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Construction of sophisticated phase interface using nanofiber framework to bring innovation to the battery cell architecture

Research Project

Project/Area Number 17K06002
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Polymer/Textile materials
Research InstitutionTokyo Metropolitan University

Principal Investigator

Tanaka Manabu  首都大学東京, 都市環境科学研究科, 准教授 (00531831)

Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2019: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2018: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2017: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Keywordsナノファイバー / エレクトロスピニング / 高分子電解質 / イオン伝導 / リチウムイオン / 電池 / 相界面 / 電極
Outline of Final Research Achievements

A series of polymer electrolytes were synthesized. The lithium ion conductive nanofiber framework (NfF) and their composite membranes were fabricated. The NfF prevented crystallization of matrix electrolytes and showed good ion conductivity and high lithium ion transference numbers. The positive effect of NfF on the ion conductive characteristics were analyzed by FT-IT, Raman spectroscopy, and solid-state NMR measurements. The all-solid-state battery using the NfF composite membranes showed stable charge-discharge cycles and long-term cycle stability, indicating the effectiveness of the NfFs and importance of the control of phase interface .

Academic Significance and Societal Importance of the Research Achievements

本研究では、高分子ナノファイバーに着目し相界面を制御することで二次電池特性の向上を達成している。本研究成果は二次電池の高性能化、小型・軽量化、コストダウンに繋がり、社会的な意義は大きい。さらに、各種高分子電解質を新たに合成して高分子構造と電解質特性の相関を明らかにするとともに、ラマン分光や固体NMR測定などを用いてイオン伝導メカニズムを検証するなど、学術的にも多数の新しい知見が得られ、当該分野の発展に貢献している。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Research-status Report
  • 2017 Research-status Report
  • Research Products

    (23 results)

All 2020 2019 2018 2017 Other

All Journal Article (6 results) (of which Peer Reviewed: 6 results) Presentation (12 results) (of which Int'l Joint Research: 5 results,  Invited: 5 results) Book (2 results) Remarks (2 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Fabrication and characterizations of soft and flexible Poly(dimethylsiloxane)-incorporated network polymer electrolyte membranes2020

    • Author(s)
      Grewal Manjit Singh、Tanaka Manabu、Kawakami Hiroyoshi
    • Journal Title

      Polymer

      Volume: 186 Pages: 122045-122045

    • DOI

      10.1016/j.polymer.2019.122045

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Secondary Battery Performance of Solid Polymer Electrolyte Membranes Based on Lithium Ion Conductive Polyimide Nanofibers2020

    • Author(s)
      Takushi Shimane, Tsukasa Watanabe, Nohara Yokota, Futoshi Matsumoto, Manabu Tanaka, Hiroyoshi Kawakami
    • Journal Title

      Journal of Photopolymer Science and Technology

      Volume: -

    • NAID

      130007867560

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Bifunctional poly(ethylene glycol) based crosslinked network polymers as electrolytes for all‐solid‐state lithium ion batteries2019

    • Author(s)
      Grewal Manjit Singh、Tanaka Manabu、Kawakami Hiroyoshi
    • Journal Title

      Polymer International

      Volume: 68 Issue: 4 Pages: 684-693

    • DOI

      10.1002/pi.5750

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Free-standing polydimethylsiloxane-based cross-linked network solid polymer electrolytes for future lithium ion battery applications2019

    • Author(s)
      Grewal Manjit Singh、Tanaka Manabu、Kawakami Hiroyoshi
    • Journal Title

      Electrochimica Acta

      Volume: 307 Pages: 148-156

    • DOI

      10.1016/j.electacta.2019.03.172

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Development of all-solid-state battery based on lithium ion conductivepolymer nanofiber framework2019

    • Author(s)
      Tsukasa Watanabe, Yuta Inafune, Manabu Tanaka, Yasumasa Mochizuki, Futoshi Matsumoto, Hiroyoshi Kawakami
    • Journal Title

      Journal of Power Sources

      Volume: 423 Pages: 255-262

    • DOI

      10.1016/j.jpowsour.2019.03.066

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Sulfonated polyimide nanofiber framework: Evaluation of intrinsic proton conductivity and application to composite membranes for fuel cells2018

    • Author(s)
      Ito Genki、Tanaka Manabu、Kawakami Hiroyoshi
    • Journal Title

      Solid State Ionics

      Volume: 317 Pages: 244-255

    • DOI

      10.1016/j.ssi.2018.01.029

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Presentation] 次世代燃料電池に向けた高分子ナノファイバー複合電解質膜の開発2020

    • Author(s)
      田中 学
    • Organizer
      水素エネルギー協会(HESS)第161回定例研究会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] 加湿作動を志向した表面修飾ナノファイバー複合電解質膜の開発2019

    • Author(s)
      田中 学
    • Organizer
      第26回燃料電池シンポジウム
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] リチウム塩添加ナノファイバー複合電解質膜の電池特性評価2019

    • Author(s)
      落合 美月, 中澤 駿, 田中 学,川上 浩良
    • Organizer
      第68回高分子学会年次大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 高分子ナノファイバーを複合化した電解質膜のリチウムイオン伝導性特性2019

    • Author(s)
      松田優, 田中学, 川上浩良
    • Organizer
      平成31年度繊維学会年次大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] リチウム塩添加PVDFナノファイバー複合高分子電解質膜からなる全固体型二次電池の作製と特性評価2019

    • Author(s)
      稲船 勇太, 落合 美月, 松田 優, 田中 学, 川上 浩良
    • Organizer
      第60回電池討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Ion Conductive Polymer Nanofibers: Fabrication, Characterization, and Application2019

    • Author(s)
      Manabu Tanaka, Hiroyoshi Kawakami
    • Organizer
      Asian International Symposium -Polymer-, The 99th CSJ Annual Meeting
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Proton Conductive Polymer Nanofiber Framework: Fabrication and Application to Polymer Electrolyte Fuel Cells2018

    • Author(s)
      Manabu Tanaka, Hiroyoshi Kawakami
    • Organizer
      The Fiber Society’s Spring 2018 Conference
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Ion Conductive Polymer Nanofiber Framework for All-Solid-State Lithium Ion Battery2017

    • Author(s)
      Manabu Tanaka, Tsukasa Watanabe, Hiroyoshi Kawakami
    • Organizer
      The 21st International Conference on Solid-State Ionics (SSI-21)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Polymer Composite Membranes based on Proton Conductive Nanofiber Framework for Fuel Cell Applications2017

    • Author(s)
      Manabu Tanaka, Hiroyoshi Kawakami
    • Organizer
      The 17th IUPAC International Symposium on MacroMolecular Complexes (MMC-17)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] ナノファイバーフレームワークからなる固体高分子電解質の設計と二次電池応用2017

    • Author(s)
      田中 学, 稲船 勇太, 中澤 駿, 竹中 海斗, 川上 浩良
    • Organizer
      第66回高分子討論会
    • Related Report
      2017 Research-status Report
  • [Presentation] Solid Polymer Electrolytes Based on Ion Conductive Nanofiber Framework for Lithium Ion Battery2017

    • Author(s)
      Manabu Tanaka, Tsukasa Watanabe, Yuta Inafune, Hiroyoshi Kawakami
    • Organizer
      232nd ECS MEETING
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] リチウムイオン伝導性ナノファイバーフレームワークからなる固体高分子電解質の作製と二次電池特性評価2017

    • Author(s)
      田中 学, 稲船 勇太, 中澤 駿, 竹中 海斗, 川上 浩良
    • Organizer
      第58回電池討論会
    • Related Report
      2017 Research-status Report
  • [Book] ナノファイバーの製造・加工技術と応用事例 (第8章 第2節 分担執筆)2019

    • Author(s)
      田中 学, 川上 浩良
    • Total Pages
      483
    • Publisher
      技術情報協会
    • Related Report
      2019 Annual Research Report
  • [Book] 燃料電池 (19巻, 1号, p29-33)2019

    • Author(s)
      田中 学, 川上 浩良
    • Publisher
      低加湿作動を志向した表面修飾ナノファイバー複合電解質膜の開発
    • Related Report
      2019 Annual Research Report
  • [Remarks] 東京都立大学 都市環境学部 環境応用化学科 准教授 田中 学のホームページ

    • URL

      http://www.comp.tmu.ac.jp/m-tanaka/

    • Related Report
      2019 Annual Research Report
  • [Remarks] 首都大学東京 都市環境学部 環境応用化学科 助教 田中 学のホームページ

    • URL

      http://www.comp.tmu.ac.jp/m-tanaka/

    • Related Report
      2018 Research-status Report 2017 Research-status Report
  • [Patent(Industrial Property Rights)] ナノファイバー、ナノファイバー繊維集積体、複合膜、高分子固体電解質およびリチウムイオン電池2019

    • Inventor(s)
      川上 浩良、田中 学、渡辺 司
    • Industrial Property Rights Holder
      川上 浩良、田中 学、渡辺 司
    • Industrial Property Rights Type
      特許
    • Filing Date
      2019
    • Related Report
      2019 Annual Research Report

URL: 

Published: 2017-04-28   Modified: 2021-02-19  

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