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Bio-assisted nanophotocatalysis for solar-hydrogen

Research Project

Project/Area Number 17K06011
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Inorganic industrial materials
Research InstitutionYamagata University

Principal Investigator

Arima Bashir Ahmmad  山形大学, 大学院理工学研究科, 准教授 (30596549)

Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2019: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2018: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2017: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywords光触媒 / 水素製造 / ナノコンポジット / バイオ分子 / グラファイトシリカ / ナノテク
Outline of Final Research Achievements

This research is aimed to synthesize biomolecule / inorganic nanocomposites for the development of a highly efficient H2 production system via water splitting. In the first part, the effect of bacteriorhodopsin (bR) on the photocatalytic hydrogen production over GS/TiO2 has been investigated. The obtained experimental results supported our previously reported mechanism of the H2 output over GS/TiO2. In the second part, biomolecule decorated CdS nanocomposite by solvothermal method. The as-synthesized CdS nanocomposite showed about 18 times higher activity compared to pure CdS in terms of H2 production via water splitting. Improved activity may be attributed to the increased specific surface area of the nanocomposite. These results indicate that nanocomposite of biomolecule/ inorganic compound could be a promising candidate for solar H2 production via water splitting.

Academic Significance and Societal Importance of the Research Achievements

本研究ではバイオ分子・無機化合物を用いて水分解から水素製造機構解明した。バイオ分子を利用した異例な水素発生システムを詳細に調べることでバイオナノテクノロジー分野及び光触媒の反応場に関する新たな知見が得られると共に光触媒の研究にも大きく貢献することが期待される。また、バイオ分子・CdSナノコンポジットを利用して通常のCdSより水素発生量を約20倍の増加に成功した。試料合成の最適条件を設定し、さらなる増加が見込まれる。これにより、太陽光を有効に利用して水素の産業生産の実現が可能となり、現在大変開発が進んでいる燃料電池やそれを搭載した自動車の普及、地球温暖化の根本的な防止に大きく貢献できる。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Research-status Report
  • 2017 Research-status Report
  • Research Products

    (35 results)

All 2020 2019 2018 2017 Other

All Journal Article (15 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 5 results,  Open Access: 4 results) Presentation (13 results) (of which Int'l Joint Research: 4 results,  Invited: 2 results) Remarks (6 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Efficient light trapping structures for organic photovoltaics fabricated by nanoimprint lithography2020

    • Author(s)
      Shigeru Kubota, Kenta Hiraga, Kensaku Kanomata,Bashir Ahmmad, Jun Mizuno, Fumihiko Hirose
    • Journal Title

      Journal of Photopolymer Science and Technology

      Volume: 印刷中 Pages: 1-5

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] 酸化亜鉛コーティングをした色素増感太陽電池の試作と評価2020

    • Author(s)
      鈴木拓馬・吉田一樹・鹿又健作・三浦正範・有馬 ボシール アハンマド・久保田 繁・廣瀬文彦
    • Journal Title

      電子情報通信学会技術研究報告

      Volume: 119 Pages: 29-31

    • Related Report
      2019 Annual Research Report
  • [Journal Article] ヒスチジン添加したCdS@TiO2 コアーシェル型ナノコンポジットの合成及び水の光分解による水素製造評価2020

    • Author(s)
      間井寛人・東條郁也・久保田 繁・廣瀬文彦・有馬ボシールアハンマド
    • Journal Title

      電子情報通信学会技術研究報告

      Volume: 119 Pages: 25-28

    • Related Report
      2019 Annual Research Report
  • [Journal Article] バイオ分子/CdSナノコンポジットの合成及び水の光分解による水素製造評価2020

    • Author(s)
      東條郁也・久保田繁・廣瀬文彦・有馬ボシールアハンマド
    • Journal Title

      電子情報通信学会技術研究報告

      Volume: 119 Pages: 19-23

    • Related Report
      2019 Annual Research Report
  • [Journal Article] Room temperature atomic layer deposition of niobium oxide using plasma excited humidified argon and its application to anticorrosion to hydrochloric acid2019

    • Author(s)
      Yoshida Kazuki、Tokoro Kentaro、Kanomata Kensaku、Miura Masanori、Saito Kentaro、Ahmmad Bashir、Kubota Shigeru、Hirose Fumihiko
    • Journal Title

      Journal of Vacuum Science & Technology A

      Volume: 37 Issue: 6 Pages: 060901-060901

    • DOI

      10.1116/1.5116844

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Effects of carbon materials and bacteriorhodopsin on photocatalytic hydrogen production over TiO22019

    • Author(s)
      Bashir Ahmmad Arima, Shigeru Kubota, Yoshiko Okada, Fumihiko Hirose
    • Journal Title

      IEICE tech. Rep

      Volume: 118 Pages: 19-22

    • Related Report
      2018 Research-status Report
    • Open Access
  • [Journal Article] Synthesis and magnetic properties of Pr, Gd co-doped bismuth ferrite2019

    • Author(s)
      Mizuno Kosuke, Shigeru Kubota, Fumihiko Hirose, Bashir Ahmmad Arima
    • Journal Title

      IEICE tech. Rep

      Volume: 118 Pages: 15-17

    • NAID

      40021840923

    • Related Report
      2018 Research-status Report
    • Open Access
  • [Journal Article] 色素増感太陽電池の表面修飾による高効率化2019

    • Author(s)
      野口雄祐、森義晴、吉田一樹、鹿又健作、三浦正範、有馬 ボシール アハンマド、廣瀬文彦
    • Journal Title

      電子情報通信学会技術研究報告

      Volume: 118 Pages: 27-31

    • Related Report
      2018 Research-status Report
    • Open Access
  • [Journal Article] Room-Temperature Atomic Layer Deposition of SnO<sub>2</sub> Using Tetramethyltin and Its Application to TFT Fabrication2018

    • Author(s)
      K. Tokoro, S. Saito, K. Kanomata, M. Miura, B. Ahmmad, Shigeru Kubota,F. Hirose
    • Journal Title

      IEICE Transactions on Electronics

      Volume: E101.C Issue: 5 Pages: 317-322

    • DOI

      10.1587/transele.E101.C.317

    • NAID

      130006729734

    • ISSN
      0916-8524, 1745-1353
    • Year and Date
      2018-05-01
    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] フォト電極修飾によるCdS量子ドット太陽電池の効率向上に関する研究2018

    • Author(s)
      木幡優弥、三浦正範、鹿又健作、久保田 繁、廣瀬文彦、有馬 ボシール アハンマド
    • Journal Title

      電子情報通信学会技術研究報告

      Volume: 118 Pages: 31-33

    • Related Report
      2018 Research-status Report
    • Open Access
  • [Journal Article] 光合成モデルシステムを用いた水素製造に関する研究2018

    • Author(s)
      有馬 ボシールアハンマド、鹿又健作、久保田繁、廣瀬文彦
    • Journal Title

      電子情報通信学会技術研究報告

      Volume: 118 Pages: 25-28

    • Related Report
      2017 Research-status Report
  • [Journal Article] 金ナノ粒子の局在表面プラズモン共鳴による量子ドット増感太陽電池の効率向上に関する研究2017

    • Author(s)
      木幡優弥、三浦 正範、鹿又健作、久保田繁、廣瀬文彦、有馬ボシールアハンマド
    • Journal Title

      電子情報通信学会技術研究報告

      Volume: 117 Pages: 101-105

    • Related Report
      2017 Research-status Report
  • [Journal Article] ゼオライト修飾光電極を用いた色素増感太陽電池の試作と評価2017

    • Author(s)
      今井 貴大、三浦 正範、鹿又健作、有馬ボシールアハンマド、久保田繁、廣瀬文彦
    • Journal Title

      電子情報通信学会技術研究報告

      Volume: 117 Pages: 95-98

    • Related Report
      2017 Research-status Report
  • [Journal Article] Room-Temperature Atomic Layer Deposition of Aluminum Silicate and its Application in Dye sensitized Solar Cells2017

    • Author(s)
      Takahiro Imai, Yoshiharu Mori, Kensaku Kanomata, Masanori Miura, Bashir Ahmmad, Shigeru Kubota, Fumihiko Hirose
    • Journal Title

      Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films

      Volume: 36 Issue: 1

    • DOI

      10.1116/1.5002716

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Preparation of high crystalline nanoparticles of rare-earth based complex perovskites and comparison of their structural and magnetic properties with bulk counterparts2017

    • Author(s)
      Mohammed Basith, M A Islam, Bashir Ahmmad, Md Sarowar Hossain, Kristian Molhave
    • Journal Title

      Materials Research Express

      Volume: 4 Issue: 7 Pages: 075012-075012

    • DOI

      10.1088/2053-1591/aa769e

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Presentation] Biomolecule Decorated Nanoparticles of CdS Photocatalyst for Highly Efficient Hydrogen Production via Water Splitting2019

    • Author(s)
      Fumiya Tojo, Shigeru Kubota, Fumihiko Hirose, Bashir Ahmmad
    • Organizer
      The 7th International Conference on Smart Systems Eingineering 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Histidine Decorated CdS@TiO2 Core-Shell Nanocomposites Photocatalyst for Hydrogen Production via Water Splitting2019

    • Author(s)
      Hiroto Mai, Fumiya Tojo, Shigeru Kubota, Fumihiko Hirose, Bashir Ahmmad
    • Organizer
      The 7th International Conference on Smart Systems Eingineering 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Biomolecule impregnated nano-photocatalysts for hydrogen production2019

    • Author(s)
      Bashir Ahmmad, Fumiya Tojo, Hiroto Mai
    • Organizer
      Joint Meeting of the Tohoku Area Chemistry Societies/Symposium for Young Researchers
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] Multiferroic Properties of Gd and Pr Co-Doped BiFeO3 Ceramics2019

    • Author(s)
      Naoto Kubota, M. K. Alam, F. A. Khan, Shigeru Kubotaa, Fumihiko Hirosea, Bashir Ahmmad
    • Organizer
      The 7th International Conference on Smart Systems Eingineering 2019
    • Related Report
      2019 Annual Research Report
  • [Presentation] Histidine decorated nanoparticles of cadmium sulfide for highly efficient hydrogen production via water splitting2019

    • Author(s)
      Bashir Ahmmad, Fumiya Tojo, Shigeru Kubota, Fumihiko Hirose
    • Organizer
      7th International Conference on Semiconductor Photochemistry
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] TiO2光触媒による水素発生に及ぼすカーボン材料及びバクテリアロドプシンの効果2019

    • Author(s)
      有馬 ボシールアハンマド、岡田佳子、久保田繁、廣瀬文彦
    • Organizer
      電子情報通信学会CPM研究会
    • Related Report
      2018 Research-status Report
  • [Presentation] Pr, Gd共添加ビスマスフェライトの合成及び磁化特性評価2019

    • Author(s)
      水野浩輔、久保田繁、廣瀬文彦、有馬 ボシールアハンマド
    • Organizer
      電子情報通信学会CPM研究会
    • Related Report
      2018 Research-status Report
  • [Presentation] 色素増感太陽電池の表面修飾による高効率化2019

    • Author(s)
      野口雄祐、森義晴、吉田一樹、鹿又健作、三浦正範、有馬 ボシール アハンマド、廣瀬文彦
    • Organizer
      電子情報通信学会CPM研究会
    • Related Report
      2018 Research-status Report
  • [Presentation] Effect of graphite silica or carbon nanotube on the photocatalytic hydrogen production over TiO22018

    • Author(s)
      B. Ahmmad, K. Kanomata, S. Kubota, F. Hirose
    • Organizer
      The 1st International Symposium on Hydrogen Energy and Energy Technologies
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] フォト電極修飾によるCdS量子ドット太陽電池の効率向上に関する研究2018

    • Author(s)
      木幡優弥、三浦正範、鹿又健作、久保田 繁、廣瀬文彦、有馬 ボシール アハンマド
    • Organizer
      電子情報通信学会CPM研究会
    • Related Report
      2018 Research-status Report
  • [Presentation] 光合成モデルシステム及び光触媒を用いた水素製造に関する研究2018

    • Author(s)
      有馬 ボシールアハンマド
    • Organizer
      無機化学セミナーin岡山
    • Related Report
      2017 Research-status Report
    • Invited
  • [Presentation] Hydrogen Production Using Artificial Photosynthesis System2018

    • Author(s)
      Bashir Ahmmad Arima, Kensaku Kanomata, Shigeru Kubota, Fumihiko Hirose
    • Organizer
      電子情報通信学会電子デバイス研究会
    • Related Report
      2017 Research-status Report
  • [Presentation] 金ナノ粒子の局在表面プラズモン共鳴による量子ドット増感太陽電池の効率向上に関する研究2017

    • Author(s)
      木幡優弥、三浦 正範、鹿又健作、久保田繁、廣瀬文彦、有馬ボシールアハンマド
    • Organizer
      電子情報通信学会電子部品・材料研究会
    • Related Report
      2017 Research-status Report
  • [Remarks] 有馬研究室HP

    • URL

      http://nanoenergy-lab.yz.yamagata-u.ac.jp/

    • Related Report
      2019 Annual Research Report
  • [Remarks] Research map

    • URL

      https://researchmap.jp/30596549/?lang=ja

    • Related Report
      2019 Annual Research Report
  • [Remarks] Research gate

    • URL

      https://www.researchgate.net/profile/Bashir_Ahmmad

    • Related Report
      2019 Annual Research Report
  • [Remarks] ORCiD

    • URL

      https://orcid.org/0000-0001-7748-9746

    • Related Report
      2019 Annual Research Report
  • [Remarks] Nano Energy Lab

    • URL

      http://nanoenergy-lab.yz.yamagata-u.ac.jp

    • Related Report
      2018 Research-status Report
  • [Remarks]

    • URL

      http://yudb.kj.yamagata-u.ac.jp/html/100000575_ja.html

    • Related Report
      2017 Research-status Report
  • [Patent(Industrial Property Rights)] CdSナノコンポジットおよびその製造法2020

    • Inventor(s)
      有馬 ボシールアハンマド
    • Industrial Property Rights Holder
      山形大学
    • Industrial Property Rights Type
      特許
    • Filing Date
      2020
    • Related Report
      2019 Annual Research Report

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Published: 2017-04-28   Modified: 2021-02-19  

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