• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Analysis of mass transfer in the microparticle/solution system controlled in the micrometer-sized space

Research Project

Project/Area Number 17K05894
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Analytical chemistry
Research InstitutionUniversity of Tsukuba

Principal Investigator

NAKATANI Kiyoharu  筑波大学, 数理物質系, 教授 (00250415)

Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2019: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2018: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2017: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywords細孔内拡散 / 物質移動 / シリカゲル / 顕微分析 / 多孔性粒子 / 表面・界面物性 / 反応・分離工学 / 共焦点顕微鏡
Outline of Final Research Achievements

Mass transfer of a dye in the porous microparticle/solution system has been analyzed using microspectroscopic and microelectrochemical methods controlled in the micrometer-sized space. A single microparticle such as ODS silica gel was trapped by laser manipulation technique. The distribution rate of a dye from a solution into the single laser-trapped microparticle was measured by fluorescence recovery after quick photobleaching. Release of a dye from the laser-trapped microparticle into the solution was measured by fluorescence microspectroscopy after quick bulk electrolysis of the dye. The intraparticle diffusion was controlled by surface diffusion, not pore diffusion. Furthermore, the mass transfer was significantly influenced by desorption of the dye on the pore walls of the microparticle.

Academic Significance and Societal Importance of the Research Achievements

クロマトグラフィーや触媒の分離機構,物質移動機構に直接関連するとともに,新規分析手法として高分子/溶液界面,液/液界面や電極/溶液界面等,界面が関わる基礎プロセスの解明に関連し,分析化学,界面・コロイド科学,生化学,環境科学などの分野の極めて重要な知見になったものと考えられる。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Research-status Report
  • 2017 Research-status Report
  • Research Products

    (7 results)

All 2020 2019 2018 2017 Other

All Presentation (5 results) (of which Invited: 1 results) Remarks (2 results)

  • [Presentation] レーザー捕捉・顕微分光・電気化学法による多孔質微粒子/溶液系物質移動過程の解析2020

    • Author(s)
      中谷清治
    • Organizer
      日本分析化学会第80回分析化学討論会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] 単一多孔質微粒子/溶液系の物質移動過程における分配比と吸脱着速度の影響2019

    • Author(s)
      本間廉,長友重紀,中谷清治
    • Organizer
      日本分析化学会第68年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 単一ODSシリカゲル微粒子/溶液系におけるクマリン系色素の移動機構の解析2018

    • Author(s)
      秦克弥,中谷清治
    • Organizer
      日本分析化学会第67年会
    • Related Report
      2018 Research-status Report
  • [Presentation] レーザー捕捉・光退色後蛍光回復法による単一多孔質微粒子/溶液系における物質移動過程の検討2018

    • Author(s)
      本間廉,秦克弥,中谷清治
    • Organizer
      日本分析化学会第67年会
    • Related Report
      2018 Research-status Report
  • [Presentation] 共焦点顕微蛍光法による表面修飾シリカゲル/溶液系におけるポア・表面拡散過程の解析2017

    • Author(s)
      秦克弥,佐藤辰巳,中谷清治
    • Organizer
      日本分析化学会第77回分析化学討論会
    • Related Report
      2017 Research-status Report
  • [Remarks] 筑波大学数理物質系化学域中谷研究室

    • URL

      http://www.chem.tsukuba.ac.jp/nakatani/

    • Related Report
      2019 Annual Research Report
  • [Remarks] 筑波大学化学域中谷研究室

    • URL

      http://www.chem.tsukuba.ac.jp/nakatani/

    • Related Report
      2018 Research-status Report 2017 Research-status Report

URL: 

Published: 2017-04-28   Modified: 2021-02-19  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi