Development of Novel Electron-Transfer Reactions via Organonitrogen Active Species
| Project/Area Number |
17K05861
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Synthetic chemistry
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| Research Institution | Kyoto University |
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Principal Investigator |
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| Project Period (FY) |
2017-04-01 – 2020-03-31
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| Project Status |
Completed (Fiscal Year 2019)
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| Budget Amount *help |
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2019: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2018: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2017: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
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| Keywords | 有機活性種 / 遷移金属触媒 / 電子移動 / コバルト触媒 / 含窒素複素環 / 不斉合成 / 触媒的不斉合成 / 一電子移動 / 鉄触媒 / オキシムエステル / ラジカル / 含窒素化合物 / 均一系触媒 / 酸化還元 |
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| Outline of Final Research Achievements |
We have developed transition metal-catalyzed transformation of cyclic O-acyloximes as an novel type of precursors for organonitrogen active species. In this study, we have utilized 3d transition metal catalysts such as iron and cobalt for such transformations. As a result, we have developed cobalt- and iron-catalyzed several types of transformation reactions of O-acyloximes into various nitrogen-containing heterocyclic molecules.
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| Academic Significance and Societal Importance of the Research Achievements |
本研究成果は電子移動型反応による有機窒素活性種の新規発生法開発という当初目的を十分に達成したと言える．電子移動型反応は効率に優れた反応であるため，様々な触媒反応の効率化に果たす役割は大きく，この成果が有機合成化学の発展を含む分子科学への貢献を将来的に果たすことが予想され，ひいては本邦の社会経済に対する将来的な貢献も期待される．
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Report
(4 results)
Research Products
(21 results)
