W. Lim, A. Shigematsu, T. Yamada, K. Otsubo, A. E. Khudozhitkov, A. G. Stepanov, D. I. Kolokolov, M. Maesato and H. Kitagawa
    • Organizer
      日本化学会 第99春季年会 (2019)
    • Related Report
      2018 Research-status Report
  • [Presentation] Artificial Control of Materials’ Properties2018

    • Author(s)
      Mitsuhiko Maesato
    • Organizer
      International Conference on Advancement in Science & Technology (ICAST) 2018
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Spin Liquids and Superconductivity based on BEDT-TTF2018

    • Author(s)
      M. Maesato, S. Tomeno, Y. Kimura, Y. Yoshida, G. Saito, H. Kitagawa
    • Organizer
      International Conference on Science and Technology of Synthetic Metals (ICSM) 2018
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] High pressure transport and Raman measurements of the 3D Dirac semimetal candidate ET-Ag4(CN)52018

    • Author(s)
      Andhika Kiswandhi, Mitsuhiko Maesato, Shinya Tomeno, Yukihiro Yoshida, Yasuhiro Shimizu, Gunzi Saito, Hiroshi Kitagawa
    • Organizer
      International Conference on Science and Technology of Synthetic Metals (ICSM) 2018
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] New Triangular Lattice BEDT-TTF Salt with Disorder-Free Anions2018

    • Author(s)
      S. Tomeno, Y. Yoshida, M. Maesato, H. Kitagawa
    • Organizer
      International Conference on Science and Technology of Synthetic Metals (ICSM) 2018
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Synthesis of A Degenerated Neutral Radical State based on Metal Dithiolene Complex2018

    • Author(s)
      Y. Kimura, M. Hayashi, M. Maesato, H. Kitagawa
    • Organizer
      International Conference on Science and Technology of Synthetic Metals (ICSM) 2018
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] κ-(ET)2Cu[Au(CN)2]Clの低温物性2018

    • Author(s)
      留野慎也, 吉田幸大, 前里光彦, 北川宏
    • Organizer
      日本物理学会 2018年秋季大会
    • Related Report
      2018 Research-status Report
  • [Presentation] High pressure investigation of Dirac semimetal candidate (ET)Ag4(CN)5 up to 14 GPa2018

    • Author(s)
      Andhika Kiswandhi, Mitsuhiko Maesato, Shinya Tomeno, Yukihiro Yoshida, Yasuhiro Shimizu, Prashant Shahi, Jun Gouchi, Yoshiya Uwatoko, Gunzi Saito, Hiroshi Kitagawa
    • Organizer
      日本物理学会 2018年秋季大会
    • Related Report
      2018 Research-status Report
  • [Presentation] Superconductivity in Pd Thin Film Irradiated with Hydrogen Ion Beam2018

    • Author(s)
      Naoya Suzuki, Ryo Nakayama, Mitsuhiko Maesato, Hiroshi Kitagawa
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Research-status Report
  • [Presentation] Observation of giant isotope effects induced by deuterium ion beam irradiation of zinc oxide2018

    • Author(s)
      Ryo Nakayama, Naoya Suzuki, Mitsuhiko Maesato, Makoto Arita, Hiroshi Nakanishi, Hiroshi Kiragawa
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Research-status Report
  • [Presentation] Pd-H Chemical Bond in α-phase PdHx2018

    • Author(s)
      Shun Dekura, Hirokazu Kobayashi, Ryuichi Ikeda, Mitsuhiko Maesato, Haruka Yoshino, Masaaki Ohba, Takayoshi Ishimoto, Shogo Kawaguchi, Yoshiki Kubota, Satoru Yoshioka, Syo Matsumura, Takeharu Sugiyama, Hiroshi Kitagawa
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Research-status Report
  • [Presentation] Pd薄膜における水素誘起超伝導 II2018

    • Author(s)
      鈴木直也、中山亮、前里光彦、北川宏
    • Organizer
      日本物理学会第73回年次大会
    • Related Report
      2017 Research-status Report
  • [Presentation] 水素イオンビーム照射された酸化亜鉛薄膜における巨大同位体効果2018

    • Author(s)
      中山 亮、鈴木 直也、前里 光彦、有田 誠、中西 寛、北川 宏
    • Organizer
      日本物理学会第73回年次大会
    • Related Report
      2017 Research-status Report
  • [Presentation] 陰イオン層にディスオーダーを含まない新規三角格子ET塩2018

    • Author(s)
      留野慎也、前里光彦、吉田幸大、北川宏
    • Organizer
      日本物理学会第73回年次大会
    • Related Report
      2017 Research-status Report
  • [Presentation] κ-(ET)2Ag2xCu2(1-x)(CN)3の合成と電子物性2018

    • Author(s)
      吉田幸大、留野慎也、木村要二郎、前里光彦、齋藤軍治、北川宏
    • Organizer
      日本物理学会第73回年次大会
    • Related Report
      2017 Research-status Report
  • [Presentation] α相PdHxにおける特異な水素吸蔵状態2018

    • Author(s)
      出倉駿、小林浩和、前里光彦、秋葉宙、山室修、李相賢、萩原雅人、鳥居周輝、神山崇、北川宏
    • Organizer
      日本物理学会第73回年次大会
    • Related Report
      2017 Research-status Report
  • [Presentation] 分子性導体における磁性と伝導性の制御2017

    • Author(s)
      前里光彦
    • Organizer
      第2回固体化学フォーラム研究会
    • Related Report
      2017 Research-status Report
    • Invited
  • [Presentation] 低温下水素イオンビーム照射を用いた酸化亜鉛薄膜の物性制御2017

    • Author(s)
      中山 亮、前里 光彦、長岡 孝、有田 誠、Zhu Wenliang、Pezzotti Giuseppe、北川 宏
    • Organizer
      第2回固体化学フォーラム研究会
    • Related Report
      2017 Research-status Report
  • [Presentation] Iodine-based Functional Materials2017

    • Author(s)
      Mitsuhiko Maesato
    • Organizer
      One Day Symposium of Research Center for Structural Thermodynamics (RCST)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Commonalities and Differences in Spin Liquids Based on BEDT-TTF2017

    • Author(s)
      Mitsuhiko Maesato
    • Organizer
      12th International Symposium on Crystalline Organic Metals, Superconductors and Magnets (ISCOM2017)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Uniaxial Straij induced Superconductivity in Quantum Spin Liquid κ-(ET)2Ag2(CN)32017

    • Author(s)
      Shinya Tomeno, Mitsuhiko Maesato, Yukihiro Yoshida, Takaaki Hiramatsu, Gunzi Saito, Hiroshi, Kitagawa
    • Organizer
      12th International Symposium on Crystalline Organic Metals, Superconductors and Magnets (ISCOM2017)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] 水素イオンビーム照射による物質・物性変換2017

    • Author(s)
      中山 亮、 鈴木 直也、前里 光彦、有田 誠、北川 宏
    • Organizer
      先端ナノデバイス・材料テクノロジー第151委員会 平成29年度 第4回研究会
    • Related Report
      2017 Research-status Report
    • Invited
  • [Presentation] 酸化亜鉛に対する低温での重水素分子イオン照射による同位体効果の観測2017

    • Author(s)
      中山 亮、鈴木 直也、前里 光彦、有田 誠、北川 宏
    • Organizer
      第11回分子科学討論会
    • Related Report
      2017 Research-status Report
  • [Presentation] Pd薄膜における水素誘起超伝導2017

    • Author(s)
      鈴木直也、中山亮、前里光彦、北川宏
    • Organizer
      日本物理学会2017年秋季大会
    • Related Report
      2017 Research-status Report
  • [Presentation] 一軸歪下での量子スピン液体κ-(ET)2Ag2(CN)3の超伝導2017

    • Author(s)
      留野慎也、前里光彦、吉田幸大、平松孝章、斎藤軍治、北川宏
    • Organizer
      日本物理学会2017年秋季大会
    • Related Report
      2017 Research-status Report
  • [Presentation] Isotope Effects in ZnO Induced by Deuterium Ion Beam Irradiation at Low temperature2017

    • Author(s)
      Ryo Nakayama, Mitsuhiko Maesato, Hiroshi Kitagawa
    • Organizer
      3rd Japan-Korea Joint Symposium on Protonics and Related Materials
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research

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Published: 2017-04-28   Modified: 2021-02-19  

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