Development of functional nano thin film by hydrogen ion beam
Project/Area Number |
17K05832
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Research Category |
Grant-in-Aid for Scientific Research (C)
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Allocation Type | Multi-year Fund |
Section | 一般 |
Research Field |
Functional solid state chemistry
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Research Institution | Kyoto University |
Principal Investigator |
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Project Period (FY) |
2017-04-01 – 2020-03-31
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Project Status |
Completed (Fiscal Year 2019)
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Budget Amount *help |
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2019: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2018: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2017: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
|
Keywords | 水素イオンビーム / 薄膜 / ドーピング / 電気抵抗 / 酸化物 / 同位体効果 / ペロブスカイト型酸化物 / パラジウム / 超伝導 / 水素 / ナノ材料 / 低温物性 |
Outline of Final Research Achievements |
Hydrogen ion beam irradiation is a powerful method for introducing a large amount of hydrogen into materials. Since the desorption of hydrogen can be suppressed at low temperature, extremely large amount of hydrogen can be doped by low temperature hydrogen ion beam irradiation. Importantly, this method is applicable to any material of interest. In addition, we can investigate hydrogen-induced exotic physical properties simultaneously by in situ physical property measurements. In this study, we succeeded in changing the physical properties of various nano thin films by utilizing low temperature hydrogen ion beam irradiation with in situ physical property measurements.
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Academic Significance and Societal Importance of the Research Achievements |
本研究では、水素イオンビーム照射装置を用いて、ナノ薄膜の機能を創発する新しい基盤技術を確立した。固体中に水素を自在に導入できる水素イオンビームを用いると、例えば、身近なありふれた材料を有用な高機能物質に変換することが期待できる。実際に、電気を流さない酸化物の絶縁体に水素を注入することにより、金属へと変換できることを示した。また、金属に水素を注入することによって超伝導に変換できることも示した。水素はクリーンなエネルギー源としても重要な物質であり、水素を利用したマテリアルイノベーションは今後ますます重要になる。本研究はその基盤を構築する成果をあげた。
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Report
(4 results)
Research Products
(47 results)
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[Journal Article] Canting Antiferromagnetic Spin-Order (TN = 102 K) in a Monomer Mott Insulator (ET)Ag4(CN)5 with a Diamond Spin-Lattice2020
Author(s)
A. Otsuka, Y. Shimizu, G. Saito, M. Maesato, A. Kiswandhi, T. Hiramatsu, Y. Yoshida, H. Yamochi, M. Tsuchiizu, Y. Nakamura, H. Kishida, and H. Ito
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Journal Title
Bull. Chem. Soc. Jpn.
Volume: 93
Issue: 2
Pages: 260-272
DOI
NAID
Related Report
Peer Reviewed
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[Journal Article] The electronic state of hydrogen in α phase of the hydrogen-storage material PdH(D)x: Does a chemical bond between palladium and hydrogen exist?2018
Author(s)
S. Dekura, H. Kobayashi, R. Ikeda, M. Maesato, H. Yoshino, M. Ohba, T. Ishimoto, S. Kawaguchi, Y. Kubota, S. Yoshioka, S. Matsumura, T. Sugiyama, H. Kitagawa
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Journal Title
Angew. Chem. Int. Ed.
Volume: 57
Issue: 31
Pages: 9823-9827
DOI
Related Report
Peer Reviewed
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[Journal Article] Design and Preparation of a Quantum Spin Liquid Candidate κ-(ET)2Ag2(CN)3 having a nearby Superconductivity2017
Author(s)
T. Hiramatsu, Y. Yoshida, G. Saito, A. Otsuka, H. Yamochi, M . Maesato, Y. Shimizu, H. Ito, Y. Nakamura, H. Kishida, M. Watanabe, R. Kumai
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Journal Title
Bull. Chem. Soc. Jpn.
Volume: 90
Issue: 9
Pages: 1073-1082
DOI
NAID
Related Report
Peer Reviewed / Open Access
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[Presentation] New Spin Liquid Candidates Based on BEDT-TTF2019
Author(s)
M. Maesato, Y. Yoshida, S. Tomeno, Y. Kimura, A. Kiswandhi, Y. Nakamura, H. Kishida, Y. Shimizu, G. Saito, H. Kitagawa
Organizer
13th International Symposium on Crystalline Organic Metals, Superconductors and Magnets (ISCOM)
Related Report
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[Presentation] Pd-H Chemical Bond in α-phase PdHx2018
Author(s)
Shun Dekura, Hirokazu Kobayashi, Ryuichi Ikeda, Mitsuhiko Maesato, Haruka Yoshino, Masaaki Ohba, Takayoshi Ishimoto, Shogo Kawaguchi, Yoshiki Kubota, Satoru Yoshioka, Syo Matsumura, Takeharu Sugiyama, Hiroshi Kitagawa
Organizer
日本化学会第98春季年会
Related Report
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