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physical properties and preparation of molecular nanocoils

Research Project

Project/Area Number 17K06028
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Device related chemistry
Research InstitutionTokyo University of Agriculture and Technology

Principal Investigator

tatewaki yoko  東京農工大学, 工学(系)研究科(研究院), 講師 (30435763)

Co-Investigator(Kenkyū-buntansha) 西原 禎文  広島大学, 理学研究科, 准教授 (00405341)
Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2019: ¥390,000 (Direct Cost: ¥300,000、Indirect Cost: ¥90,000)
Fiscal Year 2018: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2017: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywordsナノコイル / 分子集合体 / 電荷移動錯体 / 電磁特性 / 電気物性 / 分子性コイル / 分子性導体 / 起電力 / 螺旋構造 / 分子性ナノワイヤ / スキャホールド / ナノ材料 / マイクロ・ナノデバイス / 電子・電気材料 / 超分子化学
Outline of Final Research Achievements

In this study, we prepared a molecular nanocoils and measured the electromagnetic properties. The nanocoils showed the conductivity at room temperature after mixing acceptors to form the aggregated state. Furthermore, we aimed to develop new functional materials by clarifying the electromagnetic properties of the obtained nanocoils. The applicant has challenged the creation of self-activated molecular nanocoils by developing the highly conductive molecule design and substrate interface control method.
1. Synthesis of new organic conductors and preparation of molecular electromagnetic nanocoils
2. Electromagnetic properties of molecular electromagnetic nanocoils

Academic Significance and Societal Importance of the Research Achievements

これまでに分子性1次元組織体は多数報告されているが、その殆どの物性は伝導特性であった。しかし、本研究で得られる分子性電磁ナノコイルは、電気特性と磁気特性が連動するナノ構造であり、構造と物性の相関解明が可能であることから創造的な研究であると言える。また、本研究で得られるナノコイルは導電性を有しているため、電磁コイルとして機能することが予想されるが、有機物からなるコイル由来の誘導起電力応答を確認している報告例は国内外において皆無である。そのため、本研究が達成された暁には、分子エレクトロニクス分野をリードする独創的な研究に成り得る。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Research-status Report
  • 2017 Research-status Report
  • Research Products

    (37 results)

All 2019 2018 2017 Other

All Int'l Joint Research (2 results) Journal Article (9 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 8 results,  Open Access: 4 results) Presentation (22 results) (of which Int'l Joint Research: 4 results,  Invited: 1 results) Book (2 results) Remarks (1 results) Patent(Industrial Property Rights) (1 results)

  • [Int'l Joint Research] The university of Edinburgh(英国)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] University of Edinburgh(英国)

    • Related Report
      2018 Research-status Report
  • [Journal Article] One-dimensional molecular nano-branched structures of tetrathiafulvalene derivative with crown ether2019

    • Author(s)
      Shota Nakamura, Tsubasa Takei, Sadafumi Nishihara, Shuji Okada, Tomoyuki Akutagawa, Takayoshi Nakamura and Yoko Tatewaki
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 59 Issue: SD Pages: SDDA10-SDDA10

    • DOI

      10.7567/1347-4065/ab5914

    • NAID

      210000157606

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Structures and Physical Properties of Self-Assembled Helical Nanostructures Composed of Charge Transfer Complexes2019

    • Author(s)
      Yoko Tatewaki, Hiroki Iwata , Satoshi Noguchi ,Sadafumi Nishihara,Tomoyuki Akutagawa,Takayoshi nakamura
    • Journal Title

      IEICE Technical Report

      Volume: 119 Pages: 13-15

    • NAID

      40022118217

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Single Crystal Structures and Physical Properties of Porphyrin Derivatives2019

    • Author(s)
      Taku Kato, Sadafumi Nishihara,Tomoyuki Akutagawa,Takayoshi Nakamura, Yoko Tatewaki
    • Journal Title

      IEICE Technical Report

      Volume: 119 Pages: 21-24

    • NAID

      40022118244

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Properties of Disk-like Threefold Symmetrical Tetrathiafulvalene Derivative2019

    • Author(s)
      Yuto Kimura ,Sadafumi Nishihara ,Tomoyuki Akutagawa , Takayoshi Nakamura Yoko Tatewaki
    • Journal Title

      IEICE Technical Report

      Volume: 119 Pages: 25-28

    • NAID

      40022118477

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Solid state polymerization of diacetylene derivatives with 1,4-benzoquinone2019

    • Author(s)
      Kazuki Saito ,Shuji Okada, Yoko Tatewaki
    • Journal Title

      IEICE Technical Report

      Volume: 119 Pages: 29-32

    • NAID

      40022118505

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Optimizing Lithium Ion Conduction through Crown Ether-Based Cylindrical Channels in [Ni(dmit)2]- Salts2018

    • Author(s)
      Katsuya Ichihashi, Daisuke Konno, Takuya Date, Takumi Nishimura, Kseniya Yu. Maryunina, Katsuya Inoue, Toshimi Nakaya, Kazuhiro Toyoda, Yoko Tatewaki, Tomoyuki Akutagawa, Takayoshi Nakamura, Sadafumi Nishihara,
    • Journal Title

      Chem. Mater

      Volume: 30 Issue: 20 Pages: 7130-7137

    • DOI

      10.1021/acs.chemmater.8b03027

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Solid-state polymerization of 1,4-bis(hexatriynyl)benzene derivatives2018

    • Author(s)
      Sasamura, K ; Mizuguchi, K ; Tatewaki, Y ; Okada, S
    • Journal Title

      POLYMER JOURNAL

      Volume: 50 Issue: 12 Pages: 1159-1167

    • DOI

      10.1038/s41428-018-0107-x

    • NAID

      40021735617

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Self-Assembly and Solid-State Polymerization of Butadiyne Derivatives with Amide and Trialkoxyphenyl Groups2017

    • Author(s)
      K, Kikuchi, Y. Tatewaki, S. Okada
    • Journal Title

      Bull. Chem. Soc. Jpn.

      Volume: 90(3) Issue: 3 Pages: 298-305

    • DOI

      10.1246/bcsj.20160347

    • NAID

      130005439825

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] “Synthesis and Solid-State Polymerization of a Macrocyclic Compound with Two Butadiyne Units”2017

    • Author(s)
      K, Kikuchi, Y. Tatewaki, *S. Okada
    • Journal Title

      Bull. Chem. Soc. Jpn.

      Volume: 90(4), Issue: 4 Pages: 387-394

    • DOI

      10.1246/bcsj.20160418

    • NAID

      130006770728

    • Related Report
      2017 Research-status Report
  • [Presentation] 有機導電性分子を用いたナノコイル構造の作製とその特性2019

    • Author(s)
      帯刀陽子
    • Organizer
      表面真空学会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] 三回対称性を有する tetrathiafulvalene 誘導体の合成2019

    • Author(s)
      木村雄登,西原禎文,帯刀陽子
    • Organizer
      繊維学会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Tetrathiafulvalene にキラル分子を付与した誘導体の合成と 分子集合体作成2019

    • Author(s)
      野口聡士,西原禎文, 帯刀陽子
    • Organizer
      繊維学会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Electronic Properties of Molecular Nanocoils Composed of TTF Derivatives with Chiral Units and F4TCNQ Complexes2019

    • Author(s)
      Yoko Tatewaki
    • Organizer
      M and be 10
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Preparation of Molecular Nanocoils Composed of Charge Transfer Complexes2019

    • Author(s)
      Satoshi Noguchi
    • Organizer
      M and be 10
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] キラル部位を有する有機導電体を用いた1次元集合体の作製と評価2019

    • Author(s)
      岩田 浩輝、西原 禎文、芥川 智之、中村 貴義、帯刀 陽子
    • Organizer
      応用物理学会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 有機導体からなるナノコイルの作製2019

    • Author(s)
      野口 聡士1、西原 禎文2、芥川 智行3、中村 貴義4、帯刀 陽子
    • Organizer
      応用物理学会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 分子性導体からなる螺旋分子ナノ集合体の構造と物性2019

    • Author(s)
      帯刀陽子・岩田浩輝・野口聡士・西原禎文・芥川智行・中村貴義
    • Organizer
      電子情報通信学会
    • Related Report
      2019 Annual Research Report
  • [Presentation] ポルフィリン誘導体の単結晶構造解析と物性評価2019

    • Author(s)
      加藤 拓 西原禎文・芥川智行・中村貴義
    • Organizer
      電子情報通信学会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 三回対称ディスク状分子であるtetrathiafulvalene誘導体の合成と評価2019

    • Author(s)
      木村雄登 西原禎文・芥川智行・中村貴義
    • Organizer
      電子情報通信学会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 1,4-benzoquinoneを直結したジアセチレン誘導体の合成と固相重合2019

    • Author(s)
      齊藤和樹・岡田修司・帯刀陽子
    • Organizer
      電子情報通信学会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 導電性有機材料を用いた螺旋状高次集合体の構造と電磁特性評価2019

    • Author(s)
      帯刀 陽子1、岩田 浩輝1、菅野由佳1、西原 禎文2、芥川智行3、中村貴義
    • Organizer
      応用物理学会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 電荷移動錯体を利用した螺旋状分子集合体の作製とその電磁気特性2019

    • Author(s)
      帯刀 陽子1、岩田 浩輝1、菅野由佳1、西原 禎文2、芥川智行3、中村貴義4
    • Organizer
      日本化学会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 電荷移動錯体からなる分子集合体ナノコイルの創成と電気特性2019

    • Author(s)
      岩田 浩輝、岩本 健太郎、西原 禎文、帯刀 陽子
    • Organizer
      応用物理学会
    • Related Report
      2018 Research-status Report
  • [Presentation] TTF誘導体を用いた1次元組織体の作製2018

    • Author(s)
      竹井翼、西原禎文、帯刀陽子
    • Organizer
      応用物理学会
    • Related Report
      2018 Research-status Report
  • [Presentation] 金属配位能を有する分子を骨格としたカプセル状分子の作製と物性評価2018

    • Author(s)
      岩田浩輝、竹井翼、西原禎文、帯刀陽子
    • Organizer
      繊維学会
    • Related Report
      2018 Research-status Report
  • [Presentation] 光,電気応答性材料を目指した様々なかご状分子の合成と物性評価2018

    • Author(s)
      加藤拓、只井桃、西原禎文、帯刀陽子
    • Organizer
      繊維学会
    • Related Report
      2018 Research-status Report
  • [Presentation] スキャホールドに用いる分子性ナノコイルの物性評価2018

    • Author(s)
      岩本 健太郎,西原 禎文,帯刀陽子
    • Organizer
      応用物理学会
    • Related Report
      2018 Research-status Report
  • [Presentation] Electronic Properties of Molecular Nanowires Composed of Organic Conductors2017

    • Author(s)
      T. Takei, S. Nishihara, Y. Tatewaki,
    • Organizer
      The Institute of Electronics, Information and Communication Engineers,
    • Related Report
      2017 Research-status Report
  • [Presentation] ナノファイバーを利用したスキャホールド材料の創成2017

    • Author(s)
      岩本健太郎*,帯刀陽子
    • Organizer
      ナノファイバー学会第8回年次大会
    • Related Report
      2017 Research-status Report
  • [Presentation] self Assemble Structures Composed of Nonplanar π-conjugated Derivatives2017

    • Author(s)
      Tsubasa Takei
    • Organizer
      JSPS CtC/Leverhulme Trust 6th Joint Workshop, Montreal 2017
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Molecular Nanocoils of Conducting Molecules with Chiral Units2017

    • Author(s)
      Yoko Tatewaki
    • Organizer
      JSPS CtC/Leverhulme Trust 6th Joint Workshop, Montreal 2017
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Book] ナノファイバー2019

    • Author(s)
      帯刀陽子 西原禎文 岡田修司
    • Total Pages
      4
    • Publisher
      技術情報協会
    • ISBN
      9784861047657
    • Related Report
      2019 Annual Research Report
  • [Book] ケミカルエンジニアリング2019

    • Author(s)
      帯刀陽子 西原禎文 岡田修司
    • Total Pages
      5
    • Publisher
      化学工業社
    • Related Report
      2019 Annual Research Report
  • [Remarks]

    • URL

      http://web.tuat.ac.jp/~tatewaki/member.html

    • Related Report
      2019 Annual Research Report
  • [Patent(Industrial Property Rights)] 電磁材料、並びに、それを含むシールド材、導電シート及び給電部材2019

    • Inventor(s)
      帯刀 陽子 西原 禎 文
    • Industrial Property Rights Holder
      帯刀 陽子 西原 禎 文
    • Industrial Property Rights Type
      特許
    • Filing Date
      2019
    • Related Report
      2019 Annual Research Report

URL: 

Published: 2017-04-28   Modified: 2021-02-19  

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